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A study of temperature and pressure-induced structural and electronic changes in SbCl5 intercalated graphite: Part III. Analysis of the T and p dependence of the c-axis resistivity

Published online by Cambridge University Press:  03 March 2011

B. Sundqvist ,
O.E. Andersson ,
E. McRae ,
M. Lelaurain  and
J.F. Maréché
B. Sundqvist
Affiliation:
Department of Experimental Physics, Urnea University, S-90187 Urnea, Sweden
O.E. Andersson
Affiliation:
Department of Experimental Physics, Urnea University, S-90187 Urnea, Sweden
E. McRae
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Miéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérate Appliquée, B.P. 239, 54506 Vandoeuvre-lès-Nancy Cédex, France
M. Lelaurain
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Miéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérate Appliquée, B.P. 239, 54506 Vandoeuvre-lès-Nancy Cédex, France
J.F. Maréché
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Miéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérate Appliquée, B.P. 239, 54506 Vandoeuvre-lès-Nancy Cédex, France
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Abstract

We present experimental data for the c-axis electrical resistivity of SbCl5 intercalated graphite between 20 and 300 K. The data are analyzed together with our previous results for these and other samples [O. E. Andersson et al., J. Mater. Res. 7, 2989 (1992)]. Before the analysis, we correct the experimental data to constant volume, as assumed by theorists. We show that the correction factor is much larger for these materials than for normal metals. Although the original data showed significant nonlinearities with T, the corrected data are linear in T to within the experimental accuracy for low-stage compounds below the intercalate crystallization temperature. We compare our results with several models and conclude that both the temperature dependence, the pressure dependence, and the relative changes in the in-plane and c-axis resistivities associated with intercalate crystallization can be best described by a band conduction model.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 2 , February 1995 , pp. 436 - 446
Copyright
Copyright © Materials Research Society 1995

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References

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