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Comment on “Homogeneity of Zr64.13Cu15.75Ni10.12Al10 bulk metallic glass,” by L-Y. Chen, Y-W. Zeng, Q-P. Cao, B-J. Park, Y-M. Chen, K. Hono, U. Vainio, Z-L. Zhang, U. Kaiser, X-D. Wang, and J-Z. Jiang [J. Mater. Res. 24, 3116 (2009)]

Published online by Cambridge University Press:  31 January 2011

Yanhui Liu  and
Wei H. Wang
Wei H. Wang*
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100080, People's Republic of China
*
a)Address all correspondence to this author. e-mail: whw@aphy.iphy.ac.cn
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Abstract

In a recent work, Chen et al. [L-Y. Chen et al., J. Mater. Res.24, 3116 (2009)] presented microstructural observation on a plastic Zr64.13Cu15.75Ni10.12Al10 bulk metallic glass (BMG) reported in Liu et al. [Y.H. Liu et al., Science315, 1385 (2007)] by using transmission electron microscopy (TEM) and anomalous small-angle x-ray scattering experiments. Based on their observation, they draw a conclusion that there are no micrometer-sized or nanometer-sized structural heterogeneities in the BMG, and the large plasticity of the BMG cannot be ascribed to the structural heterogeneities. In this comment, we show that their assessment and analysis of their observation are problematic, and it is not evident and precise to use their observation to claim that the BMG is homogeneous and the structural heterogeneity in the glass is an artifact.

Keywords

AmorphousAlloy
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Journal of Materials Research , Volume 25 , Issue 3 , March 2010 , pp. 598 - 601
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1.Chen, L-Y., Zeng, Y-W., Cao, Q-P., Park, B-J., Chen, Y-M., Hono, K., Vainio, U., Zhang, Z-L., Kaiser, U., Wang, X-D., Jiang, J-Z.Homogeneity of the Zr64.13Cu15.75Ni10.12Al10 bulk metallic glass. J. Mater. Res. 24, 3116 (2009)CrossRefGoogle Scholar
2.Liu, Y.H., Wang, G., Wang, R.J., Zhao, D.Q., Pan, M.X., Wang, W.H.Super plastic bulk metallic glasses at room temperature. Science 315, 1385 (2007)CrossRefGoogle ScholarPubMed
3.Shamiminouri, A., Liu, Y., Lewandowski, J.J.Effects of thermal exposure and test temperature on structure evolution and hardness/viscosity of an iron-based metallic glass. Metall. Mater. Trans. A 40, 1314 (2009)CrossRefGoogle Scholar
4.Ha, H.M., Miller, J.R., Payer, J.H.Devitrification of Fe-based amorphous metal SAM 1651 and the effect of heat-treatment on corrosion behavior. J. Electrochem. Soc. 156, C246 (2009)CrossRefGoogle Scholar
5.Du, X.H., Huang, J.C., Hsieh, K.C., Lai, Y.H., Chen, H.M., Jang, J.S.C., Liaw, P.K.Two-glassy-phase bulk metallic glass with remarkable plasticity. Appl. Phys. Lett. 91, 131901 (2007)CrossRefGoogle Scholar
6.Du, X.H., Huang, J.C., Hsieh, K.C., Jang, J.S.C., Liaw, P.K., Chen, H.M., Chou, H.S., Lai, Y.H.Designing ductile Zr-based bulk metallic glasses with phase separated microstructure. Adv. Eng. Mater. 11, 387(2009)CrossRefGoogle Scholar
7.Ichitsubo, T., Matsubara, E., Yamamoto, T., Chen, H.S., Nishiyama, N., Saida, J., Anazawa, K.Microstructure of fragile metallic glasses inferred from ultrasound-accelerated crystallization in Pd-based metallic glasses. Phys. Rev. Lett. 95, 245501 (2005)CrossRefGoogle ScholarPubMed
8.Sun, B.B., Wang, Y.B., Wen, J., Yang, H., Sui, M.L., Wang, J.Q., Ma, E.Artifacts induced in metallic glasses during TEM sample preparation. Scr. Mater. 53, 805 (2005)CrossRefGoogle Scholar
9.Chang, H.J., Park, E.S., Kim, Y.C., Kim, D.H.Observation of artifact-free amorphous structure in Cu–Zr-based alloy using transmission electron microscopy. Mater. Sci. Eng., A 406, 119 (2005)CrossRefGoogle Scholar
10.Wang, J.G., Zhao, D.Q., Pan, M.X., Shek, C.H., Wang, W.H.Mechanical heterogeneity and mechanism of plasticity in metallic glasses. Appl. Phys. Lett. 94, 031904 (2009)CrossRefGoogle Scholar
11.Yu, H.B., Hu, J., Xia, X.X., Sun, B.A., Li, X.X., Wang, W.H., Bai, H.Y.Stress induced structural inhomogeneity and plasticity of bulk metallic glasses. Scr. Mater. 61, 640 (2009)CrossRefGoogle Scholar
12.Ichitsubo, T., Hosokawa, S., Matsuda, K., Matsubara, E., Nishiyama, N., Tsutsui, S., Baron, A.Q.R.Nanoscale elastic inhomogeneity of a Pd-based metallic glass: Sound velocity from ultrasonic and inelastic x-ray scattering experiments. Phys. Rev. B. 76, 140201(R) (2007)CrossRefGoogle Scholar
13.Nagahama, D., Ohkubo, T., Hono, K.Crystallization of Ti36Zr24Be40 metallic glass. Scr. Mater. 49, 729 (2003)CrossRefGoogle Scholar
14.Chen, Y.M., Ohkubo, T., Mukai, T., Hono, K.Structure of shear bands in Pd40Ni40P20 bulk metallic glass. J. Mater. Res. 24, 1 (2009)CrossRefGoogle Scholar
15.Lee, M.H., Lee, J.K., Kim, K.T., Thomas, J., Das, J., Kühn, U., Eckert, J.Deformation-induced microstructural heterogeneity in monolithic Zr44Ti11Cu9.8Ni10.2Be25 bulk metallic glass. Phys. Status Solidi RRL 3, 46 (2009)CrossRefGoogle Scholar
16.Yu, H.B., Wang, W.H., Zhang, J.L., Shek, C.H., Bai, H.Y.Statistic analysis of the mechanical behavior of bulk metallic glasses. Adv. Eng. Mater. 11, 370 (2009)CrossRefGoogle Scholar
17.Pauly, S., Liu, G., Wang, G., Kühn, U., Mattern, N., Eckert, J.Microstructural heterogeneities governing the deformation of Cu47.5Zr47.5Al5 bulk metallic glass composites. Acta Mater. 57, 5445 (2009)CrossRefGoogle Scholar
18.Hofmann, D.C., Suh, J.Y., Wiest, A., Duan, G., Lind, M.L., Demetriou, M.D., Johnson, W.L.Designing metallic glass matrix composites with high toughness and tensile ductility. Nature 451, 1085 (2008)CrossRefGoogle ScholarPubMed
19.Das, J., Tang, M.B., Kim, K.B., Theissmann, R., Baier, F., Wang, W.H., Eckert, J.‘‘Work-hardenable’’ ductile bulk metallic glass. Phys. Rev. Lett. 94, 205501 (2005)CrossRefGoogle ScholarPubMed
20.Yao, K.F., Ruan, F., Yang, Y.Q., Chen, N.Superductile bulk metallic glass. Appl. Phys. Lett. 88, 122106 (2006)CrossRefGoogle Scholar
21.Sharma, P., Yubuta, K., Kimura, H., Inoue, A.Brittle metallic glass deforms plastically at room temperature in glassy multilayers. Phys. Rev. B 80, 024106 (2009)CrossRefGoogle Scholar
22.Zhang, J.L., Yu, H.B., Lu, J.X., Bai, H.Y., Shek, C.H.Enhancing plasticity of Zr46.75Ti8.25Cu7.5Ni10Be27.5 bulk metallic glass by precompression. Appl. Phys. Lett. 95, 071906 (2009)CrossRefGoogle Scholar
23.He, L., Zhong, M.B., Han, Z.H., Zhao, Q., Jiang, F., Sun, J.Orientation effect of pre-introduced shear bands in a bulk-metallic glass on its “work-ductilising”. Mater. Sci. Eng., A 496, 285 (2008)CrossRefGoogle Scholar
24.Kim, K.B., Das, J., Baier, F., Tang, M.B., Wang, W.H., Eckert, J.Heterogeneity of a Cu47.5Zr47.5Al5 bulk metallic glass. Appl. Phys. Lett. 88, 051911 (2006)CrossRefGoogle Scholar
25.Lunkenheimer, P., Schneider, U., Brand, R., Loidl, A.Glassy dynamics. Contemp. Phys. 41, 15 (2000)CrossRefGoogle Scholar