Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-28T01:24:13.584Z Has data issue: false hasContentIssue false
  • English
  • Français

Graphene-induced confined crystal growth of octahedral Zn2SnO4 and its improved Li-storage properties

Published online by Cambridge University Press:  19 November 2012

Wentao Song ,
Jian Xie ,
Shuangyu Liu ,
Gaoshao Cao ,
Tiejun Zhu  and
Xinbing Zhao
Wentao Song
Affiliation:
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Jian Xie*
Affiliation:
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Shuangyu Liu
Affiliation:
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Gaoshao Cao
Affiliation:
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Tiejun Zhu
Affiliation:
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Xinbing Zhao
Affiliation:
State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
*
a)Address all correspondence to this author. e-mail: xiejian1977@zju.edu.cn
Get access

Abstract

A Zn2SnO4/graphene (Zn2SnO4/G) hybrid was prepared by a facile one-pot hydrothermal route using SnCl4·5H2O, ZnSO4·7H2O, and graphite oxide as the precursors and NaOH as the mineralizer. Microsized Zn2SnO4 crystals with an octahedral shape are firmly confined by the graphene sheets, forming a unique hybrid structure. The confining effect of graphene leads to a more homogeneous size distribution of Zn2SnO4 crystals in Zn2SnO4/G than in bare Zn2SnO4. The introduction of graphene also brings an improved Li-storage performance for Zn2SnO4 due to the combined buffering, conducting, and confining effects of graphene. After being cycled at 200 mA/g for 50 times, Zn2SnO4/G can still keep a charge capacity of 326 mAh/g, while for bare Zn2SnO4, its charge capacity drops to only 100 mAh/g after the same cycles.

Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 24 , 28 December 2012 , pp. 3096 - 3102
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Idota, Y., Kubota, T., Matsufuji, A., Maekawa, Y., and Miyasaka, T.: Tin-based amorphous oxide: A high-capacity lithium-ion-storage material. Science 276, 1395 (1997).CrossRefGoogle Scholar
Courtney, I.A. and Dahn, J.R.: Electrochemical and in situ x-ray diffraction studies of the reaction of lithium with tin oxide composite. J. Electrochem. Soc. 144, 2045 (1997).CrossRefGoogle Scholar
Huggins, R.A.: Lithium alloy negative electrodes. J. Power Sources 81–82, 13 (1999).CrossRefGoogle Scholar
Li, H., Huang, X.J., and Chen, L.Q.: Anodes based on oxide materials for lithium rechargeable batteries. Solid State Ionics 123, 189 (1999).CrossRefGoogle Scholar
Wang, H.B., Pan, Q.M., Cheng, Y.X., Zhao, J.W., and Yin, G.P.: Evaluation of ZnO nanorod arrays with dandelion-like morphology as negative electrodes for lithium-ion batteries. Electrochim. Acta 54, 2851 (2009).CrossRefGoogle Scholar
Sharma, Y., Sharma, N., Subba Rao, G.V., and Chowdari, B.V.R.: Nanophase ZnCo2O4 as a high performance anode material for Li-ion batteries. Adv. Funct. Mater. 1728, 2855 (2007).CrossRefGoogle Scholar
Xiao, L.F., Zhao, Y.Q., Yin, J., and Zhang, L.Z.: Clewlike ZnV2O4 hollow spheres: Nonaqueous sol-gel synthesis, formation mechanism, and lithium storage properties. Chem. Eur. J. 15, 9442 (2009).CrossRefGoogle ScholarPubMed
Wang, G., Gao, X.P., and Shen, P.W.: Hydrothermal synthesis of Co2SnO4 nanocrystals as anode materials for Li-ion batteries. J. Power Sources 192, 719 (2009).CrossRefGoogle Scholar
Guo, X.W., Lu, X., Fang, X.P., Mao, Y., Wang, Z.X., Chen, L.Q., Xu, X.X., Yang, H., and Liu, Y.N.: Lithium storage in hollow spherical ZnFe2O4 as anode materials for lithium ion. Electrochem. Commun. 12, 847 (2010).CrossRefGoogle Scholar
Fen, T.P., Yogesh, S., and Snellius, P.S.: Nanoweb anodes composed of one-dimensional, high aspect ratio, size tunable electrospun ZnFe2O4 nanofibers for lithium ion batteries. J. Mater. Chem. 21, 14999 (2011).Google Scholar
Lavela, P. and Tirado, J.L.: CoFe2O4 and NiFe2O4 synthesized by sol-gel procedures for their use as anode materials for Li ion batteries. J. Power Sources 172, 379 (2007).CrossRefGoogle Scholar
Deng, Y.F., Zhang, Q.M., Tang, S.D., Zhang, L.T., Deng, S.N., Shi, Z.C., and Chen, G.H.: One-pot synthesis of ZnFe2O4/C hollow spheres as superior anode materials for lithium ion batteries. Chem. Commun. 47, 6828 (2011).CrossRefGoogle ScholarPubMed
Qi, Y., Du, N., Zhang, H., Wu, P., and Yang, D.R.: Synthesis of Co2SnO4@C core–shell nanostructures with reversible lithium storage. J. Power Sources 196, 10234 (2011).CrossRefGoogle Scholar
Wang, G., Liu, Z.Y., and Liu, P.: Co2SnO4–multiwalled carbon nanotubes composite as a highly reversible anode material for lithium-ion batteries. Electrochim. Acta 56, 9515 (2011).CrossRefGoogle Scholar
Belliard, F., Connor, P.A., and Irvine, J.T.S.: Novel tin oxide-based anodes for Li-ion batteries. Solid State Ionics 135, 163 (2000).CrossRefGoogle Scholar
Rong, A., Gao, X.P., Li, G.R., Yan, T.Y., Zhu, H.Y., Qu, J.Q., and Song, D.Y.: Hydrothermal synthesis of Zn2SnO4 as anode materials for Li-ion battery. J. Phys. Chem. B 110, 14754 (2006).CrossRefGoogle ScholarPubMed
Zheng, X.Z., Li, Y.F., Xu, Y.X., Hong, Z.S., and Wei, M.D.: Metal-organic frameworks: Promising materials for enhancing electrochemical properties of nanostructured Zn2SnO4 anode in Li-ion batteries. CrystEngComm 14, 2112 (2012).CrossRefGoogle Scholar
Chen, H.Y., Wang, J.X., Yu, H.C., Yang, H.X., Xie, S.S., and Li, J.Q.: Transmission electron microscopy study of pseudoperiodically twinned Zn2SnO4 nanowires J. Phys. Chem. B 109, 2573 (2005).CrossRefGoogle ScholarPubMed
Nikolić, N., Srećković, T., and Ristić, M.M.: The influence of mechanical activation on zinc stannate spinel formation. J. Eur. Ceram. Soc. 21, 2071 (2001).CrossRefGoogle Scholar
Baruah, S. and Dutta, J.: Zinc stannate nanostructures: Hydrothermal synthesis. Sci. Technol. Adv. Mater. 12, 013004 (2011).CrossRefGoogle ScholarPubMed
Li, D., Müller, M.B., Gilje, S., Kaner, R.B., and Wallace, G.G.: Processable aqueous dispersions of graphene nanosheets. Nat. Nanotechnol. 3, 101 (2008).CrossRefGoogle ScholarPubMed
Hummers, W.S. and Offeman, R.E.: Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339 (1958).CrossRefGoogle Scholar
Zhang, C.M., Zhu, J.X., Rui, X.H., Chen, J., Sim, D.H., Shi, W.H., Hng, H.H., Lim, T.M., and Yan, Q.Y.: Synthesis of hexagonal-symmetry alpha-iron oxyhydroxide crystals using reduced graphene oxide as a surfactant and their Li storage properties. CrystEngComm 14, 147 (2012).CrossRefGoogle Scholar
Shin, H.J., Kim, K.K., Benayad, A., Yoon, S.M., Park, H.K., Jung, I.S., Jin, M.H., Jeong, H.K., Kim, J.M., Choi, J.Y., and Lee, Y.H.: Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance. Adv. Funct. Mater. 19, 1987 (2009).CrossRefGoogle Scholar
Miyauchi, M., Liu, Z.F., Zhao, Z.G., Anandan, S., and Hara, K.: Single crystalline zinc stannate nanoparticles for efficient photo-electrochemical devices. Chem. Commun. 46, 1529 (2010).CrossRefGoogle ScholarPubMed
Zeng, J., Xin, M.D., Li, K.W., Wang, H., Yan, H., and Zhang, W.J.: Transformation process and photocatalytic activities of hydrothermally synthesized Zn2SnO4 nanocrystals. J. Phys. Chem. C 112, 4159 (2008).CrossRefGoogle Scholar
Zhu, H.L., Yang, D.R., Yu, G.X., Zhang, H., Jin, D.L., and Yao, K.H.: Hydrothermal synthesis of Zn2SnO4 nanorods in the diameter regime of sub-5 nm and their properties. J. Phys. Chem. B 110, 7631 (2006).CrossRefGoogle ScholarPubMed
Lana-Villarreal, T., Boschloo, G., and Hagfeldt, A.: Nanostructured zinc stannate as semiconductor working electrodes for dye-sensitized solar cells. J. Phys. Chem. C 111, 5549 (2007).CrossRefGoogle Scholar
Ji, G., Ma, Y., and Lee, J.Y.: Mitigating the initial capacity loss (ICL) problem in high-capacity lithium ion battery anode materials. J. Mater. Chem. 21, 9819 (2011).CrossRefGoogle Scholar
Seonga, I.W., Kim, K.T., and Yoon, W.Y.: Electrochemical behavior of a lithium-pre-doped carbon-coated silicon monoxide anode cell. J. Power Sources 189, 511 (2009).CrossRefGoogle Scholar
Liu, S.Y., Xie, J., Zheng, Y.X., Cao, G.S., Zhu, T.J., and Zhao, X.B.: Nanocrystal manganese oxide (Mn3O4, MnO) anchored on graphite nanosheet with improved electrochemical Li-storage properties. Electrochim. Acta 66, 271 (2012).CrossRefGoogle Scholar
Stoller, M.D., Park, S., Zhu, Y.W., An, J.H., and Ruoff, R.S.: Graphene-based ultracapacitor. Nano Lett. 8, 3498 (2008).CrossRefGoogle Scholar
Lee, C., Wei, X.D., Kysar, J.W., and Hone, J.: Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321, 385 (2008).CrossRefGoogle ScholarPubMed
Park, S., An, J.H., Jung, I.W., Piner, R.D., An, S.J., Li, X.S., Velamakanni, A., and Ruoff, R.S.: Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents. Nano Lett. 9, 1593 (2009).CrossRefGoogle Scholar
Liang, Y.F., Huang, S.T., and Yang, L.: Many-electron effects on optical absorption spectra of strained graphene. J. Mater. Res. 27, 403 (2012).CrossRefGoogle Scholar
Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieva, I.V., and Firsov, A.A.: Electric filed effect in atomically thin carbon films. Science 306, 666 (2004).CrossRefGoogle Scholar
Yuan, W.S., Tian, Y.W., and Liu, G.Q.: Synthesis and electrochemical properties of pure phase Zn2SnO4 and composite Zn2SnO4/C. J. Alloys Compd. 506, 683 (2010).CrossRefGoogle Scholar
Hou, X.H., Cheng, Q., Bai, Y., and Zhang, W.F.: Preparation and electrochemical characterization of Zn2SnO4 as anode materials for lithium ion batteries. Solid State Ionics 181, 631 (2010).CrossRefGoogle Scholar
Feng, N., Peng, S.L., Sun, X.L., Qiao, L., Li, X.W., Wang, P., Hu, D.K., and He, D.Y.: Synthesis of monodisperse single crystal Zn2SnO4 cubes with high lithium storage capacity. Mater. Lett. 76, 66 (2012).CrossRefGoogle Scholar