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Ag-coated nylon fabrics as flexible substrates for surface-enhanced Raman scattering swabbing applications

Published online by Cambridge University Press:  19 May 2020

Airong Liu
Affiliation:
Key Lab of Science & Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Shuo Zhang
Affiliation:
Key Lab of Science & Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Shanyi Guang
Affiliation:
Key Lab of Science & Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Fengyan Ge*
Affiliation:
Key Lab of Science & Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
Juan Wang*
Affiliation:
School of Chemical Engineering, Shijiazhuang University, Shijiazhuang, Hebei 050035, China
*
a)Address all correspondence to these authors. e-mail: DHUfyge@163.com
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Abstract

A flexible surface-enhanced Raman scattering (SERS) substrate was prepared by vacuum evaporation of silver on the surface of woven nylon fabrics. SERS properties of the Ag-coated nylon fabrics varied as the thickness of silver coatings changed, relative to the morphologies and distribution of silver nanoparticles (NPs) on fiber. The SERS enhancement performance of Ag-coated nylon fabrics was evaluated by collecting Raman signals of different concentrations of p-aminothiophenol (PATP). The results suggested that the nylon fabrics coated with 10 nm thickness Ag NPs coatings possessed high SERS activity and its detection concentration for PATP is as low as 10−9 M. Furthermore, sensitive SERS signals with excellent reproducibility (Relative standard deviation = 8.25%) and stability (30 days) have been demonstrated. In addition, the SERS nylon fabrics have been applied to rapidly detect thiram pesticides on cucumber, which indicated a great potential for trace analysis.

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Article
Copyright
Copyright © Materials Research Society 2020

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References

Li, J.F., Zhang, Y.J., Ding, S.Y., Panneerselvam, R., and Tian, Z.Q.: Core–shell nanoparticle-enhanced Raman spectroscopy. Chem. Rev. 117, 5002 (2017).CrossRefGoogle ScholarPubMed
Liu, J., Si, T., and Zhang, Z.: Mussel-inspired immobilization of silver nanoparticles toward sponge for rapid swabbing extraction and SERS detection of trace inorganic explosives. Talanta 204, 189 (2019).CrossRefGoogle ScholarPubMed
Shi, R., Liu, X., and Ying, Y.: Facing challenges in real-life application of surface-enhanced Raman scattering (SERS): Design and nanofabrication of SERS substrates for rapid field test of food contaminants. J. Agric. Food Chem. 66, 6525 (2017).CrossRefGoogle ScholarPubMed
Xu, T., Wang, X., Huang, Y., Lai, K., and Fan, Y.: Rapid detection of trace methylene blue and malachite green in four fish tissues by ultra-sensitive surface-enhanced Raman spectroscopy coated with gold nanorods. Food Contr. 106, 106720 (2019).CrossRefGoogle Scholar
Ko, H., Singamaneni, S., and Tsukruk, V.V.: Nanostructured surfaces and assemblies as SERS media. Small 4, 1576 (2010).CrossRefGoogle Scholar
Xu, K., Zhou, R., Takei, K., and Hong, M.: Toward flexible surface‐enhanced Raman scattering (SERS) sensors for point‐of‐care diagnostics. Adv. Sci. 6, 1900925 (2019).CrossRefGoogle ScholarPubMed
Prikhozhdenko, E.S., Bratashov, D.N., Gorin, D.A., and Yashchenok, A.M.: Flexible surface-enhanced Raman scattering-active substrates based on nanofibrous membranes. Nano Res. 11, 1 (2018).CrossRefGoogle Scholar
Hoppmann, E.P., Wei, W.Y., and White, I.M.: Highly sensitive and flexible inkjet printed SERS sensors on paper. Methods 63, 219 (2013).CrossRefGoogle ScholarPubMed
Ross, M.B., Ashley, M.J., Schmucker, A.L., Singamaneni, S., Naik, R.R., Schatz, G.C., and Mirkin, C.A.: Structure–function relationships for surface-enhanced Raman spectroscopy-active plasmonic paper. J. Phys. Chem. C 120, 20789 (2016).CrossRefGoogle Scholar
Wang, C., Liu, B., and Dou, X.: Silver nanotriangles-loaded filter paper for ultrasensitive SERS detection application benefited by interspacing of sharp edges. Sens. Actuators, B 231, 357 (2016).CrossRefGoogle Scholar
Zhang, R., Xu, B.B., Liu, X.Q., Zhang, Y.L., Xu, Y., Chen, Q.D., and Sun, H.B.: Highly efficient SERS test strips. Chem. Commun. 48, 5913 (2012).CrossRefGoogle ScholarPubMed
Chen, C., Tang, Y., Vlahovic, B., and Yan, F.: Electrospun polymer nanofibers decorated with noble metal nanoparticles for chemical sensing. Nanoscale Res. Lett. 12, 451 (2017).CrossRefGoogle ScholarPubMed
Liu, Z., Yan, Z., Lu, J., Ping, S., Mei, L., Lu, B., and Liu, Y.: Gold nanoparticle decorated electrospun nanofibers: A 3D reproducible and sensitive SERS substrate. Appl. Surf. Sci. 403, 29 (2017).CrossRefGoogle Scholar
Ballerini, D.R., Ying, H.N., Garnier, G., Ladewig, B.P., Wei, S., and Jarujamrus, P.: Gold nanoparticle‐functionalized thread as a substrate for SERS study of analytes both bound and unbound to gold. AIChE J. 60, 1598 (2014).CrossRefGoogle Scholar
Cai, L., Deng, Z., Dong, J., Song, S., Wang, Y., and Chen, X.: Fabrication of non-woven fabric-based SERS substrate for direct detection of pesticide residues in fruits. J. Test. Eval. 1, 322 (2017).Google Scholar
Duy, P.K., Yen, P.T.H., Chun, S., Ha, V.T.T., and Chung, H.: Carbon fiber cloth-supported Au nanodendrites as a rugged surface-enhanced Raman scattering substrate and electrochemical sensing platform. Sens. Actuators, B 225, 377 (2016).CrossRefGoogle Scholar
Ge, F., Chen, Y., Liu, A., Guang, S., and Cai, Z.: Flexible and recyclable SERS substrate fabricated by decorated TiO2 film with Ag NPs on the cotton fabric. Cellulose 26, 2689 (2019).CrossRefGoogle Scholar
Liu, J., Zhou, J., Tang, B., Zeng, T., Li, Y., Li, J., Ye, Y., and Wang, X.: Surface enhanced Raman scattering (SERS) fabrics for trace analysis. Appl. Surf. Sci. 386, 296 (2016).CrossRefGoogle Scholar
Gong, Z., Du, H., Cheng, F., Wang, C., Wang, C., and Fan, M.: Fabrication of SERS swab for direct detection of trace explosives in fingerprints. ACS Appl. Mater. Interfaces 6, 21931 (2014).CrossRefGoogle ScholarPubMed
Qu, L.L., Geng, Y.Y., Bao, Z.N., Riaz, S., and Li, H.: Silver nanoparticles on cotton swabs for improved surface-enhanced Raman scattering, and its application to the detection of carbaryl. Microchim. Acta 183, 1307 (2016).CrossRefGoogle Scholar
Kelly, F.M. and Johnston, J.H.: Colored and functional silver nanoparticle-wool fiber composites. ACS Appl. Mater. Interfaces 3, 1083 (2011).CrossRefGoogle ScholarPubMed
Tang, B., Sun, L., Kaur, J., Yu, Y., and Wang, X.: In-situ synthesis of gold nanoparticles for multifunctionalization of silk fabrics. Dyes Pigm. 103, 183 (2014).CrossRefGoogle Scholar
Robinson, A.M., Lili, Z., Shah Alam, M.Y., Paridhi, B., Harroun, S.G., Dhananjaya, D., Jonathan, B., and Brosseau, C.L.: The development of “fab-chips” as low-cost, sensitive surface-enhanced Raman spectroscopy (SERS) substrates for analytical applications. Analyst 140, 779 (2015).CrossRefGoogle ScholarPubMed
Chen, Y., Ge, F., Guang, S., and Cai, Z.: Self-assembly of Ag nanoparticles on the woven cotton fabrics as mechanical flexible substrates for surface enhanced Raman scattering. J. Alloys Compd. 726, 484 (2017).CrossRefGoogle Scholar
Chen, Y., Ge, F., Guang, S., and Cai, Z.: Low-cost and large-scale flexible SERS-cotton fabric as a wipe substrate for surface trace analysis. Appl. Surf. Sci. 436, 111 (2018).CrossRefGoogle Scholar
Cheng, D., He, M., Ran, J., Cai, G., Wu, J., and Wang, X.: Depositing a flexible substrate of triangular silver nanoplates onto cotton fabrics for sensitive SERS detection. Sens. Actuators, B 270, 508 (2018).CrossRefGoogle Scholar
Lin, X.M., Cui, Y., Xu, Y.H., Ren, B., and Tian, Z.Q.: Surface-enhanced Raman spectroscopy: Substrate-related issues. Anal. Bioanal. Chem. 394, 1729 (2009).CrossRefGoogle ScholarPubMed
Fan, M., Zhang, Z., Hu, J., Cheng, F., Wang, C., Tang, C., Lin, J., Brolo, A.G., and Zhan, H.: Ag decorated sandpaper as flexible SERS substrate for direct swabbing sampling. Mater. Lett. 133, 57 (2014).CrossRefGoogle Scholar
Li, Z., Wang, M., Jiao, Y., Liu, A., Wang, S., Zhang, C., Yang, C., Xu, Y., Li, C., and Man, B.: Different number of silver nanoparticles layers for surface enhanced Raman spectroscopy analysis. Sens. Actuators, B 255, 374 (2018).CrossRefGoogle Scholar
Ru, E.C.L., Blackie, E.J., Meyer, M., and Etchegoin, P.G.: Surface enhanced Raman scattering enhancement factors: A comprehensive study. J. Phys. Chem. C 111, 13794 (2007).Google Scholar
Wang, Z., Li, M., Wang, W., Fang, M., Sun, Q., and Liu, C.: Floating silver film: A flexible surface-enhanced Raman spectroscopy substrate for direct liquid phase detection at gas-liquid interfaces. Nano Res. 9, 1148 (2016).CrossRefGoogle Scholar
Sun, H., Liu, H., and Wu, Y.: A green, reusable SERS film with high sensitivity for in-situ detection of thiram in apple juice. Appl. Surf. Sci. 416, 704 (2017).CrossRefGoogle Scholar
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