Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-10T16:58:27.710Z Has data issue: false hasContentIssue false
  • English
  • Français

Interfacial polyelectrolyte complexation spinning of graphene/cellulose nanofibrils for fiber-shaped electrodes

Published online by Cambridge University Press:  08 January 2020

Yufan Lin ,
Shengping Wen ,
Xiangfang Peng ,
Yuhua Cai ,
Lihong Geng  and
Binyi Chen
Yufan Lin
Affiliation:
Department of Industrial Equipment and Control Engineering, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
Shengping Wen
Affiliation:
Department of Industrial Equipment and Control Engineering, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
Xiangfang Peng
Affiliation:
Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou, Fujian 350108, China
Yuhua Cai
Affiliation:
Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou, Fujian 350108, China
Lihong Geng*
Affiliation:
Department of Materials Science and Engineering, Fujian University of Technology, Fuzhou, Fujian 350108, China
Binyi Chen*
Affiliation:
Department of Industrial Equipment and Control Engineering, School of Mechanical & Automotive Engineering, South China University of Technology, Guangzhou, Guangdong 510640, China
*
a)Address all correspondence to these authors. e-mail: glhfjut@fjut.edu.cn
b)e-mail: mebychen@scut.edu.cn
Get access

Abstract

Graphene-based flexible and wearable supercapacitors have been produced by wet spinning, in which organic solvent coagulating bath was prerequisite and spacers were usually incorporated to improve the electrochemical property but sacrificing the mechanical property. In this work, a nonorganic solvent spinning technology named as interfacial polyelectrolyte complexation (IPC), which was based on the spontaneous self-assembly of two oppositely charged polyelectrolyte solutions/suspensions to form continuous fibers on drawing in their interfaces, was proposed to fabricate graphene fiber–shaped electrodes for supercapacitors. Due to the excellent mechanical performance and hydrophilicity, cellulose nanofibrils (CNFs) were added to serve as an efficient reinforcing agent and spacer of graphene fiber electrodes. Consequently, the mechanical performance and specific capacitance of the fibers were improved but electrical conductivity was declined. Taking overall consideration, CNF/rGO60 fiber electrode possessed a superior integrated performance with a capacitance of 182.6 F/g, tensile strength of 480 MPa, and electrical conductivity of 5538.7 S/m. The IPC spinning provided an environmentally friendly strategy for the fabrication of fiber-shaped functional devices.

Keywords

graphene fiberscellulose nanofibrilsinterfacial polyelectrolyte complexationmechanical performanceelectrochemical property
Type
Article
Information
Journal of Materials Research , Volume 35 , Issue 2 , 28 January 2020 , pp. 122 - 131
Check for updates
Copyright
Copyright © Materials Research Society 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Minjeong, H., Jonghwa, P., Youngoh, L., and Hyunhyub, K.: Triboelectric generators and sensors for self-powered wearable electronics. ACS Nano 9, 4 (2015).Google Scholar
Wei, Z., Lin, S., Qiao, L., Song, C., Fei, W., and Xiao-Ming, T.: Fiber-based wearable electronics: A review of materials, fabrication, devices, and applications. Adv. Mater. 26, 31 (2014).Google Scholar
Cai, X., Peng, M., Yu, X., Fu, Y., and Zou, D.: Flexible planar/fiber-architectured supercapacitors for wearable energy storage. J. Mater. Chem. C 2, 7 (2014).CrossRefGoogle Scholar
Shao, Y., El-Kady, M.F., Wang, L.J., Zhang, Q., Li, Y., Wang, H., Mousavi, M.F., and Kaner, R.B.: Graphene-based materials for flexible supercapacitors. ChemInform 46, 30 (2015).CrossRefGoogle Scholar
Yu, D., Goh, K., Wang, H., Wei, L., Jiang, W., Zhang, Q., Dai, L., and Chen, Y.: Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage. Nat. Nanotechnol. 9, 7 (2014).CrossRefGoogle ScholarPubMed
Yu, D., Zhai, S., Jiang, W., Goh, K., Wei, L., Chen, X., Jiang, R., and Chen, Y.: Transforming pristine carbon fiber tows into high performance solid-state fiber supercapacitors. Adv. Mater. 27, 33 (2015).CrossRefGoogle ScholarPubMed
Guoping, W., Lei, Z., and Jiujun, Z.: A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41, 2 (2012).Google Scholar
Ramadoss, A., Yoon, K.Y., Kwak, M.J., Kim, S.I., Ryu, S.T., and Jang, J.H.: Fully flexible, lightweight, high performance all-solid-state supercapacitor based on 3-dimensional-graphene/graphite-paper. J. Power Sources 337, 159 (2017).CrossRefGoogle Scholar
Sakka, M.A., Gualous, H., and Mierlo, J.V.: Characterization of supercapacitors matrix. Electrochim. Acta 55, 25 (2010).CrossRefGoogle Scholar
Simon, P. and Gogotsi, Y.: Materials for electrochemical capacitors. Nat. Mater. 7, 11 (2008).CrossRefGoogle ScholarPubMed
Yan, J., Qian, W., Tong, W., and Fan, Z.: Supercapacitors: Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities. Adv. Energy Mater. 4, 4 (2014).Google Scholar
Vangari, M., Pryor, T., and Jiang, L.: Supercapacitors: Review of materials and fabrication methods. J. Energy Eng. 139, 2 (2013).CrossRefGoogle Scholar
Raymundo-Piñero, E., Leroux, F., and Béguin, F.: A high-performance carbon for supercapacitors obtained by carbonization of a seaweed biopolymer. Adv. Mater. 18, 14 (2010).Google Scholar
Wang, K., Meng, Q., Zhang, Y., Wei, Z., and Miao, M.: High-performance two-ply yarn supercapacitors based on carbon nanotubes and polyaniline nanowire arrays. Adv. Mater. 25, 10 (2013).Google ScholarPubMed
Yue, H., Huhu, C., Fei, Z., Nan, C., Lan, J., Zhihai, F., and Liangti, Q.: All-in-one graphene fiber supercapacitor. Nanoscale 6, 12 (2014).Google Scholar
Yuning, M., Yang, Z., Chuangang, H., Huhu, C., Yue, H., Zhipan, Z., Gaoquan, S., and Liangti, Q.: All-graphene core-sheath microfibers for all-solid-state, stretchable fibriform supercapacitors and wearable electronic textiles. Adv. Mater. 25, 16 (2013).Google Scholar
Pumera, M.: Graphene-based nanomaterials for energy storage. Energy Environ. Sci. 4, 3 (2011).CrossRefGoogle Scholar
Stoller, M.D., Park, S., Zhu, Y., An, J., and Ruoff, R.S.: Graphene-based ultracapacitors. Nano Lett. 8, 10 (2008).CrossRefGoogle ScholarPubMed
Yang, X. and Li, D.: Electrolyte-mediated dense integration of graphene materials for compact capacitive energy storage. Science 341, 6145 (2013).CrossRefGoogle Scholar
Xu, Z. and Gao, C.: Graphene chiral liquid crystals and macroscopic assembled fibres. Nat. Commun. 2, 1 (2011).CrossRefGoogle ScholarPubMed
Huang, T., Zheng, B., Kou, L., Gopalsamy, K., Xu, Z., Gao, C., Meng, Y., and Wei, Z.: Flexible high performance wet-spun graphene fiber supercapacitors. RSC Adv. 3, 46 (2013).CrossRefGoogle Scholar
Huang, T., Zheng, B., Liu, Z., Kou, L., and Gao, C.: High rate capability supercapacitors assembled from wet-spun graphene films with a CaCO3 template. J. Mater. Chem. A 3, 5 (2015).Google Scholar
Li, Z., Huang, T., Gao, W., Xu, Z., Chang, D., Zhang, C., and Gao, C.: Hydrothermally activated graphene fiber fabrics for textile electrodes of supercapacitors. ACS Nano 11, 11 (2017).CrossRefGoogle ScholarPubMed
Tieqi, H., Xingyuan, C., Shengying, C., Qiuyan, Y., Hao, C., Yingjun, L., Karthikeyan, G., Zhen, X., Weiwei, G., and Chao, G.: Tri-high designed graphene electrodes for long cycle-life supercapacitors with high mass loading. Energy Storage Mater. 17, 349 (2019).Google Scholar
Dong, Z., Jiang, C., Cheng, H., Zhao, Y., Shi, G., Jiang, L., and Qu, L.: Facile fabrication of light, flexible and multifunctional graphene fibers. Adv. Mater. 24, 14 (2012).CrossRefGoogle ScholarPubMed
Xu, Z., Sun, H., Zhao, X., and Gao, C.: Ultrastrong fibers assembled from giant graphene oxide sheets. Adv. Mater. 25, 2 (2013).Google ScholarPubMed
Chen, S., Ma, W., Cheng, Y., Weng, Z., Sun, B., Wang, L., Chen, W., Li, F., Zhu, M., and Cheng, H.M.: Scalable non-liquid-crystal spinning of locally aligned graphene fibers for high-performance wearable supercapacitors. Nano Energy 15, 642 (2015).CrossRefGoogle Scholar
Yu, Y., Sun, Y., Cao, C., Yang, S., Liu, H., Li, P., Huang, P., and Song, W.: Graphene-based composite supercapacitor electrodes with diethylene glycol as inter-layer spacer. J. Mater. Chem. A 2, 21 (2014).CrossRefGoogle Scholar
Kou, L., Huang, T., Zheng, B., Han, Y., Zhao, X., Gopalsamy, K., Sun, H., and Gao, C.: Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics. Nat. Commun. 5, 5 (2014).CrossRefGoogle ScholarPubMed
Sun, G., Liu, J., Zhang, X., Wang, X., Li, H., Yu, Y., Huang, W., Zhang, H., and Chen, P.: Fabrication of ultralong hybrid microfibers from nanosheets of reduced graphene oxide and transition-metal dichalcogenides and their application as supercapacitors. Angew. Chem. 53, 46 (2015).Google Scholar
Cheng, Q., Tang, J., Ma, J., Zhang, H., Shinya, N., and Qin, L.C.: Graphene and nanostructured MnO composite electrodes for supercapacitors. Carbon 49, 9 (2011).CrossRefGoogle Scholar
Yu, G., Hu, L., Vosgueritchian, M., Wang, H., Xie, X., Mcdonough, J.R., Cui, X., Cui, Y., and Bao, Z.: Solution-processed graphene/MnO2 nanostructured textiles for high-performance electrochemical capacitors. Nano Lett. 11, 7 (2011).CrossRefGoogle ScholarPubMed
Chen, G., Chen, T., Hou, K., Ma, W., Tebyetekerwa, M., Cheng, Y., Weng, W., and Zhu, M.: Robust, hydrophilic graphene/cellulose nanocrystal fiber-based electrode with high capacitive performance and conductivity. Carbon 127, 218 (2018).CrossRefGoogle Scholar
Xin, G., Zhu, W., Deng, Y., Cheng, J., Zhang, L.T., Chung, A.J., De, S., and Lian, J.: Microfluidics-enabled orientation and microstructure control of macroscopic graphene fibres. Nat. Nanotechnol. 14, 2 (2019).CrossRefGoogle ScholarPubMed
Zhen, X., Haiyan, S., Xiaoli, Z., and Chao, G.: Ultrastrong fibers assembled from giant graphene oxide sheets. Adv. Mater. 25, 2 (2013).Google Scholar
Xu, Z., Liu, Y., Zhao, X., Peng, L., Sun, H., Xu, Y., Ren, X., Jin, C., Xu, P., and Wang, M.: Ultrastiff and strong graphene fibers via full-scale synergetic defect engineering. Adv. Mater. 28, 30 (2016).Google ScholarPubMed
Jalili, R., Aboutalebi, S.H., Esrafilzadeh, D., Shepherd, R.L., Chen, J., Aminorroaya-Yamini, S., Konstantinov, K., Minett, A.I., Razal, J.M., and Wallace, G.G.: Graphene oxide: Scalable one-step wet-spinning of graphene fibers and yarns from liquid crystalline dispersions of graphene oxide: Towards multifunctional textiles. Adv. Funct. Mater. 23, 43 (2013).Google Scholar
Zhang, Y., Peng, J., Li, M., Saiz, E., Wolf, S.E., and Cheng, Q.: Bioinspired supertough graphene fiber through sequential interfacial interactions. ACS Nano 12, 9 (2018).Google ScholarPubMed
Zhang, K. and Liimatainen, H.: Hierarchical assembly of nanocellulose-based filaments by interfacial complexation. Small 14, 38 (2018).Google ScholarPubMed
Toivonen, M.S., Kurkisuonio, S., Wagermaier, W., Hynninen, V., Hietala, S., and Ikkala, O.: Interfacial polyelectrolyte complex spinning of cellulose nanofibrils for advanced bicomponent fibers. Biomacromolecules 18, 4 (2017).CrossRefGoogle ScholarPubMed
Nechyporchuk, O., Bordes, R., and Köhnke, T.: Wet spinning of flame-retardant cellulosic fibers supported by interfacial complexation of cellulose nanofibrils with silica nanoparticles. ACS Appl. Mater. Interfaces 9, 44 (2017).CrossRefGoogle ScholarPubMed
Grande, R., Trovatti, E., Carvalho, A.J., and Gandini, A.: Continuous microfiber drawing by interfacial charge complexation between anionic cellulose nanofibers and cationic chitosan. J. Mater. Chem. A 5, 25 (2017).CrossRefGoogle Scholar
Amaike, M., Senoo, Y., and Yamamoto, H.: Sphere, honeycomb, regularly spaced droplet and fiber structures of polyion complexes of chitosan and gellan. Macromol. Rapid Commun. 19, 6 (1998).3.0.CO;2-X>CrossRefGoogle Scholar
Clemons, C.: Nanocellulose in spun continuous fibers: A review and future outlook. J. Renewable Mater. 4, 5 (2016).Google Scholar
Wan, A.C., Cutiongco, M.F., Tai, B.C., Leong, M.F., Lu, H.F., and Yim, E.K.: Fibers by interfacial polyelectrolyte complexation–processes, materials and applications. Mater. Today 19, 8 (2016).CrossRefGoogle Scholar
Granero, A.J., Razal, J.M., Wallace, G.G., and in het Panhuis, M.: Mechanical reinforcement of continuous flow spun polyelectrolyte complex fibers. Macromol. Biosci. 9, 4 (2010).Google Scholar
Granero, A.J., Razal, J.M., Wallace, G.G., and Panhuis, M.I.H.: Cover picture: Spinning carbon nanotube-gel fibers using polyelectrolyte complexation (adv. Funct. Mater. 23/2008). Adv. Funct. Mater. 18, 23 (2008).Google Scholar
Meng, F.L., Toh, J.K.C., Chan, D., Narayanan, K., Hong, F.L., Lim, T.C., Wan, A.C.A., and Ying, J.Y.: Patterned prevascularised tissue constructs by assembly of polyelectrolyte hydrogel fibres. Nat. Commun. 4, 4 (2013).Google Scholar
Ohkawa, K., Takahashi, Y., Yamada, M., and Yamamoto, H.: Polyion complex fiber and capsule formed by self-assembly of chitosan and poly(α,l-glutamic acid) at solution interfaces. Macromol. Mater. Eng. 286, 3 (2015).Google Scholar
Wan, A.C., Yim, E.K., Liao, I.C., Le, V.C., and Leong, K.W.: Encapsulation of biologics in self-assembled fibers as biostructural units for tissue engineering. J. Biomed. Mater. Res., Part A 71, 4 (2004).Google ScholarPubMed
Wan, A.C.A., Meng, F.L., Toh, J.K.C., Zheng, Y., and Ying, J.Y.: Multicomponent fibers by multi-interfacial polyelectrolyte complexation. Adv. Healthcare Mater. 1, 1 (2012).CrossRefGoogle ScholarPubMed
Reddy, J.P. and Rhim, J.W.: Extraction and characterization of cellulose microfibers from agricultural wastes of onion and garlic. J. Nat. Fibers 15, 4 (2018).CrossRefGoogle Scholar
Geng, L., Chen, B., Peng, X., and Kuang, T.: Strength and modulus improvement of wet-spun cellulose I filaments by sequential physical and chemical cross-linking. Mater. Des. 136, 45 (2017).CrossRefGoogle Scholar
Mao, Y., Liu, K., Zhan, C., Geng, L., Chu, B., and Hsiao, B.S.: Characterization of nanocellulose using small-angle neutron, X-ray, and dynamic light scattering techniques. J. Phys. Chem. B 121, 6 (2017).CrossRefGoogle ScholarPubMed
Geng, L., Peng, X., Zhan, C., Naderi, A., Sharma, P.R., Mao, Y., and Hsiao, B.S.: Structure characterization of cellulose nanofiber hydrogel as functions of concentration and ionic strength. Cellulose 24, 12 (2017).CrossRefGoogle Scholar
Zargar, V., Asghari, M., and Dashti, A.: A review on chitin and chitosan polymers: Structure, chemistry, solubility, derivatives, and applications. ChemBioEng Rev. 2, 3 (2015).CrossRefGoogle Scholar
Pillai, C.K.S., Paul, W., and Sharma, C.P.: Chitin and chitosan polymers: Chemistry, solubility and fiber formation. Prog. Polym. Sci. 34, 7 (2009).CrossRefGoogle Scholar
Yao, C., Xiong, Z., Zhang, D., Peng, Y., and Ma, Y.: High performance supercapacitors based on reduced graphene oxide in aqueous and ionic liquid electrolytes. Carbon 49, 2 (2011).Google Scholar
Supplementary material: File

Lin et al. supplementary material

Lin et al. supplementary material

Download Lin et al. supplementary material(File)
File 343.4 KB