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Synthesis and their photocatalytic properties of Ni-doped ZnO hollow microspheres

Published online by Cambridge University Press:  19 April 2016

Yuanyou Wang ,
Tianqing Liu ,
Qingli Huang ,
Changle Wu  and
Dan Shan
Yuanyou Wang*
Affiliation:
Jiangsu Key Laboratory of Environmental Material and Environmental Engineering, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, China; Department of Chemical Engineering, Yangzhou Polytechnic Institute, Yangzhou, 225127, China; and School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
Tianqing Liu
Affiliation:
Jiangsu Key Laboratory of Environmental Material and Environmental Engineering, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, China
Qingli Huang
Affiliation:
Testing Center, Yangzhou University, Yangzhou, 225009, China
Changle Wu
Affiliation:
Testing Center, Yangzhou University, Yangzhou, 225009, China
Dan Shan
Affiliation:
School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
*
a) Address all correspondence to this author. e-mail: wangyy@ypi.edu.cn
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Abstract

Ni-doped ZnO hollow microspheres were fabricated by calcining the mixture of zinc and nickel citrate precursors at 500 °C for 2 h. The structure, composition, Barrett–Emmett–Teller specific surface area, and optical properties of Ni-doped ZnO samples were characterized by x-ray diffraction, x-ray photoelectron spectroscopy, wave length dispersive x-ray fluorescence spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, N2 adsorption–desorption isotherms, and ultraviolet (UV)-visible diffuse reflectance spectroscopy. The photocatalytic results demonstrated that the as-synthesized Ni-doped ZnO microcrystals possessed much higher photocatalytic activity than pure ZnO in the decomposition of methylene blue under UV-light irradiation. The present work suggests that Ni-doped ZnO hollow microspheres can be applied as an efficient photocatalyst for water polluted by some chemically stable azo dyes.

Keywords

ZnO hollow spheresNi dopingphotocatalytic activity
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 15 , 15 August 2016 , pp. 2317 - 2328
Copyright
Copyright © Materials Research Society 2016 

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References

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