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Barium titanate-added lead nickel niobate ferroelectrics: Accelerated perovskite formation and dielectric properties

Published online by Cambridge University Press:  31 January 2011

Chung-Hsin Lu  and
Jai-Fang Wu
Chung-Hsin Lu*
Affiliation:
Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan, Republic of China
Jai-Fang Wu
Affiliation:
Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan, Republic of China
*
a) Author to whom all correspondence should be addressed.
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Abstract

The addition of BaTiO3 to Pb(Ni1/3Nb2/3)O3 has been confirmed to vary the formation kinetics of the perovskite solid solutions of Pb(Ni1/3Nb2/3)O3-BaTiO3, and to suppress the generation of the pyrochlore phase. A semiquantitatively calculated reaction conversion verified that increasing the BaTiO3 content significantly accelerated the formation of the perovskite solid solutions. The formed solid solutions of Pb(Ni1/3Nb2/3)O3-BaTiO3 (up to 90 mol% of BaTiO3) exhibited a cubic symmetry at room temperature. The lattice parameter monotonously decreased with an increase in the BaTiO3 content. The structural stability of the perovskite phase was found to be enhanced by the addition of BaTiO3 as well. The formed solid solutions were able to maintain the perovskite structure without decomposition when heated up to 1250 °C. The frequency dependence of the apparent Curie temperature and the diffuseness of the dielectric peak of sintered specimens were increased with increasing the BaTiO3 content up to 50 mol%. Whereas with further addition, the relaxor characteristics in the specimens became obscure, associated with lower frequency dependence and less broadening of the dielectric maximum. The largest broadening of the dielectric peak occurred at x = 0.5, implying that this composition exhibited the most disordered structure, which is probably related to the most random arrangement of B-site cations in oxygen octahedran.

Type
Articles
Information
Journal of Materials Research , Volume 11 , Issue 12 , December 1996 , pp. 3064 - 3070
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1.Myl'nikova, I. E. and Bokov, I. F., Sov. Phys. Cryst. 4, 408 (1958).Google Scholar
2.Myl'nikova, I. E. and Bokov, I. F., Sov. Phys. Solid State 3, 613 (1961).Google Scholar
3.Shrout, T. R., Swartz, S. L., and Haum, M. J., Am. Ceram. Soc. Bull 63, 808 (1984).Google Scholar
4.Yonezawa, M., Ferroelectrics 68, 181 (1986).CrossRefGoogle Scholar
5.Chung, S. T., Nagata, K., and Igarashi, H., Ferroelectr. 94, 243 (1989).CrossRefGoogle Scholar
6.Moon, J. H., Jang, H. M., and You, B. D., J. Mater. Res. 8, 3184 (1993).CrossRefGoogle Scholar
7.Belsick, J. R., Halliyal, A., Kumer, U., and Newnham, R. E., Am. Ceram. Soc. Bull. 66, 664 (1987).Google Scholar
8.Swartz, S. L. and Shrout, T. R., Mater. Res. Bull. 17, 1245 (1982).CrossRefGoogle Scholar
9.Swartz, S. L., Shrout, T. R., Schulze, W. A., and Cross, L. E., J. Am. Ceram. Soc. 67, 311 (1984).CrossRefGoogle Scholar
10.Lu, C. H. and Lee, J.T., J. Ceram. Soc. Jpn. 103, 1122 (1995).CrossRefGoogle Scholar
11.Sakaki, Y., Nagai, A., and Yoshimoto, T., NIST 804, Chem. Electr. Ceram. Mater., 99 (1991).Google Scholar
12.Lu, C. H. and Hwang, W. J., Ceram. Int. (in press).Google Scholar
13.Takahashi, S., Miyao, S., Yoneda, S., and Kuwabara, M., Jpn. J. Appl. Phys. 32, 4245 (1993).CrossRefGoogle Scholar
14.Didkovskaya, O. S., Kovalevskaya, I. P., Seryi, V. G., Klimov, V. V., and Venevtsev, Y. N., Sov. Phys. Cryst. 18, 184 (1973).Google Scholar
15.Halliyal, A., Kumar, U., Newnham, R. E., and Cross, L. E., Am. Ceram. Soc. Bull. 66, 671 (1987).Google Scholar
16.Sakurai, O., Katsumoto, M., Shinozaki, K., and Mizutani, N., J. Ceram. Soc. Jpn. 101, 607 (1993).CrossRefGoogle Scholar
17.Kang, D. H. and Yoon, K. H., J. Mater. Sci. 26, 56 (1991).CrossRefGoogle Scholar
18.Shrout, T. R. and Halliyal, A., Am. Ceram. Soc. Bull. 66, 704 (1987).Google Scholar
19.Cullity, B. D., Elements of X-ray Diffraction (Addison-Wesley Publishing Co., California, 1978), pp. 139, 520, and 524.Google Scholar
20.Ravindranathan, P., Komarneni, S., and Roy, R., J. Am. Ceram. Soc. 73, 1024 (1990).CrossRefGoogle Scholar
21.Lu, C. H. and Hwang, W. S., J. Mater. Res. 10, 2755 (1995).CrossRefGoogle Scholar
22.Uchino, K. and Nomura, S., Ferroelec. Lett. 44, 55 (1982).CrossRefGoogle Scholar