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Selective removal of As, Sb, and Se ions from multicomponent mixture by nanoparticles

Published online by Cambridge University Press:  11 April 2016

Si-Hong Wang*
Affiliation:
Analysis and Inspection Center, Yanbian University, Yanji, Jilin 133002, China; and Key Laboratory of Organism Functional Factors of the Changbai Mountains of Ministry of Education, Yanbian University, Yanji, Jilin 133002, China
Jing-Dong Zhang
Affiliation:
Analysis and Inspection Center, Yanbian University, Yanji, Jilin 133002, China
Ji-Shou Piao
Affiliation:
Key Laboratory of Organism Functional Factors of the Changbai Mountains of Ministry of Education, Yanbian University, Yanji, Jilin 133002, China
Dong-Hao Li*
Affiliation:
Key Laboratory of Organism Functional Factors of the Changbai Mountains of Ministry of Education, Yanbian University, Yanji, Jilin 133002, China
*
a) Address all correspondence to these authors. e-mail: shwang@ybu.edu.cn
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Abstract

In this work, the selective removal of ions from multicomponent mixtures using functionalized magnetic nanoparticles (FMNPs) was demonstrated. As, Sb, and Se ions were efficiently removed from complex mixtures, such as Rhodiola rosea extracts and influent water from the sewage treatment unit of a beer brewery. As, Sb, and Se ions could be selectively adsorbed by FMNP, as demonstrated by the inductively coupled plasma mass spectrometer analyses. We also demonstrated that Pb ions are weakly adsorbed, whereas Cu, Cd, and Zn ions cannot be adsorbed by FMNP. The complexity of the mixture did not affect the selective removal of As, Sb, and Se ions. FMNP could be recycled and used repeatedly. Magnetic separation could then be applied for the selective separation of complex mixtures, such as plant extracts, industrial wastewater, and tap water.

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Articles
Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Wang, S.-H., Wang, S.-F., Xuan, W., Zeng, Z.-H., Jin, J.-Y., Ma, J., and Tian, G.R.: Nitro as a novel zinc-binding group in the inhibition of carboxypeptidase A. Bioorg. Med. Chem. 16(7), 3596 (2008).CrossRefGoogle Scholar
Lunge, S., Singh, S., and Sinha, A.: Magnetic iron oxide (Fe3O4) nanoparticles from tea waste for arsenic removal. J. Magn. Magn. Mater. 356, 21 (2014).CrossRefGoogle Scholar
Shan, C., Ma, Z., and Tong, M.: Efficient removal of trace antimony(III) through adsorption by hematite modified magnetic nanoparticles. J. Hazard. Mater. 268, 229 (2014).CrossRefGoogle ScholarPubMed
Khajeh, M., Laurent, S., and Dastafkan, K.: Nanoadsorbents: Classification, preparation, and applications (with emphasis on aqueous media). Chem. Rev. 113(10), 7728 (2013).CrossRefGoogle Scholar
Laurent, S., Forge, D., Port, M., Roch, A., Robic, C., Vander Elst, L., and Muller, R.N.: Magnetic iron oxide nanoparticles: Synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications. Chem. Rev. 108(6), 2064 (2008).CrossRefGoogle ScholarPubMed
Huang, Y. and Keller, A.A.: Magnetic nanoparticle adsorbents for emerging organic contaminants. ACS Sustainable Chem. Eng. 1(7), 731 (2013).CrossRefGoogle Scholar
Malekpour, A. and Khodadadi, M.: Albumin-functionalized magnetic nanoparticles as an efficient sorbent for removal of Pb(II), Cd(II), Cu(II) and Cr(VI) ions from aqueous solutions. RSC Adv. 6, 14705 (2016).CrossRefGoogle Scholar
Shi, J., Li, H., Lu, H., and Zhao, X.: Use of carboxyl functional magnetite nanoparticles as potential sorbents for the removal of heavy metal ions from aqueous solution. J. Chem. Eng. Data 60(7), 2035 (2015).CrossRefGoogle Scholar
Yantasee, W., Warner, C.L., Sangvanich, T., Addleman, R.S., Carter, T.G., Wiacek, R.J., Fryxell, G.E., Timchalk, C., and Warner, M.G.: Removal of heavy metals from aqueous systems with thiol functionalized superparamagnetic nanoparticles. Environ. Sci. Technol. 41(14), 5114 (2007).CrossRefGoogle Scholar
Ali, I.: New generation adsorbents for water treatment. Chem. Rev. 112(10), 5073 (2012).CrossRefGoogle ScholarPubMed
Reddy, L.H., Arias, J.L., Nicolas, J., and Couvreur, P.: Magnetic nanoparticles: Design and characterization, toxicity and biocompatibility, pharmaceutical and biomedical applications. Chem. Rev. 112(11), 5818 (2012).CrossRefGoogle ScholarPubMed
Chowdhury, S.R., Yanful, E.K., and Pratt, A.R.: Arsenic removal from aqueous solutions by mixed magnetite–maghemite nanoparticles. Environ. Earth Sci. 64(2), 411 (2011).CrossRefGoogle Scholar
Hu, J., Chen, G., and Lo, I.M.C.: Removal and recovery of Cr(VI) from wastewater by maghemite nanoparticles. Water Res. 39(18), 4528 (2005).CrossRefGoogle Scholar
Hu, J., Chen, G., and Lo, I.: Selective removal of heavy metals from industrial wastewater using maghemite nanoparticle: Performance and mechanisms. J. Environ. Eng. 132(7), 709 (2006).CrossRefGoogle Scholar
Liu, J.-F., Zhao, Z.-S., and Jiang, G.-B.: Coating Fe3O4 magnetic nanoparticles with humic acid for high efficient removal of heavy metals in water. Environ. Sci. Technol. 42(18), 6949 (2008).CrossRefGoogle ScholarPubMed
Liu, X., Hu, Q., Fang, Z., Zhang, X., and Zhang, B.: Magnetic chitosan nanocomposites: A useful recyclable tool for heavy metal ion removal. Langmuir 25(1), 3 (2009).CrossRefGoogle ScholarPubMed
Giakisikli, G. and Anthemidis, A.N.: Magnetic materials as sorbents for metal/metalloid preconcentration and/or separation. A review. Anal. Chim. Acta 789, 1 (2013).CrossRefGoogle ScholarPubMed
Lu, A.-H., Salabas, E.L., and Schüth, F.: Magnetic nanoparticles: Synthesis, protection, functionalization, and application. Angew. Chem., Int. Ed. 46(8), 1222 (2007).CrossRefGoogle ScholarPubMed
Xin, X., Wei, Q., Yang, J., Yan, L., Feng, R., Chen, G., Du, B., and Li, H.: Highly efficient removal of heavy metal ions by amine-functionalized mesoporous Fe3O4 nanoparticles. Chem. Eng. J. 184, 132 (2012).CrossRefGoogle Scholar
Tan, Y., Chen, M., and Hao, Y.: High efficient removal of Pb(II) by amino-functionalized Fe3O4 magnetic nanoparticles. Chem. Eng. J. 191, 104 (2012).CrossRefGoogle Scholar
Hao, Y.-M., Man, C., and Hu, Z.-B.: Effective removal of Cu(II) ions from aqueous solution by amino-functionalized magnetic nanoparticles. J. Hazard. Mater. 184(1–3), 392 (2010).CrossRefGoogle ScholarPubMed
Panossian, A., Wikman, G., and Sarris, J.: Rosenroot (Rhodiola rosea): Traditional use, chemical composition, pharmacology and clinical efficacy. Phytomedicine. 17(7), 481 (2010).CrossRefGoogle ScholarPubMed
Liao, W., Gan, Y.-X., Zhao, S.-L., Luo, N.-N., Rahmadini, N., Giannotta, F., Fu, C.-M., Rui, L., and Wang, J.-S.: Comparative analysis of trace elements contained in Rhizoma curcumae from different origins and their vinegar products by ICP-MS. Anal. Methods 6(20), 8187 (2014).CrossRefGoogle Scholar
Wang, S.-H. and Zhang, J.-D.: The comparation and determination of inorganic elements in Rhodiola angusta Nakai. Yanbian Daxue Xuebao, Ziran Kexueban 39(2), 125 (2013).Google Scholar
Wang, L., Bao, J., Wang, L., Zhang, F., and Li, Y.: One-pot synthesis and bioapplication of amine-functionalized magnetite nanoparticles and hollow nanospheres. Chem.–Eur. J. 12(24), 6341 (2006).CrossRefGoogle ScholarPubMed
Wang, J., Zhao, G., Li, Y., Zhu, H., Peng, X., and Gao, X.: One-step fabrication of functionalized magnetic adsorbents with large surface area and their adsorption for dye and heavy metal ions. Dalton Trans. 43(30), 11637 (2014).CrossRefGoogle ScholarPubMed
Feng, L., Cao, M., Ma, X., Zhu, Y., and Hu, C.: Superparamagnetic high-surface-area Fe3O4 nanoparticles as adsorbents for arsenic removal. J. Hazard. Mater. 217–218, 439 (2012).CrossRefGoogle ScholarPubMed
Stathi, P., Litina, K., Gournis, D., Giannopoulos, T.S., and Deligiannakis, Y.: Physicochemical study of novel organoclays as heavy metal ion adsorbents for environmental remediation. J. Colloid Interface Sci. 316(2), 298 (2007).CrossRefGoogle ScholarPubMed
Yu, X., Tian, X., and Wang, S.: Adsorption of Ni, Pd, Pt, Cu, Ag and Au on the Fe3O4(111) surface. Surf. Sci. 628, 141 (2014).CrossRefGoogle Scholar
Li, H., Xiao, D.-l., He, H., Lin, R. and Zuo, P.-l.: Adsorption behavior and adsorption mechanism of Cu(II) ions on amino-functionalized magnetic nanoparticles. Trans. Nonferrous Met. Soc. China 23(9), 2657 (2013).CrossRefGoogle Scholar
Gavrilescu, M.: Removal of heavy metals from the environment by biosorption. Eng. Life Sci. 4(3), 219 (2004).CrossRefGoogle Scholar
Zhang, F., Zhu, Z., Dong, Z., Cui, Z., Wang, H., Hu, W., Zhao, P., Wang, P., Wei, S., Li, R., and Ma, J.: Magnetically recoverable facile nanomaterials: Synthesis, characterization and application in remediation of heavy metals. Microchem. J. 98(2), 328 (2011).CrossRefGoogle Scholar
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