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Composition-controlled ternary Rh–Pd–Pt solid-solution alloy nanoparticles by laser irradiation of mixed solution of metallic ions

Published online by Cambridge University Press:  09 April 2014

Md Samiul Islam Sarker ,
Takahiro Nakamura  and
Shunichi Sato
Md Samiul Islam Sarker*
Affiliation:
Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Aoba-ku, Sendai 980-8577, Japan; and Department of Physics, University of Rajshahi, Rajshahi 6205, Bangladesh
Takahiro Nakamura
Affiliation:
Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Aoba-ku, Sendai 980-8577, Japan
Shunichi Sato
Affiliation:
Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Aoba-ku, Sendai 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: samiul@mail.tagen.tohoku.ac.jp
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Abstract

We present a bottom-up fabrication route to fabricate solid-solution Rh–Pd–Pt ternary alloy nanoparticles (NPs), with well-controlled compositions through femtosecond laser irradiation of a mixed solution of metallic ions, without any reducing agents and complicated processes. The structure of fabricated NPs was crystalline, and formation of solid-solution alloy formation was confirmed by electron and x-ray diffraction measurements. The crystalline nature of alloy NPs was also confirmed through high-resolution transmission electron microscope measurement. According to energy dispersive spectroscopy analysis, elemental composition of an individual NP was almost the same as the initial feeding ratio of ions in the mixed solutions. The electronic state of the element in alloy NPs was confirmed to be pure metal by XPS measurement. The structural studies of Rh–Pd–Pt NPs suggested that the demonstrated technique opens up a new dimension for the fabrication of NPs, which has well-controlled properties for practical use in various fields.

Keywords

Rh–Pd–Pt alloy NPssolid-solutionfemtosecond lasercatalyst

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Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 7 , 14 April 2014 , pp. 856 - 864
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Link, S., Wang, Z.L., and El-Sayed, M.A.: Alloy formation of gold–silver nanoparticles and the dependence of the plasmon absorption on their composition. J. Phys. Chem. B 103, 3529 (1999).CrossRefGoogle Scholar
RF. Service: Small clusters hit the big time. Science 271, 920 (1996).CrossRefGoogle Scholar
Zeng, Y., Wang, Y., Jiang, J., and Jin, Z.: Rh nanoparticle catalysed hydrogenation of olefins in the thermoregulated ionic liquid. Catal. Commun. 19, 70 (2012).CrossRefGoogle Scholar
Renzas, J.R., Huang, W., Zhang, Y., Grass, M.E., and Somorjai, G.A.: Rh1-xPdx nanoparticle composition dependence in CO oxidation by NO. Catal. Lett. 141, 235 (2011).CrossRefGoogle Scholar
Zhang, H. and Toshima, N.: Preparation of novel Au-Pt-Ag trimetallic nanoparticles and their high catalytic activity for aerobic glucose oxidation. Appl. Catal. A: General 400, 9 (2011).CrossRefGoogle Scholar
Newton, M.A., Jyoti, B., Dent, A.J., Diaz-Moreno, S., Fiddy, S.G., and Evans, J.: The impact of phase changes, alloying and segregation in supported RhPd catalysts during selective NO reduction by H2. Chem. Phys. Chem. 5, 1056 (2004).CrossRefGoogle ScholarPubMed
Renzas, J.R., Huang, W., Zhang, Y., Grass, M.E., Hoang, D.T., Alayoglu, S., Butcher, D.R., Tao, F.F., Liu, Z., and Somoraji, G.A.: Rh(1-x)Pd(x) nanoparticle composition dependence in CO oxidation by oxygen: Catalytic activity enhancement in bimetallic systems. Phys. Chem. Chem. Phys. 13, 2556 (2010).CrossRefGoogle ScholarPubMed
Siepen, K., Bönnemann, H., Brijoux, W., Rothe, J., and Hormes, J.: EXAFS/XANES, chemisorption and IR investigation of colloidal Pt/Rh bimetallic catalysts. Appl. Organomet. Chem. 14, 549 (2000).3.0.CO;2-J>CrossRefGoogle Scholar
Lyman, C.E., Lakis, R.E., and Stenger, H.G.: X-ray emission spectrometry of phase separation in Pt-Rh nanoparticles for nitric oxide reduction. Ultramicroscopy 58, 25 (1995).CrossRefGoogle Scholar
Zhang, X., Zhang, F., and Chan, K.Y.: Preparation of Pt–Ru–Co trimetallic nanoparticles and their electrocatalytic properties. Catal. Commun. 5, 749 (2004).CrossRefGoogle Scholar
Wang, L. and Yamauchi, Y.: Strategic synthesis of trimetallic Au@Pd@Pt core-shell nanoparticles from Poly(vinylpyrrolidone)-based aqueous solution toward highly active electrocatalysts. Chem. Mater. 23, 2457 (2011).CrossRefGoogle Scholar
Zhang, H. and Toshima, N.: Glucose oxidation using Au-containing bimetallic and trimetallic nanoparticles. Catal. Sci. Technol. 3, 268 (2013).CrossRefGoogle Scholar
Matsushita, T., Shiraishi, Y., Horiuchi, S., and Toshima, N.: Synthesis and catalysis of polymer-protected Pd-Ag-Rh trimetallic nanoparticles with a core–shell structure. Bull. Chem. Soc. Jpn. 80, 1217 (2007).CrossRefGoogle Scholar
Tsai, S.H., Liu, Y.H., Wu, P.L., and Yeh, C.H.: Preparation of Au–Ag–Pd trimetallic nanoparticles and their application as catalysts. J. Mater. Chem. 13, 978 (2003).CrossRefGoogle Scholar
Bond, G.C.: The electronic structure of platinum-gold alloy particles. Platinum. Met. Rev. 51, 63 (2007).CrossRefGoogle Scholar
Herbani, Y., Nakamura, T., and Sato, S.: Femtosecond laser-induced formation of gold rich nanoalloys from the aqueous mixture of gold-silver ions. J. Nanomater. 2010, 154210 (2010).CrossRefGoogle Scholar
Nakamura, T., Herbani, Y., and Sato, S.: Fabrication of solid-solution gold-platinum nanoparticles with controllable compositions by high-intensity laser irradiation of solution. J. Nanopart. Res. 14, 785 (2012).CrossRefGoogle Scholar
Sarker, M.S.I., Nakamura, T., Herbani, Y., and Sato, S.: Fabrication of Rh based solid solution bimetallic alloy nanoparticles with fully tunable composition through femtosecond laser irradiation in aqueous solution. Appl. Phys. A 110, 145 (2013).CrossRefGoogle Scholar
Herbani, Y., Nakamura, T., and Sato, S.: Synthesis of platinum-based binary and ternary alloy nanoparticles in intense laser field. J. Coll. Interface Sci. 375, 78 (2012).CrossRefGoogle ScholarPubMed
Pommeret, S., Gobert, F., Mostafavi, M., Lampre, I., and Mialocq, J.C.: Femtochemistry of hydrated electron at decimolar concentration. J. Phys. Chem. A 105, 11400 (2001).CrossRefGoogle Scholar
Chin, S.L. and Legacé, S.: Generation of H2, O2 and H2O2 from water by the use of intense femtosecond laser pulses and the possibility of laser sterilization. Appl. Opt. 35, 907 (1996).CrossRefGoogle Scholar
Yuge, K.: Concentration effects on segregation behavior of Pt-Rh nanoparticles. Phys Rev B 84, 085451 (2011).CrossRefGoogle Scholar
Vegard, L. and Dale, H.: Untersuchungen ueber Mischkristalle und Legierungen. J. Kristallogr. 67, 148 (1928).Google Scholar
Jakobi, J., Menendez-Manjon, A., Chakravadhanula, V.S.K., Kienle, L., Wagener, P., and Barcikowski, S.: Stoichiometry of alloy nanoparticles from laser ablation of PtIr in acetone and their electrophoretic deposition on PtIr electrodes. Nanotechnology 22, 145601 (2011).CrossRefGoogle ScholarPubMed
Kuhn, H.R. and Günter, D.: Elemental fractionation studies in laser ablation inductively coupled plasma mass spectrometry on laser-induced brass aerosols. Anal. Chem. 75, 747 (2003).CrossRefGoogle ScholarPubMed
Christ, B.V.: Hand Book of Monochromatic XPS Spectra (Wiley, New York, 2000).Google Scholar
Park, J.Y., Zhang, Y., Grass, M., Zhang, T., and Somoraji, G.A.: Tuning of catalytic CO oxidation by changing composition of Rh-Pt bimetallic nanoparticles. Nano. Lett. 8, 673 (2008).CrossRefGoogle ScholarPubMed