Hostname: page-component-cd9895bd7-gvvz8 Total loading time: 0 Render date: 2024-12-28T00:54:38.934Z Has data issue: false hasContentIssue false

An electron microscopic study of a rapidly solidified Al-5 wt. % Co alloy

Published online by Cambridge University Press:  31 January 2011

G. Van Tendeloo
Affiliation:
University of Antwerp (RUCA), Groenenborgerlaan 171, B-2020 Antwerpen, Belgium
Jyothi Menon
Affiliation:
Centre of Advanced Study in Metallurgy, Banaras Hindu University, Varanasi-221 005, India
C. Suryanarayana
Affiliation:
Centre of Advanced Study in Metallurgy, Banaras Hindu University, Varanasi-221 005, India
Get access

Abstract

An Al-5 wt. % Co alloy has been rapidly solidified from the liquid state, resulting in the formation of a slightly supersaturated aluminum solid solution and the monoclinic Al9Co2 phase. High-resolution electron microscopy and electron diffraction have been extensively employed to characterize the as-solidified as well as the annealed foils. The high-resolution micrographs of the as-solidified solid solution showed the presence of clustering and D 1a - type ordering on an extremely small microscopic scale. Annealing at temperatures above 623 K resulted in the precipitation of Al9Co2 in the form of platelets arranged in a Widmanstätten pattern. Orientation relationships between the Al9Co2 platelets and the matrix have been established. Guinier-Preston zonelike platelets on close-packed {111} planes, however, have also been observed upon electron irradiation in the annealed alloys, presumably due to the enhanced diffusivity of cobalt atoms.

Type
Articles
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Suryanarayana, C., Rapidly Quenched Metals–A Bibliography 1973-1979 (IFI/Plenum, New York, 1980).Google Scholar
2Jones, H., Rapid Solidification of Metals and Alloys (The Institution of Metallurgists, London, 1982), Monograph No. 8.Google Scholar
3Cahn, R. W., in Physical Metallurgy, edited by Cahn, R. W. and Haasen, P. (Elsevier, Amsterdam, 1983), 3rd ed., p. 1780.Google Scholar
4Suryanaryana, C., Ramachandrarao, P., and Anantharaman, T. R., in Light Metals: Science and Technology, edited by Suryanarayana, C., Prasad, P. M., Malhotra, S. L., and Anantharaman, T. R. (Trans Tech, Aedermannsdorf, Switzerland, 1985), p. 85.Google Scholar
5Shechtman, D., Blech, I., Gratias, D., and Cahn, J. W., Phys. Rev. Lett. 53, 1951 (1984).CrossRefGoogle Scholar
6Rao, M. H., Sridhar, G., and Suryanarayana, C., Int. J. Rapid Solidification 1, 199 (1985).Google Scholar
7Hehman, F. and Jones, H., in Rapidly Solidified Alloys and Their Mechanical and Magnetic Properties, edited by Giessen, B. C., Polk, D. E., and Taub, A. I. (Materials Research Society, Pittsburgh, PA, 1986), Vol. 58.Google Scholar
8Ray, R. and Clemm, P., Met. Powder Rep. 41, 261 (1986).Google Scholar
9Mondolfo, L. F., Aluminium Alloys–Structure and Properties (Butterworths, London, 1976).Google Scholar
10Villars, P. and Calvert, L. D., Pearson's Handbook of Crystallographic Data for Intermetallic Phases (American Society of Metals, Metals Park, OH, 1985).Google Scholar
11Garrett, R. K. Jr., and Sanders, T. H. Jr., Mater. Sci. Eng. 60, 269 (1983).Google Scholar
12Sater, J. M. and Sanders, T. H. Jr., in Rapidly Solidified Materials, edited by Lee, P. W. and Carbonara, R. S. (American Society of Metals, Metals Park, OH, 1986), p. 357.Google Scholar
13Menon, J. and Suryanarayana, C., Z. Metallkde. (to be published).Google Scholar
14Menon, J. and Suryanarayana, C., in the Proceedings of the Xlth International Congress on Electron Microscopy, edited by Imura, T., Maruse, S., and Suzuki, T. (Japanese Society of Electron Microscopy, Tokyo, 1986), Vol. II, p. 1621.Google Scholar
15Tendeloo, G. Van and Amelinckx, S., Phys. Status Solidi A 49, 337 (1978).CrossRefGoogle Scholar
16Ruedl, E., Delavignette, P., and Amelinckx, S., Phys. Status Solidi 28, 305 (1968).CrossRefGoogle Scholar
17Bendersky, L., Metall. Trans. A 16, 683 (1985).CrossRefGoogle Scholar
18Kim, Y. W. and Jackson, A. G., Scr. Metall. 20, 777 (1986).CrossRefGoogle Scholar
19Lorimer, G. W., in Precipitation Processes in Solids, edited by Russell, K. C. and Aaronson, H. I. (American Institute of Metallurgical Engineers, Warrendale, PA, 1978), p. 87.Google Scholar
20Anantharaman, T. R., Ramachandrarao, P., Suryanarayana, C., Lele, S., and Chattopadhyay, K., Trans. Indian Inst. Met. 30, 423 (1977).Google Scholar