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The effect of target crystallography on the growth of Pb(Mg1/3Nb2/3)O3 thin films using pulsed laser deposition

Published online by Cambridge University Press:  31 January 2011

M. H. Corbett
Affiliation:
Condensed Matter Physics and Materials Science Research Division, School of Mathematics and Physics, The Queen's University of Belfast, Belfast BT7 1NN, United Kingdom
G. Catalan
Affiliation:
Condensed Matter Physics and Materials Science Research Division, School of Mathematics and Physics, The Queen's University of Belfast, Belfast BT7 1NN, United Kingdom
R. M. Bowman*
Affiliation:
Condensed Matter Physics and Materials Science Research Division, School of Mathematics and Physics, The Queen's University of Belfast, Belfast BT7 1NN, United Kingdom
J. M. Gregg
Affiliation:
Condensed Matter Physics and Materials Science Research Division, School of Mathematics and Physics, The Queen's University of Belfast, Belfast BT7 1NN, United Kingdom
*
a)Address all correspondence to this author. e-mail: r.m.bowman@qub.ac.uk
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Abstract

Pulsed laser deposition has been used to make two sets of lead magnesium niobate thin films grown on single-crystal h100j MgO substrates. One set was fabricated using a perovskite-rich target while the other used a pyrochlore-rich target. It was found that the growth conditions required to produce almost 100% perovskite Pb(Mg1/3Nb2/3)O3 (PMN) films were largely independent of target crystallography. Films were characterized crystallographically using x-ray diffraction and plan view transmission electron microscopy, chemically using energy dispersive x-ray analysis, and electrically by fabricating a planar thin film capacitor structure and monitoring capacitance as a function of temperature. All characterization techniques indicated that perovskite PMN thin films had been successfully fabricated.

Type
Articles
Copyright
Copyright © Materials Research Society 1999

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