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Optical thermometry and heating based on the upconversion fluorescence from Yb3+/Er3+ co-doped NaLa(MoO4)2 phosphor

Published online by Cambridge University Press:  18 October 2016

Guofeng Liu ,
Zhiyi Gao ,
Zuoling Fu ,
Zhen Sun ,
Xiangtong Zhang ,
Zhijian Wu  and
Jung Hyun Jeong
Guofeng Liu
Affiliation:
Coherent Light and Atomic and Molecular Spectroscopy Laboratory, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, China
Zhiyi Gao
Affiliation:
Coherent Light and Atomic and Molecular Spectroscopy Laboratory, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, China
Zuoling Fu*
Affiliation:
Coherent Light and Atomic and Molecular Spectroscopy Laboratory, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, China
Zhen Sun
Affiliation:
Coherent Light and Atomic and Molecular Spectroscopy Laboratory, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, China
Xiangtong Zhang
Affiliation:
Coherent Light and Atomic and Molecular Spectroscopy Laboratory, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, China
Zhijian Wu
Affiliation:
State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Jung Hyun Jeong*
Affiliation:
Department of Physics, Pukyong National University, Busan 608-737, South Korea
*
a) Address all correspondence to these authors. e-mail: zlfu@jlu.edu.cn
b) e-mail: jhjeong@pknu.ac.kr
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Abstract

The NaLa(MoO4)2:Yb3+/Er3+ phosphor is synthesized through hydrothermal method with the further calcinations. The intense green upconversion (UC) emission is observed when it is excited by 980 nm pump power. Then we investigate the mechanism of UC emission based on the power dependent upconversion luminescence (UCL) spectra. Temperature sensing performance based on the Stark levels (2H11/2/4S3/2) of Er3+ is estimated through investigating temperature-dependent UCL spectra from 298 K to 573 K. And the maximum value of sensor sensitivity based on FIR is approximately 0.00474 K−1. Moreover, the variations of UCL intensities from 2H11/2/4S3/2 → 4I15/2 transitions have been monitored with increasing pump power, which suggests that the pump energy can be absorbed by sample and heat it. In addition, the internal temperature of materials can be estimated by FIR technique. All the experimental results indicate that the phosphor has good potential in optical temperature sensing and optical heating.

Keywords

optical temperature sensorsfluorescence intensity ratiorare earth-doped oxides

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Type
Articles
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Journal of Materials Research , Volume 31 , Issue 22 , 28 November 2016 , pp. 3482 - 3488
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Copyright © Materials Research Society 2016 

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References

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