Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-14T23:29:08.508Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and characterization of single-crystalline CdS nanorods prepared by γ-irradiation

Published online by Cambridge University Press:  31 January 2011

Haijiao Zhang ,
Gang Liu ,
Xiaojuan Wan ,
Huijiao Guo ,
Zheng Jiao  and
Minghong Wu
Haijiao Zhang
Affiliation:
Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai, China
Gang Liu
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai, China
Xiaojuan Wan
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai, China
Huijiao Guo
Affiliation:
Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai, China
Zheng Jiao*
Affiliation:
Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai, China
Minghong Wu*
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai, China
*
a) e-mail: zjiao@shu.edu.cn
b) e-mail: mhwu@staff.shu.edu.cn
Get access

Abstract

Under γ-irradiation, thiacetamide (TAA) releases S2− in acidic solutions (e.g., pH = 3), and the S2− can react with available Cd2+ in soft templates to form CdS nanorods. Single-crystalline CdS nanorods were prepared in this study. The effects of various synthesis parameters on the crystalline type, morphology, average particle size, and photoelectric properties were thoroughly investigated, including the concentrations of reactants, dose of irradiation, and the type and dosage of templates. The structure and selected physical and chemical properties of products were characterized by x-ray diffraction (XRD), Fourier transform infrared (FTIR), ultraviolet-visible (UV-vis), selected area electron diffraction (SAED), transmission electron microscopy (TEM), and photoluminescence (PL) spectrophotometer techniques. Results indicated that the ratio of reactants to templates greatly affected the morphology of CdS nanorods; the types of soft templates also had significant effects on the morphology and crystalline type of the nanorod products.

Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 1 , January 2009 , pp. 227 - 236
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Stroscio, J.A., Eigler, D.M.: Atomic and molecular manipulation with the scanning tunneling microscope. Science 254, 1319 1991CrossRefGoogle ScholarPubMed
2.Lieber, C.M., Liu, J., Sheehan, P.E.: Understanding and manipulating inorganic materials using scanning probe microscopes. Angew. Chem. Int. Ed. Engl. 35, 686 1996CrossRefGoogle Scholar
3.Datta, A., Kar, S., Ghatak, J., Chaudhuri, S.: Solvothermal synthesis of CdS nanorods: Role of basic experimental parameters. J. Nanosci. Nanotechnol. 6, 3897 2007Google Scholar
4.Wang, Y., Herron, N.: Nanometer-sized semiconductor clusters: Materials synthesis, quantum-size effects and photophysical properties. J. Phys. Chem. 95, 525 1991CrossRefGoogle Scholar
5.Xie, Y., Huang, J.X., Li, B., Liu, Y., Qian, Y.T.: A novel peanut-like nanostructure of II±VI semiconductor CdS and ZnS. Adv. Mater. 12, 1523 20003.0.CO;2-T>CrossRefGoogle Scholar
6.Tseng, C.H., Wang, C.C., Chen, C.Y.: Modification of polypropylene fibers by plasma and preparation of hybrid luminescent and rodlike CdS nanocrystals/polypropylene fibers. J. Nanosci. Nanotechnol. 6, 3897 2006CrossRefGoogle ScholarPubMed
7.Janetand, C.M., Viswanath, R.P.: Large scale synthesis of CdS nanorods and its utilization in photo-catalytic H2 production. Nanotechnology 17, 4966 2006Google Scholar
8.Tang, Z.Y., Kotov, N.A., Giersing, M.: Spontaneous organization of single CdTe nanoparticles into luminescent nanowires. Science 297, 237 2002CrossRefGoogle ScholarPubMed
9.Cho, K.S., Talapin, D.V., Gaschler, W., Murray, C.B.: Designing PbSe nanowires and nanorings through oriented attachment of nanoparticles. J. Am. Chem. Soc. 127, 7140 2005CrossRefGoogle ScholarPubMed
10.Jiang, L.P., Xu, S., Miao, J.J., Wang, H., Zhu, J.J.: Sonochemical synthesis of CdS and CdSe nanowires. J. Nanosci. Nanotechnol. 6, 2584 2006CrossRefGoogle ScholarPubMed
11.Wyrwa, D., Beyer, N., Schmid, G.: One-dimensional arrangements of metal nanoclusters. Nano Lett. 2, 219 2002CrossRefGoogle Scholar
12.Lazzari, M., Lopez-Quintela, M.A.: Block copolymers as a tool for nanomaterial fabrication. Adv. Mater. 15, 1583 2003CrossRefGoogle Scholar
13.Xie, Y., Qiao, Z.P., Chen, M., Liu, X.M., Qian, Y.T.: γ-irradiation route to semiconductor/polymer nanocable fabrication. Adv. Mater. 11, 1512 19993.0.CO;2-S>CrossRefGoogle Scholar
14.Martin, T.P., Schaber, H.: Matrix isolated II-VI molecules: Sulfides of Mg, Ca, Sr, Zn and Cd. Spectrochim. Acta, Part A 38, 655 1982CrossRefGoogle Scholar
15.Farias, P.M.A., Santosb, B.S., Longo, R.L., Ferreira, R., Cesar, C.L.: CdS nanoparticles: Structural and energetical correlations. Mater. Chem. Phys. 89, 21 2005CrossRefGoogle Scholar
16.Banerjee, R., Jayakrishnan, R., Ayyub, P.: Effect of the size-induced structural transformation on the band gap in CdS nanoparticles. J. Phys.: Condens. Matter 12, 10654 2000Google Scholar
17.Zelaya-Angel, O., Lozada-Morales, R.: Sphalerite-wurtzite phase transformation in CdS. Phys. Rev. B 62, 13064 2000CrossRefGoogle Scholar
18.Bandaranayake, R.J., Wen, G.W., Lin, J.Y., Jiang, H.X., Sorensen, C.M.: Structural phase behavior in II–VI semiconductor nanoparticles. Appl. Phys. Lett. 67, 831 1995CrossRefGoogle Scholar
19.Niu, H.X., Yang, Q., Tang, K.B., Xie, Y., Zhu, Y.C.: Soft-template synthesis of single-crystalline CdS dendrites. J. Nanosci. Nanotechnol. 6, 162 2006CrossRefGoogle ScholarPubMed
20.Yu, S.H., Wu, Y.S., Yang, J., Han, Z.H., Xie, Y., Qian, Y.T., Liu, X.M.: Controllable synthesis of nanocrystalline CdS with different morphologies and particle sizes by a novel solvothermal process. Chem. Mater. 10, 2309 1998CrossRefGoogle Scholar
21.Yang, J.P., Meldrum, F.C., Fendler, J.H.: Epitaxial-growth of size quantized cadmium-sulfide crystals under arachidic acid monolayers. J. Phys. Chem. 99, 5500 1995CrossRefGoogle Scholar
22.Singh, R.S., Sanagapalli, S., Jayaraman, V., Singh, V.P.: Ultrasound-assisted fabrication of nanoporous CdS films. J. Nanosci. Nanotechnol. 4, 176 2004CrossRefGoogle ScholarPubMed
23.Chen, Q.W., Zhu, D.L., Zhu, C., Wang, J., Zhang, Y.G.: A way to obtain visible blue light emission in porous silicon. Appl. Phys. Lett. 82, 1018 2003CrossRefGoogle Scholar
24.Liu, C., Hu, Z., Wu, Q., Wang, X., Chen, Y., Sang, H., Zhu, J., Deng, S., Xu, N.: Vapor-solid growth and characterization of aluminum nitride nanocones. J. Am. Soc. 127, 1318 2005CrossRefGoogle ScholarPubMed
25.Zezza, F., Comparelli, R., Striccoli, M., Curri, M.L., Tommasi, R., Agostiano, A., Della Monica, M.: High quality CdS nanocrystals: Surface effects. Synth. Met. 139, 597 2003CrossRefGoogle Scholar
26.Dong, X.Y., Zhang, X.T., Liu, B., Wang, H.Z., Li, Y.C., Huang, Y.B., Du, Z.L.: Controlled synthesis of manganese oxohydroxide (MnOOH) and Mn3O4 nanorods using novel reverse micelles. J. Nanosci. Nanotechnol. 6, 818 2006CrossRefGoogle ScholarPubMed
27.Zweifel, D.A., Wei, A.: Sulfide-arrested growth of gold nanorods. Chem. Mater. 17, 4256 2005CrossRefGoogle ScholarPubMed
28.Zhang, J., Sun, L.D., Jiang, X.C., Liao, C.S., Yan, C.H.: Shape evolution of one-dimensional single-crystalline ZnO nanostructures in a microemulsion system. Cryst. Growth Des. 4, 309 2004CrossRefGoogle Scholar
29.Wang, Z.X., Chen, J.F., Xue, X., Hu, Y.: Synthesis of monodispersed CdS nanoballs through γ-irradiation route and building core-shell structure CdS@SiO2. Mater. Res. Bull. 42, 2211 2007CrossRefGoogle Scholar
30.Zhan, J.H., Yang, X.G., Zhang, W.X., Wang, D.W., Xie, Y., Qian, Y.T.: A solvothermal route to wurtzite ZnSe nanoparticles. J. Mater. Res. 15, 629 2000CrossRefGoogle Scholar