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Redox-responsive supramolecular polymer based on β-cyclodextrin and ferrocene-decorated main chain of PAA

Published online by Cambridge University Press:  06 October 2015

Wenping Guo  and
Zhongli Lei
Wenping Guo
Affiliation:
Key Laboratory of Applied Surface and Colloid Chemistry, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an Shaanxi 710062, China
Zhongli Lei*
Affiliation:
Key Laboratory of Applied Surface and Colloid Chemistry, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an Shaanxi 710062, China
*
a)Address all correspondence to this author. e-mail: zhllei@snnu.edu.cn
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Abstract

Herein, we present a method for introducing β-cyclodextrin (β-CD) and Ferrocene (Fc) into the main chain of poly(acrylic acid) (PAA) to fabricate a novel supramolecular polymer, which was investigated by Fourier transform infrared spectroscopy and 1H Nuclear Magnetic Resonance (1H NMR). This polymer can self-assemble into interesting nanoparticles in aqueous solution. The redox-responsive Fc–CD host–guest interactions endow these nanoparticles with unique self-degradable and self-healable features under redox potential control. This redox behavior of the supramolecular polymer would open up an approach for redox-controlled biological materials with great application potential.

Keywords

supramolecular polymernanoparticleshost–guest interactionsredox-responsive
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 21 , 13 November 2015 , pp. 3201 - 3210
Copyright
Copyright © Materials Research Society 2015 

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Footnotes

Contributing Editor: Tao Xie

References

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