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Synthesis and characterization of copper–silver core–shell nanowires obtained by electrodeposition followed by a galvanic replacement reaction in aqueous solution; comparison with a galvanic replacement reaction in ionic media

Published online by Cambridge University Press:  10 November 2015

Samuel Levi ,
Céline Rousse ,
Valérie Mancier ,
Jean Michel  and
Patrick Fricoteaux
Samuel Levi
Affiliation:
LISM, EA 4695, Department of Chemistry, UFR Sciences Exactes et Naturelles, Reims-Champagne-Ardenne University, F-51687 Reims, France
Céline Rousse
Affiliation:
LISM, EA 4695, Department of Chemistry, UFR Sciences Exactes et Naturelles, Reims-Champagne-Ardenne University, F-51687 Reims, France
Valérie Mancier
Affiliation:
LISM, EA 4695, Department of Chemistry, UFR Sciences Exactes et Naturelles, Reims-Champagne-Ardenne University, F-51687 Reims, France
Jean Michel
Affiliation:
LRN, EA 4682, Department of Physics, UFR Sciences Exactes et Naturelles, Reims-Champagne-Ardenne University, F-51685 Reims, France
Patrick Fricoteaux*
Affiliation:
LISM, EA 4695, Department of Chemistry, UFR Sciences Exactes et Naturelles, Reims-Champagne-Ardenne University, F-51687 Reims, France
*
a)Address all correspondence to this author. e-mail: patrick.fricoteaux@univ-reims.fr
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Abstract

Copper–silver core–shell nanowires were synthesized using a combination of two methods: electrodeposition in a polycarbonate membrane as a template for the synthesis of a copper core and a galvanic replacement reaction for the elaboration of a silver shell. A comparative study between aqueous and ionic liquid media was performed for the silver shell elaboration. The kinetics of the reaction in both media was monitored by using energy dispersive x-ray spectroscopy. The shape and size of the nanowires were observed by both scanning electron microscopy and transmission electron microscopy. The core–shell structure was determined by electron energy loss spectroscopy analyses for the Cu90Ag10 composition. A homogenous silver shell was formed in aqueous media. Whereas in ionic solvent, well defined silver crystals were obtained at the surface of the nanowires but without a total formation of a silver shell structure.

Keywords

Cu–Ag core–shellnanowireselectrodeposition
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 22 , 27 November 2015 , pp. 3518 - 3527
Copyright
Copyright © Materials Research Society 2015 

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References

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