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Improvement of carbon nanocoil purity achieved by supplying catalyst molecules from the vapor phase in chemical vapor deposition

Published online by Cambridge University Press:  26 September 2014

Yoshiyuki Suda ,
Yuichi Ishii ,
Tatsuki Miki ,
Koji Maruyama ,
Hideto Tanoue ,
Hirofumi Takikawa ,
Hitoshi Ue ,
Kazuki Shimizu  and
Yoshito Umeda
Yoshiyuki Suda*
Affiliation:
Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan
Yuichi Ishii
Affiliation:
Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan
Tatsuki Miki
Affiliation:
Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan
Koji Maruyama
Affiliation:
Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan
Hideto Tanoue
Affiliation:
Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan
Hirofumi Takikawa
Affiliation:
Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan
Hitoshi Ue
Affiliation:
Fuji Research Laboratory, Tokai Carbon Co., Ltd., Oyama, Shizuoka 410-1431, Japan
Kazuki Shimizu
Affiliation:
Development Department, Shonan Plastic Manufacturing Co., Ltd., Hiratsuka, Kanagawa 254-0807, Japan
Yoshito Umeda
Affiliation:
Toho Gas Co., Ltd., Tokai, Aichi 476-8501, Japan
*
a)Address all correspondence to this author. e-mail: suda@ee.tut.ac.jp
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Abstract

We investigated how changes in the method of supplying Sn and Fe carbon nanocoil (CNC) catalysts affected the results of chemical vapor deposition. The Sn/Fe catalysts were supplied using the following four materials: a thin Sn film, a drop-coated solution of Fe2O3, tetramethyltin (TMT) vapor, and ferrocene vapor. The CNC purity was evaluated using scanning electron microscopy. The CNC purity in the overall carbon deposit was also evaluated by analyzing the cross-section of the deposit. The CNC purity averaged over the overall carbon deposit was increased 1.5-fold by the TMT supply. We obtained a maximum CNC purity of 72% using a combination of TMT and ferrocene vapors, with Sn/Fe deposition on the substrate. Energy-dispersive x-ray spectroscopy analysis of the catalyst nanoparticles in the tips of the CNCs and carbon nanofibers (CNFs) revealed that there was a large difference in the Sn/Fe molar ratios for the angular- and round-type CNFs.

Keywords

catalyticchemical vapor deposition (CVD) (deposition)Sn
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 18 , 28 September 2014 , pp. 2179 - 2187
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Motojima, S., Kawaguchi, M., Nozaki, K., and Iwanaga, H.: Growth of regularly coiled carbon filaments by Ni catalyzed pyrolysis of acetylene, and their morphology and extension characteristics. Appl. Phys. Lett. 56, 321 (1990).Google Scholar
Amelinckx, S., Zhang, X.B., Bernaerts, D., Zhang, X.F., Ivanov, V., and Nagy, J.B.: A formation mechanism for catalytically grown helix-shaped graphite nanotubes. Science 256, 635 (1994).CrossRefGoogle Scholar
Hayashida, T., Pan, L., and Nakayama, Y.: Mechanical and electrical properties of carbon tubule nanocoils. Phys. B 323, 352 (2002).CrossRefGoogle Scholar
Katsumata, T., Fujimura, Y., Nagayama, M., Tabata, H., Takikawa, H., Hibi, Y., Sakakibara, T., and Itoh, S.: Synthesis of twisted carbon nanofiber by catalytic CVD method. Trans. Mater. Res. Soc. Jpn. 29, 501 (2004).Google Scholar
Wang, G., Gao, Z., Tang, S., Chen, C., Duan, F., Zhao, S., Lin, S., Feng, Y., Zhou, L., and Qin, Y.: Microwave absorption properties of carbon nanocoils coated with highly controlled magnetic materials by atomic layer deposition. ACS Nano 6, 11009 (2012).Google Scholar
Reddy, A.L.M., Jafri, R.I., Jha, N., Ramaprabhu, S., and Ajayan, P.M.: Carbon nanocoils for multi-functional energy applications. J. Mater. Chem. 21, 16103 (2011).Google Scholar
Barranco, V., Celorrio, V., Lazaro, M.J., and Rojo, J.M.: Carbon nanocoils as unusual electrode materials for supercapacitors. J. Electrochem. Soc. 159, A464 (2012).Google Scholar
Qin, Y., Kim, Y., Zhang, L., Lee, S-M., Yang, R.B., Pan, A., Mathwig, K., Alexe, M., Gösele, U., and Knez, M.: Preparation and elastic properties of helical nanotubes obtained by atomic layer deposition with carbon nanocoils as templates. Small 6, 910 (2010).Google Scholar
Yokota, M., Shinohara, Y., Kawabata, T., Takimoto, K., Suda, Y., Oke, S., Takikawa, H., Fujimura, Y., Yamaura, T., Itoh, S., Ue, H., and Morioki, M.: Splitting and flattening of helical carbon nanofibers by acid treatment. J. Nanosci. Nanotechnol. 10, 3910 (2010).CrossRefGoogle ScholarPubMed
Li, D. and Pan, L.: Necessity of base fixation for helical growth of carbon nanocoils. J. Mater. Res. 27, 431 (2012).CrossRefGoogle Scholar
Hirahara, K. and Nakayama, Y.: The effect of a tin oxide buffer layer for the high yield synthesis of carbon nanocoils. Carbon 56, 264 (2013).Google Scholar
Chang, N-K. and Chang, S-H.: High-yield synthesis of carbon nanocoils on stainless steel. Carbon 46, 1106 (2008).CrossRefGoogle Scholar
Bi, H., Kou, K-C., Ostrikov, K., and Wang, Z-C.: High-yield atmospheric-pressure CVD of highly-uniform carbon nanocoils using Co-P catalyst nanoparticles prepared by electroless plating. J. Alloys Compd. 484, 860 (2009).Google Scholar
Qi, X., Zhong, W., Deng, Y., Au, C., and Du, Y.: Synthesis of helical carbon nanotubes, worm-like carbon nanotubes and nanocoils at 450°C and their magnetic properties. Carbon 48, 365 (2010).Google Scholar
Li, D., Pan, L., Qian, J., and Liu, D.: Highly efficient synthesis of carbon nanocoils by catalyst particles prepared by a sol-gel method. Carbon 48, 170 (2010).Google Scholar
Wang, W., Yang, K., Gaillard, J., Bandaru, P.R., and Rao, A.M.: Rational synthesis of helically coiled carbon nanowires and nanotubes through the use of tin and indium catalysts. Adv. Mater. 20, 179 (2008).Google Scholar
Cervantes-Sodi, F., Vilatela, J.J., Jimenez-Rodriguez, J.A., Reyes-Gutiérrez, L.G., Rosas-Meléndez, S., Íñiguez-Rábago, A., Ballesteros-Villarreal, M., Palacios, E., Reiband, G., and Terrones, M.: Carbon nanotube bundles self-assembled in double helix microstructures. Carbon 50, 3688 (2012).Google Scholar
Li, D-W., Pan, L-J., Liu, D-P., and Yu, N-S.: Relationship between geometric structures of catalyst particles and growth of carbon nanocoils. Chem. Vap. Deposition 16, 166 (2010).CrossRefGoogle Scholar
Qian, J., Pan, L., Li, D., Yu, N., and Liu, D.: Formation of catalyst particles for carbon nanocoil growth. J. Nanosci. Nanotechnol. 10, 7366 (2010).Google Scholar
Li, D. and Pan, L.: Growth of carbon nanocoils using Fe–Sn–O catalyst film prepared by a spin-coating method. J. Mater. Res. 26, 2024 (2011).Google Scholar
Pan, L., Hayashida, T., Harada, A., and Nakayama, Y.: Effects of iron and indium tin oxide on the growth of carbon tubule nanocoils. Phys. B 323, 350 (2002).Google Scholar
Waring, C.E. and Horton, W.S.: The kinetics of the thermal decomposition of gaseous tetramethyltin. J. Am. Chem. Soc. 67, 540 (1945).Google Scholar
Dyagileva, L.M., Mar'in, V.P., Tsyganova, E.I., and Razuvaev, G.A.: Reactivity of the first transition row metallocenes in thermal decomposition reaction. J. Organomet. Chem. 175, 63 (1979).Google Scholar
Motojima, S. and Iwanaga, H.: Preparation of micro-coiled TiC fibers by metal impurity-activated chemical vapor deposition. Mater. Sci. Eng., B 34, 159 (1995).CrossRefGoogle Scholar
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