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Oxidation behavior of in situ synthesized (TiB + TiC)/Ti–6Al–4V composites from Ti–B4C–C and Ti–TiB2–TiC systems

Published online by Cambridge University Press:  19 March 2019

Meng Yi ,
Xiangzhao Zhang ,
Chuanxin Ge ,
Guiwu Liu Open the ORCID record for Guiwu Liu [Opens in a new window] ,
Shunjian Xu ,
Demin Zhong  and
Guanjun Qiao
Meng Yi
Affiliation:
School of Mechanical and Electrical Engineering, Xinyu University, Xinyu 338000, China; School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China; and Research Institute of Precision Casting Forging Industry, Xinghua 225714, China
Xiangzhao Zhang
Affiliation:
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
Chuanxin Ge
Affiliation:
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
Guiwu Liu*
Affiliation:
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China; and School of Mechanical and Electrical Engineering, Xinyu University, Xinyu 338000, China
Shunjian Xu*
Affiliation:
School of Mechanical and Electrical Engineering, Xinyu University, Xinyu 338000, China
Demin Zhong
Affiliation:
School of Mechanical and Electrical Engineering, Xinyu University, Xinyu 338000, China
Guanjun Qiao
Affiliation:
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
*
a)Address all correspondence to these authors. e-mail: gwliu76@ujs.edu.cn
b)e-mail: xushunjian@126.com
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Abstract

The oxidation behavior of two percentages of TiB + TiC reinforced Ti–6Al–4V composites derived from Ti–B4C–C and Ti–TiB2–TiC systems was investigated at 873–1073 K for 320 h in air. The oxidation weight gain curves of the (TiB + TiC)/Ti–6Al–4V composites at 973 K basically obey parabolic law, while those at 873 and 1073 K mainly follow linear law and parabolic-linear law, respectively. The oxide layers of the composites are predominately found to be rutile TiO2, Al2O3, and the mixture of V2O3 and V2O5. The oxidation layers turn thinner with increasing the nominal volume fraction of reinforcements in the (TiB + TiC)/Ti–6Al–4V composites. Moreover, according to the calculation results of reaction index (n) and effective activation energy (Qeff) and the analyses of cross-sections of the oxidation layers, the oxidation resistance ability of the composites from Ti–TiB2–TiC system is higher than that from Ti–B4C–C system while employing the same sintering temperature and nominal volume fraction of reinforcement.

Keywords

Ticompositeoxidation
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 10 , 28 May 2019 , pp. 1762 - 1772
Copyright
Copyright © Materials Research Society 2019 

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