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Development of Mg–Zn–Y–Ca alloys containing icosahedral quasicrystal phase through trace addition of Y

Published online by Cambridge University Press:  31 August 2018

Kaibo Nie*
Affiliation:
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, People’s Republic of China; and Shanxi key laboratory of Advanced Magnesium-based Materials, Taiyuan University of Technology, Taiyuan 030024, China
Xinkai Kang
Affiliation:
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, People’s Republic of China
Kunkun Deng
Affiliation:
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, People’s Republic of China; and Shanxi key laboratory of Advanced Magnesium-based Materials, Taiyuan University of Technology, Taiyuan 030024, China
Yachao Guo
Affiliation:
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, People’s Republic of China
Jungang Han
Affiliation:
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, People’s Republic of China
Zhihao Zhu
Affiliation:
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: kaibo.nie@gmail.com, niekaibo2015@163.com
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Abstract

In this work, three Mg–Zn–Y–Ca alloys reinforced by icosahedral quasicrystal phase through trace Y addition were extruded at a low temperature of 503 K. With increasing the contents of Zn and Y, the grain size of the as-extruded alloy was significantly reduced while both the size and volume fraction of nanosized precipitates were increased. The grain refinement in the Mg–Zn–Y–Ca alloy was related to dynamical recrystallization during extrusion and the pinning effect of nanosized precipitates on the grain boundaries. After extrusion, the yield strength (YS) and ultimate tensile strength (UTS) of the three alloys were significantly increased. The YS of 294.0 MPa, UTS of 337.5 MPa, and elongation of 10.6% were obtained in the case of Mg–2.09Zn–0.26Y–0.12Ca (at.%) alloys. The improvement in the mechanical properties could mainly be due to the grain boundary strengthening and Orowan strengthening. The as-cast alloy exhibited a typical cleavage fracture while the as-extruded alloy possessed a mixture fracture of dimple fracture and cracking along the twinning.

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Article
Copyright
Copyright © Materials Research Society 2018 

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References

REFERENCES

Kulekci, M.K.: Magnesium and its alloys applications in automotive industry. Int. J. Adv. Des. Manuf. Technol. 39, 851 (2007).CrossRefGoogle Scholar
Mordike, B.L. and Ebert, T.: Magnesium. Mater. Sci. Eng., A 302, 37 (2001).CrossRefGoogle Scholar
Pan, F.S., Wang, Q.H., Jiang, B., He, J.J., Chai, Y.F., and Xu, J.: An effective approach called the composite extrusion to improve the mechanical properties of AZ31 magnesium alloy sheets. Mater. Sci. Eng., A 655, 339 (2016).CrossRefGoogle Scholar
Smola, B., Stulıková, I., von Buch, F., and Mordike, B.L.: Structural aspects of high performance Mg alloys design. Mater. Sci. Eng., A 324, 113 (2002).CrossRefGoogle Scholar
Wang, X.J., Xu, D.K., Wu, R.Z., Chen, X.B., Peng, Q.M., Jin, L., Xin, Y.C., Zhang, Z.Q., Liu, Y., Chen, X.H., Chen, G., Deng, K.K., and Wang, H.Y.: What is going on in magnesium alloys? J. Mater. Sci. Technol. 34, 245 (2018).CrossRefGoogle Scholar
Janeček, M., Král, R., Dobroň, P., Chmelík, F., Šupík, V., and Holländer, F.: Mechanisms of plastic deformation in AZ31 magnesium alloy investigated by acoustic emission and transmission electron microscopy. Mater. Sci. Eng., A 462, 311 (2007).CrossRefGoogle Scholar
Huang, H., Yuan, G.Y., Chen, C.L., Ding, W.J., and Wang, Z.C.: Excellent mechanical properties of an ultrafine-grained quasicrystalline strengthened magnesium alloy with multi-modal microstructure. Mater. Lett. 107, 181 (2013).CrossRefGoogle Scholar
Stanford, N., Atwell, D., and Barnett, M.R.: The effect of Gd on the recrystallisation, texture and deformation behaviour of magnesium-based alloys. Acta Mater. 58, 6773 (2010).CrossRefGoogle Scholar
Tian, Y., Huang, H., Yuan, G.Y., and Ding, W.J.: Microstructure evolution and mechanical properties of quasicrystal-reinforced Mg–Zn–Gd alloy processed by cyclic extrusion and compression. J. Alloys Compd. 626, 42 (2015).CrossRefGoogle Scholar
Hono, K., Mendis, C.L., Sasaki, T.T., and Oh-ishi, K.: Towards the development of heat-treatable high-strength wrought Mg alloys. Scr. Mater. 63, 710 (2010).CrossRefGoogle Scholar
Kang, J.W., Wang, C.J., Deng, K.K., Nie, K.B., Bai, Y., and Li, W.J.: Microstructure and mechanical properties of Mg–4Zn–0.5Ca alloy fabricated by the combination of forging, homogenization and extrusion process. J. Alloys Compd. 720, 196 (2017).CrossRefGoogle Scholar
Yasi, J.A., Hector, L.G., and Trinkle, D.R.: Prediction of thermal cross-slip stress in magnesium alloys from a geometric interaction model. Acta Mater. 60, 2350 (2012).CrossRefGoogle Scholar
Huang, H., Yuan, G.Y., Wang, Z.C., Chen, C.L., and Ding, W.J.: Effect of icosahedral quasicrystalline fraction and extrusion ratio on microstructure, mechanical properties, and anisotropy of Mg–Zn–Gd-based alloys. Metall. Mater. Trans. A 44A, 2725 (2013).CrossRefGoogle Scholar
Shield, J.E., Campbell, J.A., and Sordelet, D.J.: Mechanical properties of Al–Cu–Fe-based quasicrystalline coatings. J. Mater. Sci. Lett. 16, 2019 (1997).CrossRefGoogle Scholar
Medina, J., Perez, P., Garces, G., and Adeva, P.: Effects of calcium, manganese and cerium-rich mischmetal additions on the mechanical properties of extruded Mg–Zn–Y alloy reinforced by quasicrystalline I-phase. Mater. Charact. 129, 195 (2017).CrossRefGoogle Scholar
Bae, D.H., Kim, Y., and Kim, I.J.: Thermally stable quasicrystalline phase in a superplastic Mg–Zn–Y–Zr alloy. Mater. Lett. 60, 2190 (2006).CrossRefGoogle Scholar
Li, W.J., Deng, K.K., Zhang, X., Nie, K.B., and Xu, F.J.: Effect of ultra-slow extrusion speed on the microstructure and mechanical properties of Mg–4Zn–0.5Ca alloy. Mater. Sci. Eng., A 677, 367 (2016).CrossRefGoogle Scholar
Kang, J.W., Sun, X.F., Deng, K.K., Xu, F.J., Zhang, X., and Bai, Y.: High strength Mg–9Al serial alloy processed by slow extrusion. Mater. Sci. Eng., A 697, 211 (2017).CrossRefGoogle Scholar
Tian, Y., Huang, H., Yuan, G.Y., Chen, C.L., Wang, Z.C., and Ding, W.J.: Nanoscale icosahedral quasicrystal phase precipitation mechanism during annealing for Mg–Zn–Gd-based alloys. Mater. Lett. 130, 236 (2014).CrossRefGoogle Scholar
Xin, Y.C., Hong, R., Feng, B., Yu, H.H., Wu, Y., and Liu, Q.: Fabrication of Mg/AL multilayer plates using an accumulative extrusion bonding process. Mater. Sci. Eng., A 640, 210 (2015).CrossRefGoogle Scholar
Lee, J.Y., Lim, H.K., Kim, D.H., Kim, W.T., and Kim, D.H.: Effect of icosahedral phase particles on the texture evolution in Mg–Zn–Y alloys. Mater. Sci. Eng., A 491, 349 (2008).CrossRefGoogle Scholar
Singh, A., Nakamura, M., Watanabe, M., Kato, A., and Tsai, A.P.: Quasicrystal strengthened Mg–Zn–Y alloys by extrusion. Scr. Mater. 49, 417 (2003).CrossRefGoogle Scholar
Huang, H., Tian, Y., Yuan, G.Y., Chen, C.L., Ding, W.J., and Wang, Z.C.: Formation mechanism of quasicrystals at the nanoscale during hot compression of Mg alloys. Scr. Mater. 78–79, 61 (2014).CrossRefGoogle Scholar
Du, Y., Zheng, M., Qiao, X., Wang, D., Peng, W., Wu, K., and Jiang, B.: Improving microstructure and mechanical properties in Mg–6 mass% Zn alloys by combined addition of Ca and Ce. Mater. Sci. Eng., A 656, 67 (2016).CrossRefGoogle Scholar
Du, Y.Z., Qiao, X.G., Zheng, M.Y., Wu, K., and Xu, S.W.: The microstructure, texture and mechanical properties of extruded Mg–5.3Zn–0.2Ca–0.5Ce (wt%) alloy. Mater. Sci. Eng., A 620, 164 (2015).CrossRefGoogle Scholar
Du, Y.Z., Qiao, X.G., Zheng, M.Y., Wu, K., and Xu, S.W.: Development of high-strength, low-cost wrought Mg–2.5 mass% Zn alloy through micro-alloying with Ca and La. Mater. Des. 85, 549 (2015).CrossRefGoogle Scholar
Deng, K.K., Wang, X.J., Zheng, M.Y., and Wu, K.: Dynamic recrystallization behavior during hot deformation and mechanical properties of 0.2 μm SiCp reinforced Mg matrix composite. Mater. Sci. Eng., A 560, 824 (2013).CrossRefGoogle Scholar
Shao, G., Varsani, V., and Fan, Z.: Thermodynamic modelling of the Y–Zn and Mg–Zn–Y systems. Calphad 30, 286 (2006).CrossRefGoogle Scholar
Gröbner, J., Kozlov, A., Fang, X.Y., Geng, J., Nie, J.F., and Schmid-Fetzer, R.: Phase equilibria and transformations in ternary Mg-rich Mg–Y–Zn alloys. Acta Mater. 60, 5948 (2012).CrossRefGoogle Scholar
Kim, S.H., Jung, J.G., You, B.S., and Park, S.H.: Effect of Ce addition on the microstructure and mechanical properties of extruded Mg–Sn–Al–Zn alloy. Mater. Sci. Eng., A 657, 406 (2016).CrossRefGoogle Scholar
Tahreen, N., Zhang, D.F., Pan, F.S., Jiang, X.Q., Li, D.Y., and Chen, D.L.: Hot deformation and work hardening behavior of an extruded Mg–Zn–Mn–Y alloy. J. Mater. Sci. Technol. 31, 1161 (2015).CrossRefGoogle Scholar
Basu, I., Pradeep, K.G., Miessen, C., Barrales-Mora, L.A., and Al-Samman, T.: The role of atomic scale segregation in designing highly ductile magnesium alloys. Acta Mater. 116, 77 (2016).CrossRefGoogle Scholar
Grey, E.A. and Higgins, G.T.: Solute limited grain boundary migration: A rationalisation of grain growth. Acta Metall. 21, 309 (1973).CrossRefGoogle Scholar
Hadorn, J.P., Sasaki, T.T., Nakata, T., Ohkubo, T., Kamado, S., and Hono, K.: Solute clustering and grain boundary segregation in extruded dilute Mg–Gd alloys. Scr. Mater. 93, 28 (2014).CrossRefGoogle Scholar
Shi, B.Q., Chen, R.S., and Ke, W.: Effects of yttrium and zinc on the texture, microstructure and tensile properties of hot-rolled magnesium plates. Mater. Sci. Eng., A 560, 62 (2013).CrossRefGoogle Scholar
Zhang, B., Wang, Y., Geng, L., and Lu, C.: Effects of calcium on texture and mechanical properties of hot-extruded Mg–Zn–Ca alloys. Mater. Sci. Eng., A 539, 56 (2012).CrossRefGoogle Scholar
Du, Y.Z., Zheng, M.Y., Qiao, X.G., Wu, K., Liu, X.D., Wang, G.J., Lv, X.Y., Li, M.J., Liu, X.L., Wang, Z.J., and Liu, Y.T.: The effect of double extrusion on the microstructure and mechanical properties of Mg–Zn–Ca alloy. Mater. Sci. Eng., A 583, 69 (2013).CrossRefGoogle Scholar
Hantzsche, K., Bohlen, J., Wendt, J., Kainer, K.U., Yi, S.B., and Letzig, D.: Effect of rare earth additions on microstructure and texture development of magnesium alloy sheets. Mater. Sci. Eng., A 63, 725 (2010).Google Scholar
Xu, C., Nakata, T., Qiao, X.G., Jiang, H.S., Sun, W.T., Chi, Y.C., Zheng, M.Y., and Kamado, S.: Effect of extrusion parameters on microstructure and mechanical properties of Mg–7.5Gd–2.5Y–3.5Zn–0.9Ca–0.4Zr (wt%) alloy. Mater. Sci. Eng., A 685, 159 (2017).CrossRefGoogle Scholar
Hofstetter, J., Ruedi, S., Baumgartner, I., Kilian, H., Mingler, B., Povoden-Karadeniz, E., Pogatscher, S., Uggowitzer, P.J., and Loffler, J.F.: Processing and microstructure-property relations of high-strength low-alloy (HSLA) Mg–Zn–Ca alloys. Acta Mater. 98, 423 (2015).CrossRefGoogle Scholar
De Cicco, M., Konishi, H., Cao, G., Choi, H.S., Turng, L-S., Perepezko, J.H., Kou, S., Lakes, R., and Li, X.: Strong, ductile magnesium-zinc nanocomposites. Metall. Mater. Trans. A 40, 3038 (2009).CrossRefGoogle Scholar
Ma, K.K., Wen, H.M., Hu, T., Topping, T.D., Isheim, D., Seidman, D.N., Lavernia, E.J., and Schoenung, J.M.: Mechanical behavior and strengthening mechanisms in ultrafine grain precipitation-strengthened aluminum alloy. Acta Mater. 62, 141 (2014).CrossRefGoogle Scholar
Khan, M.D.F. and Panigrahi, S.K.: Age hardening, fracture behavior and mechanical properties of QE22 Mg alloy. J. Magnesium Alloys 3, 210 (2015).Google Scholar
Rao, G.S. and Prasad, Y.V.R.K.: Grain boundary strengthening in strongly textured magnesium produced by hot rolling. Metall. Trans. A 13, 2219 (1982).CrossRefGoogle Scholar
Cheng, W.L., Tian, Q.W., Yu, H., Zhang, H., and You, B.S.: Strengthening mechanisms of indirect-extruded Mg–Sn based alloys at room temperature. J. Magnesium Alloys 2, 299 (2014).CrossRefGoogle Scholar
Wang, C.J., Deng, K.K., Nie, K.B., Shang, S.J., and Liang, W.: Competition behavior of the strengthening effects in as-extruded AZ91 matrix: Influence of pre-existed Mg17Al12 phase. Mater. Sci. Eng., A 656, 102 (2016).CrossRefGoogle Scholar
Xu, S.W., Zheng, M.Y., Kamado, S., Wu, K., Wang, G.J., and Lv, X.Y.: Dynamic microstructural changes during hot extrusion and mechanical properties of a Mg–5.0 Zn–0.9 Y–0.16 Zr (wt%) alloy. Mater. Sci. Eng., A 528, 4055 (2011).CrossRefGoogle Scholar
Zhang, E., He, W.W., Du, H., and Yang, K.: Microstructure, mechanical properties and corrosion properties of Mg–Zn–Y alloys with low Zn content. Mater. Sci. Eng., A 488, 102 (2008).CrossRefGoogle Scholar