Hostname: page-component-cd9895bd7-jn8rn Total loading time: 0 Render date: 2024-12-28T17:28:29.897Z Has data issue: false hasContentIssue false
  • English
  • Français

Combustion synthesis of AlN with melamine as an additive

Published online by Cambridge University Press:  01 March 2006

Gunchoo Shim ,
Je-Shin Park  and
Sung-Wook Cho
Gunchoo Shim*
Affiliation:
Korea Institute of Geoscience and Mineral Resources, Yusung-gu, Daejeon 305-350, Republic of Korea
Je-Shin Park
Affiliation:
Korea Institute of Geoscience and Mineral Resources, Yusung-gu, Daejeon 305-350, Republic of Korea
Sung-Wook Cho
Affiliation:
Korea Institute of Geoscience and Mineral Resources, Yusung-gu, Daejeon 305-350, Republic of Korea
*
a) Address all correspondence to this author. e-mail: gshim@kigam.re.kr
Get access

Abstract

Melamine (C3H6N6) was used as an additive for synthesizing aluminum nitride by combustion synthesis. It was found that at least 0.1 M of melamine addition to 1 M of aluminum and 0.8 MPa of nitrogen pressure were necessary to initiate a stable reaction. In addition to melamine, however, use of aluminum nitride as a diluent and application of forced nitrogen flow yielded better results. Analyzing the reaction temperatures, reaction rates, nitrogen contents, x-ray diffraction patterns, and scanning electron microscopy photographs, the optimum conditions for synthesizing AlN were established: (i) reactants were 90 wt% (1 M Al + 0.1 M melamine) + 10 wt% AlN diluent, (ii) chamber pressure was 0.9 MPa, and (iii) nitrogen flow rate was 15 l/min. Under these conditions, aluminum nitride with the stoichiometric nitrogen content of 34 wt% could be obtained.

Keywords

AdditivesCeramicCombustion synthesis
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 3 , March 2006 , pp. 747 - 753
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Scheppard, M.: Aluminum nitride: A versatile but challenging material. Am. Ceram. Soc. Bull. 69((11)), 1801 (1990).Google Scholar
2.Mitchell, V.: Aluminum Nitride, 2nd ed. (Elsvier Science Ltd., London, UK, 1994).Google Scholar
3.Kuramoto, N., Taniguchi, H., Isao, I.: Translucent AlN ceramics. Proc. IEEE 74, 424 (1986).Google Scholar
4.Lenie, C.: Refractory articles and method of making same. U.S. Patent No. 3 108 887 (1963).Google Scholar
5.Yamashita, H., Imai, Y., Oguma, R., Hayashi, T., Tamura, M., Matsuo, H.: Production of high-purity aluminum nitride powder. Japan Patent No. 61-205606 (1986).Google Scholar
6.Serpek, O.: Process for producing compounds of aluminium and nitrogen UK Patent No. 13579 (1906).Google Scholar
7.Kuramoto, N., Taniguchi, H.: Fine powder of aluminum nitride, composition and sintered body thereof and processes for their production U.S. Patent No. 4 618 592 (1986).Google Scholar
8.Coffman, P.R., Petuskey, W.T., Dey, S.K.: Chemical synthesis of aluminum nitride powders, in Better Ceramics Through Chemistry IV, edited by Zelinski, B.J.J., Brinker, C.J., Clark, D.E., and Ulrich, D.R. (Mater. Res. Soc. Symp. Proc. 180 Pittsburgh, PA, 1990), p. 709.Google Scholar
9.Hashimoto, N., Sawada, Y., Bando, T., Yoden, H.: Preparation of aluminum nitride powder from aluminum polynuclear complexes. J. Am. Ceram. Soc. 74((6)), 1282 (1991).CrossRefGoogle Scholar
10.Ponthieu, E., Rao, L., Gengembre, L., Grimblot, J., Kaner, R.: Solid-state synthesis of aluminum nitride through a metathetical route. Solid State Ionics 63–65, 116 (1993).CrossRefGoogle Scholar
11.Lee, W.C., Tu, C.L., Weng, C.Y., Chunga, S.L.: A novel process for combustion synthesis of AlN powder. J. Mater. Res. 10((3)), 774 (1995).CrossRefGoogle Scholar
12.Kim, J.Y., Kumta, P.N.: A novel reductive nitrogenation approach for synthesizing aluminum nitride powders. Mater. Lett. 34, 188 (1998).CrossRefGoogle Scholar
13.Akiyama, T., Hirai, Y., Ishikawa, N.: Combustion synthesis of aluminum nitride from dross. Mater. Trans. 42((3)), 460 (2001).CrossRefGoogle Scholar
14.Bradshaw, S.M., Spicer, J.L.: Combustion synthesis of aluminum nitride particles and whiskers. J. Am. Ceram. Soc. 82((9)), 2293 (1999).CrossRefGoogle Scholar
15.Shin, J., Ahn, D.H., Shin, M.S., Kim, Y.S.: Self-propagating high-temperature synthesis of aluminum nitride under lower nitrogen pressures. J. Am. Ceram. Soc. 83((5)), 1021 (2000).CrossRefGoogle Scholar
16.Juang, R.C., Lee, C.J., Chen, C.C.: Combustion synthesis of hexagonal aluminum nitride powders under low nitrogen pressure. Mater. Sci. Eng. A 357, 219 (2003).Google Scholar
17.Chung, S.L., Lin, C.N., Lin, Z.X. Method for synthesis of aluminum nitride, U.S. Patent No. 6 482 384 (2002).Google Scholar
18.Dunmead, S.D., Munir, Z.A., Holt, J.B.: Gas-Solid reaction under a self-propagating combustion mode. Solid State Ionics 32((33)), 474 (1989).CrossRefGoogle Scholar
19.Dunmead, S.D., Holt, J.B., Kingman, D.D.: Simultaneous combustion synthesis and densification of AlN, in Combustion and Plasma Synthesis of High-Temperature Materials, edited by Munir, Z.A. and Holt, J.B. (VCH Publishers, Cambridge, UK, 1990), p. 186.Google Scholar
20.Golubkatnikov, K.A., Stangle, G.C., Spriggs, R.M.: The economics of advanced self-propagating high-temperature synthesis materials fabrication Am. Ceram. Soc. Bull. 72((12)), 96 (1993).Google Scholar
21.Kubaschewski, O., Alcock, C.B.: Metallurgical Thermochemistry, 5th ed., (Pergamon Press, New York, 1979), p. 268.Google Scholar