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Hydrogen generation from pure water using Al–Sn powders consolidated through high-pressure torsion

Published online by Cambridge University Press:  03 March 2016

Fan Zhang ,
Ryo Yonemoto ,
Makoto Arita  and
Zenji Horita
Fan Zhang*
Affiliation:
Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan; WPI, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka 819-0395, Japan
Ryo Yonemoto
Affiliation:
Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan
Makoto Arita
Affiliation:
Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan
Zenji Horita
Affiliation:
Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan; WPI, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka 819-0395, Japan
*
a)Address all correspondence to this author. e-mail: zhang@zaiko6.zaiko.kyushu-u.ac.jp
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Abstract

Al–Sn binary alloys are fabricated by powder consolidation using high-pressure torsion (HPT). The HPT-processed samples are immersed in pure water and hydrogen generation behavior is investigated with respect to the imposed strain through the HPT processing at a selected temperature in the range of 297–333 K. Microstructures of HPT-processed alloys are analyzed by x-ray diffraction, transmission electron microscopy (TEM), electron probe microanalysis (EPMA) and electron back scattered diffraction (EBSD) analysis. Results show that it is important to add more than 60 wt% of Sn to activate hydrogen generation from the Al–Sn alloys in pure water. TEM and EBSD images reveal significant grain refinement while EPMA results exhibit homogenous distribution of elements achieved by HPT. The grain refinement and distribution of elements attained by HPT processing influence greatly the hydrogen generation rate and yield of the alloys. An Al–80 wt% Sn alloy with an average grain size of ∼270 nm exhibits the highest hydrogen yield and generation rate in pure water at 333 K.

Keywords

hydrogen productionAl–Sn alloyhigh-pressure torsionAl–water reaction
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 6 , 28 March 2016 , pp. 775 - 782
Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Li, Q. and Bjerrum, N.J.: Aluminum as anode for energy storage and conversion: A review. J. Power Sources 110(1), 1 (2002).Google Scholar
Nestoridi, M., Pletcher, D., Wood, R.J.K., Wang, S., Jones, R.L., Stokes, K.R., and Wilcock, I.: The study of aluminium anodes for high power density Al/air batteries with brine electrolytes. J. Power Sources 178(1), 445 (2008).Google Scholar
Qi, G.T., Qiu, Y.B., Zhao, Y.N., and Cai, Q.Z.: The attack initiation of Al–Zn–In–Sn anode by the segregation concentrating Zn, Sn and In. Mater. Corros. 60(3), 206 (2009).Google Scholar
Bessone, J.B., Flamini, D.O., and Saidman, S.B.: Comprehensive model for the activation mechanism of Al–Zn alloys produced by indium. Corros. Sci. 47(1), 95 (2005).CrossRefGoogle Scholar
Wang, H.Z., Leung, D.Y.C., Leung, M.K.H., and Ni, M.: A review on hydrogen production using aluminum and aluminum alloys. Renewable Sustainable Energy Rev. 13(4), 845 (2009).Google Scholar
Elitzur, S., Rosenband, V., and Gany, A.: Study of hydrogen production and storage based on aluminum–water reaction. Int. J. Hydrogen Energy 39(12), 6328 (2014).Google Scholar
Huang, X., Gao, T., Pan, X., Wei, D., Lv, C., Qin, L., and Huang, Y.: A review: Feasibility of hydrogen generation from the reaction between aluminum and water for fuel cell applications. J. Power Sources 229, 133 (2013).Google Scholar
Chen, X., Liu, L., Peter, Y.Y., and Mao, S.S.: Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science 331(6018), 746 (2011).Google Scholar
Chen, X., Shen, S., Guo, L., and Mao, S.S.: Semiconductor-based photocatalytic hydrogen generation. Chem. Rev. 110(11), 6503 (2010).CrossRefGoogle ScholarPubMed
Chen, X., Li, C., Grätzel, M., Kostecki, R., and Mao, S.S.: Nanomaterials for renewable energy production and storage. Chem. Soc. Rev. 41(23), 7909 (2012).CrossRefGoogle ScholarPubMed
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., and Chen, X.: Engineering heterogeneous semiconductors for solar water splitting. J. Mater. Chem. A 3(6), 2485 (2015).Google Scholar
Yuan, J., Wen, J., Zhong, Y., Li, X., Fang, Y., Zhang, S., and Liu, W.: Enhanced photocatalytic H2 evolution over noble-metal-free NiS cocatalyst modified CdS nanorods/gC3N4 heterojunctions. J. Mater. Chem. A 3(35), 18244 (2015).Google Scholar
Ran, J., Zhang, J., Yu, J., Jaroniec, M., and Qiao, S.Z.: Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting. Chem. Soc. Rev. 43(22), 7787 (2014).Google Scholar
Khaselev, O. and Turner, J.A.: A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting. Science 280(5362), 425 (1998).Google Scholar
Reece, S.Y., Hamel, J.A., Sung, K., Jarvi, T.D., Esswein, A.J., Pijpers, J.J., and Nocera, D.G.: Wireless solar water splitting using silicon-based semiconductors and earth-abundant catalysts. Science 334(6056), 645 (2011).Google Scholar
Zheng, Y., Jiao, Y., Li, L.H., Xing, T., Chen, Y., Jaroniec, M., and Qiao, S.Z.: Toward design of synergistically active carbon-based catalysts for electrocatalytic hydrogen evolution. ACS Nano 8(5), 5290 (2014).Google Scholar
Zheng, Y., Jiao, Y., Zhu, Y., Li, L.H., Han, Y., Chen, Y., Du, A., Jaroniec, M., and Qiao, S.Z.: Hydrogen evolution by a metal-free electrocatalyst. Nat. Commun. 5, 1 (2014).Google Scholar
Chen, S., Duan, J., Tang, Y., Jin, B., and Qiao, S.Z.: Molybdenum sulfide clusters-nitrogen-doped graphene hybrid hydrogel film as an efficient three-dimensional hydrogen evolution electrocatalyst. Nano Energy 11, 11 (2015).Google Scholar
Duan, J., Chen, S., Jaroniec, M., and Qiao, S.Z.: Porous C3N4 nanolayers@N-graphene films as catalyst electrodes for highly efficient hydrogen evolution. ACS Nano 9(1), 931 (2015).CrossRefGoogle ScholarPubMed
Zheng, Y., Jiao, Y., Jaroniec, M., and Qiao, S.Z.: Advancing the electrochemistry of the hydrogen-evolution reaction through combining experiment and theory. Angew. Chem., Int. Ed. 54(1), 52 (2015).Google Scholar
Rosen, M.A.: Advances in hydrogen production by thermochemical water decomposition: a review. Energy 35(2), 1068 (2010).Google Scholar
Chin, H.L., Chen, Z.S., and Chou, C.P.: Fedbatch operation using Clostridium acetobutylicum suspension culture as biocatalyst for enhancing hydrogen production. Biotechnol. Prog. 19(2), 383 (2003).Google Scholar
Wang, H., Leung, D.Y.C., and Leung, M.K.H.: Energy analysis of hydrogen and electricity production from aluminum-based processes. Appl. Energy 90(1), 100 (2012).Google Scholar
Fan, M., Xu, F., and Sun, L.: Studies on hydrogen generation characteristics of hydrolysis of the ball milling Al-based materials in pure water. Int. J. Hydrogen Energy 32(14), 2809 (2007).Google Scholar
Ziebarth, J.T., Woodall, J.M., Kramer, R.A., and Choi, G.: Liquid phase-enabled reaction of Al–Ga and Al–Ga–In–Sn alloys with water. Int. J. Hydrogen Energy 36(9), 5271 (2011).Google Scholar
Wang, H., Chang, Y., Dong, S., Lei, Z., Zhu, Q., Luo, P., and Xie, Z.: Investigation on hydrogen production using multicomponent aluminum alloys at mild conditions and its mechanism. Int. J. Hydrogen Energy 38(3), 1236 (2013).Google Scholar
Ilyukhina, A.V., Ilyukhin, A.S., and Shkolnikov, E.I.: Hydrogen generation from water by means of activated aluminum. Int. J. Hydrogen Energy 37(21), 16382 (2012).CrossRefGoogle Scholar
Mahmoodi, K. and Alinejad, B.: Enhancement of hydrogen generation rate in reaction of aluminum with water. Int. J. Hydrogen Energy 35(11), 5227 (2010).CrossRefGoogle Scholar
Valiev, R.Z., Islamgaliev, R.K., and Alexandrov, I.V.: Bulk nanostructured materials from severe plastic deformation. Prog. Mater. Sci. 45(2), 103 (2000).Google Scholar
Valiev, R.Z., Estrin, Y., Horita, Z., Langdon, T.G., Zehetbauer, M.J., and Zhu, Y.T.: Producing bulk ultrafine-grained materials by severe plastic deformation. JOM 58(4), 33 (2006).CrossRefGoogle Scholar
Ouyang, L., Xu, Y., Dong, H., Sun, L., and Zhu, M.: Production of hydrogen via hydrolysis of hydrides in Mg–La system. Int. J. Hydrogen Energy 34(24), 9671 (2009).CrossRefGoogle Scholar
Zou, M-S., Yang, R-J., Guo, X-Y., Huang, H-T., He, J-Y., and Zhang, P.: The preparation of Mg-based hydro-reactive materials and their reactive properties in seawater. Int. J. Hydrogen Energy 36(11), 6478 (2011).CrossRefGoogle Scholar
Fan, M-Q., Xu, F., Sun, L-X., Zhao, J-N., Jiang, T., and Li, W-X.: Hydrolysis of ball milling Al–Bi–hydride and Al–Bi–salt mixture for hydrogen generation. J. Alloys Compd. 460(1–2), 125 (2008).CrossRefGoogle Scholar
Hu, H., Qiao, M., Pei, Y., Fan, K., Li, H., Zong, B., and Zhang, X.: Kinetics of hydrogen evolution in alkali leaching of rapidly quenched Ni–Al alloy. Appl. Catal., A 252(1), 173 (2003).Google Scholar
Fan, M.Q., Sun, L.X., and Xu, F.: Hydrogen production for micro-fuel-cell from activated Al–Sn–Zn–X (X: hydride or halide) mixture in water. Renewable Energy 36(2), 519 (2011).Google Scholar
Hu, X., Zhu, G., Zhang, Y., Wang, Y., Gu, M., Yang, S., Song, P., Li, X., Fang, H., Jiang, G., and Wang, Z.: Hydrogen generation through rolling using Al–Sn alloy. Int. J. Hydrogen Energy 37(15), 11012 (2012).Google Scholar
Ito, Y. and Horita, Z.: Microstructural evolution in pure aluminum processed by high-pressure torsion. Mater. Sci. Eng., A 503(1–2), 32 (2009).Google Scholar
Edalati, K. and Horita, Z.: Significance of homologous temperature in softening behavior and grain size of pure metals processed by high-pressure torsion. Mater. Sci. Eng., A 528(25–26), 7514 (2011).CrossRefGoogle Scholar
Alhamidi, A., Edalati, K., Horita, Z., Hirosawa, S., Matsuda, K., and Terada, D.: Softening by severe plastic deformation and hardening by annealing of aluminum–zinc alloy: Significance of elemental and spinodal decompositions. Mater. Sci. Eng., A 610, 17 (2014).Google Scholar