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Chemical vapor deposition of superconducting Bi-Sr-Ca-Cu-O films using fluorocarbon-based precursors

Published online by Cambridge University Press:  31 January 2011

Masanori Nemoto
Affiliation:
Scientific Research Laboratory, Central Engineering Laboratories, Nissan Motor Co., Ltd., 1, Natsushima-cho, Yokosuka, Kanagawa 237, Japan
Mitsugu Yamanaka
Affiliation:
Scientific Research Laboratory, Central Engineering Laboratories, Nissan Motor Co., Ltd., 1, Natsushima-cho, Yokosuka, Kanagawa 237, Japan
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Abstract

Superconducting Bi-Sr-Ca-Cu-O thin films have been prepared for the first time by chemical vapor deposition using triphenyl bismuth and fluorocarbon-based chelates such as bis(hexafluoroacetylacetonate)strontium, bis(hexafluoroacetylacetonate)calcium, and bis(hexafluoroacetylacetonate)copper. After annealing in air, x-ray diffraction data reveal that the films deposited on (001) SrTiO3 substrates have preferential orientation of their crystalline c-axis perpendicular to the substrate surface. Four-probe resistivity measurements reveal the onset of superconductivity at 80 K and zero resistivity at 50 K.

Type
Materials Communications
Copyright
Copyright © Materials Research Society 1990

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References

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