Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-10T12:35:21.754Z Has data issue: false hasContentIssue false

Cu2O nanoparticles supported on carbon nanofibers as a cost-effective and efficient catalyst for RhB and phenol degradation

Published online by Cambridge University Press:  22 August 2017

Yongkun Liu
Affiliation:
Department of Polymer Materials, Zhejiang Sci-Tech University, Hangzhou 310018, China
Qin Huang
Affiliation:
Department of Polymer Materials, Zhejiang Sci-Tech University, Hangzhou 310018, China
Guohua Jiang*
Affiliation:
Department of Polymer Materials, Zhejiang Sci-Tech University, Hangzhou 310018, China; National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, China; and Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Hangzhou 310018, China
Depeng Liu
Affiliation:
Department of Polymer Materials, Zhejiang Sci-Tech University, Hangzhou 310018, China; and National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, China
Weijiang Yu
Affiliation:
Department of Polymer Materials, Zhejiang Sci-Tech University, Hangzhou 310018, China; and National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, China
*
a) Address all correspondence to this author. e-mail: ghjiang_cn@zstu.edu.cn
Get access

Abstract

In this work, the hybrid carbon nanofibers (Cu2O/CNFs) containing cuprous oxide (Cu2O) nanoparticles were prepared by a convenient electrospinning method and following a carbonization treatment. The morphology, composition, and microstructure of the Cu2O/CNFs were characterized by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffractometer. The as-prepared Cu2O/CNFs exhibited a stronger absorption in the range of 250–700 nm. The band gap energy of the Cu2O/CNFs was estimated to be 2.0 eV. Due to the synergistic effect between photocatalytic activity of Cu2O and excellent adsorption capacity of CNFs, the obtained Cu2O/CNFs exhibited excellent photocatalytic activity for degradation of rhodamine B (RhB) and phenol. The possible mechanism for degradation of RhB and phenol degradation were also discussed. The resultant hybrid carbon composites offer the significant advantages, such as low dosage, high catalytic activity, easy recycling, and excellent stability. We hope that the resultant hybrid composite Cu2O/CNFs could be applied as catalytic materials for further application in the future.

Type
Articles
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

b)

These authors contributed equally to this work.

Contributing Editor: Xiaobo Chen

References

REFERENCES

Ho, Y.S., Porter, J.F., and Mckay, G.: Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: Copper, nickel and lead single component systems. Water, Air, Soil Pollut. 141, 1 (2002).Google Scholar
Chen, D.W. and Ray, A.K.: Removal of toxic metal ions from wastewater by semiconductor photocatalysis. Chem. Eng. Sci. 56, 1561 (2001).CrossRefGoogle Scholar
Singh, S., Barick, K.C., and Bahadur, D.: Fe3O4 embedded ZnO nanocomposites for the removal of toxic metal ions, organic dyes and bacterial pathogens. J. Mater. Chem. A 1, 3325 (2013).Google Scholar
Shahat, A., Hassan, H.M.A., and Azzazy, H.M.E.: Optical metal-organic framework sensor for selective discrimination of some toxic metal ions in water. Anal. Chim. Acta 793, 90 (2013).Google Scholar
Guldhe, A., Singh, B., Mutanda, T., Permaul, K., and Bux, F.: Advances in synthesis of biodiesel via enzyme catalysis: Novel and sustainable approaches. Renewable Sustainable Energy Rev. 41, 1447 (2015).Google Scholar
Gao, B., Yang, L.Y., Wang, X.R., Zhao, J.C., and Sheng, G.Y.: Influence of modified soils on the removal of diesel fuel oil from water and the growth of oil degradation micro-organism. Chemosphere 41, 419 (2000).Google Scholar
Li, Q.Y., Luo, Y., Hou, B., and Han, Z.X.: Synthesis and mechanism of flocculating-decolorizing agent PAD used for polymer-sulphonated drilling wastewater. J. Residuals Sci. Technol. 13, 135 (2016).CrossRefGoogle Scholar
Turchi, C.S. and Ollis, D.F.: Photocatalytic degradation of organic water contaminants: Mechanisms involving hydroxyl radical attack. J. Catal. 122, 178 (1992).Google Scholar
Rosal, R., Rodríguez, A., Perdigónmelón, J.A., Petre, A., Gómez, M.J., and Agüera, A.: Occurrence of emerging pollutants in urban wastewater and their removal through biological treatment followed by ozonation. Water Res. 4, 578 (2010).CrossRefGoogle Scholar
Rijn, J.V.: The potential for integrated biological treatment systems in ecirculating fish culture—A review. Aquaculture 139, 181 (1996).CrossRefGoogle Scholar
Ried, A., Mielcke, J., Wieland, A., Schaefer, S., and Sievers, M.: An overview of the integration of ozone systems in biological treatment steps. Mucosal Immunol. 3, 461 (2010).Google Scholar
Hoffmann, M.R., Martin, S.T., Choi, W.Y., and Bahnemann, D.W.: Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69 (1995).Google Scholar
Mills, A. and Hunte, S.L.: An overview of semiconductor photocatalysis. J. Photochem. Photobiol., A 108, 1 (1997).CrossRefGoogle Scholar
Xiang, Q.J., Yu, J.G., and Jaroniec, M.: Graphene-based semiconductor photocatalysts. ChemInform 43, 782 (2012).CrossRefGoogle Scholar
Liu, Y.K., Jiang, G.H., Li, L., Chen, H., Huang, Q., Du, X.X., and Tong, Z.Z.: Electrospun CeO2/Ag@carbon nanofiber hybrids for selective oxidation of alcohols. Powder Technol. 305, 597 (2016).CrossRefGoogle Scholar
Chen, H., Jiang, G.H., Yu, W.J., Liu, D.P., Liu, Y.K., Li, L., Huang, Q., Tong, Z.Z., and Chen, W.X.: Preparation of electrospun ZnS-loaded hybrid carbon nanofiberic membranes for photocatalytic applications. Powder Technol. 298, 1 (2016).Google Scholar
Nakata, K. and Fujishima, A.: TiO2 photocatalysis: Design and applications. J. Photochem. Photobiol., C 13, 169 (2012).CrossRefGoogle Scholar
Jiang, G.H., Zheng, X.Y., Wang, Y., Li, T.W., and Sun, X.K.: Photo-degradation of methylene blue by multi-walled carbon nanotubes/TiO2, composites. Powder Technol. 207, 465 (2011).CrossRefGoogle Scholar
Linsebigler, A., Guangquan, L., and Yates, J.: Photocatalysis on TiO2 surfaces: Principles, mechanisms, and selected results. Chem. Rev. 95, 735 (1995).Google Scholar
Zhu, K., Neale, N., Miedaner, A., and Frank, A.: Enhanced charge-collection efficiencies and light scattering in dye-sensitized solar cells using oriented TiO2 nanotubes arrays. Nano Lett. 7, 69 (2007).Google Scholar
Xiao, F.X.: Construction of highly ordered ZnO–TiO2 nanotube arrays (ZnO/TNTs) heterostructure for photocatalytic application. ACS Appl. Mater. Interfaces 4, 7055 (2016).CrossRefGoogle Scholar
Konstantinou, I.K. and Albanis, T.A.: TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: Kinetic and mechanistic investigations: A review. Appl. Catal., B 49, 1 (2004).Google Scholar
Khodayari, R. and Odenbrand, I.: Deactivating effects of lead on the selective catalytic reduction of nitric oxide with ammonia over a V2O5/WO3/TiO2 catalyst for waste incineration applications. Ind. Eng. Chem. Res. 37, 1196 (2016).Google Scholar
Liu, R., Ye, H.Y., Xiong, X.P., and Liu, H.Q.: Fabrication of TiO2/ZnO composite nanofibers by electrospinning and their photocatalytic property. Mater. Chem. Phys. 121, 432 (2010).Google Scholar
Fan, C.M., Min, Y.Q., Hao, X.G., Sun, Y.P., Li, X.J., and Li, F.B.: Adsorption and photocatalytic degradation of phenol over TiO2/ACF. Trans. Nonferrous Met. Soc. China 13, 452 (2003).Google Scholar
Zewge, F., Krol, R.V.D., and Appel, P.W.: Photoelectrocatalytic removal of color from water using TiO2 and TiO2/Cu2O. Bull. Chem. Soc. Ethiop. 22, 27 (2008).Google Scholar
Fang, Y., Wang, R.J., Jiang, G.H., Jin, H., Wang, Y., Sun, X.K., Wang, S., and Wang, T.: CuO/TiO2, nanocrystals grown on graphene as visible-light responsive photocatalytic hybrid materials. Bull. Mater. Sci. 35, 495 (2012).Google Scholar
Wei, Z., Jiang, G.H., Shen, L., Li, X., Wang, X.H., and Chen, W.X.: Preparation of Mn-doped BiOBr microspheres for efficient visible-light-induced photocatalysis. MRS Commun. 3, 124 (2013).Google Scholar
Jiang, G.H., Tang, B.L., Chen, H., Liu, Y.K., Li, L., Huang, Q., and Chen, W.X.: Controlled growth of hexagonal Zn2GeO4 nanorods on carbon fibers for photocatalytic oxidation of p-toluidine. RSC Adv. 5, 6125 (2015).Google Scholar
Jiang, G.H., Li, X., Wei, Z., Jiang, T.T., Du, X.X., and Chen, W.X.: Growth of N-doped BiOBr nanosheets on carbon fibers for photocatalytic degradation of organic pollutants under visible light irradiation. Powder Technol. 260, 84 (2014).CrossRefGoogle Scholar
Hara, M., Kondo, T., Komoda, M., Ikeda, S., Kondo, J.N., Domen, K., Hara, M., Shinohara, K., and Tanaka, A.: Cu2O as a photocatalyst for overall water splitting under visible light irradiation. Chem. Commun. 3, 357 (1998).Google Scholar
Chen, S.F., Zhang, S.J., Liu, W., and Zhao, W.: Study on the photocatalytic activity of p–n junction photocatalyst Cu2O/TiO2 . J. Nanosci. Nanotechnol. 9, 4397 (2009).Google Scholar
Niu, F.X., Fu, F., Gao, X.M., and Zhang, X.M.: Preparation of WO3/Cu2O photocatalyst and its application to photocatalytical degradation of phenol. Spec. Petrochem. 31, 6 (2014).Google Scholar
He, J., Shao, D.W., Zheng, L.C., and Zheng, R.K.: Construction of Z-scheme Cu2O/Cu/AgBr/Ag photocatalyst with enhanced photocatalytic activity and stability under visible light. Appl. Catal., B 203, 917 (2017).Google Scholar
Xu, H.L., Wang, W.Z., and Zhu, W.: Shape evolution and size-controllable synthesis of Cu2O octahedra and their morphology-dependent photocatalytic properties. J. Phys. Chem. B 110, 13829 (2006).Google Scholar
Zhao, M., Shang, F.J., Song, Y., Wang, F., Zhou, Z.T., Lv, J.G., and Zi, Z.F.: Effect of solution concentration on surface morphology, chemical composition and photoresponse of CuO/Cu2O composite thin films grown by hydrothermal synthesis. J. Mater. Sci. 25, 4877 (2014).Google Scholar
Nian, J.N., Hu, C.C., and Teng, H.: Electrodeposited p-type Cu2O for H2, evolution from photoelectrolysis of water under visible light illumination. Int. J. Hydrogen Energy 33, 2897 (2008).Google Scholar
Zhang, G.Q., Yu, L., Wu, H.B., Hoster, H.E., and Lou, X.W.: Formation of ZnMn2O4 ball-in-ball hollow microspheres as a high-performance anode for lithium-ion batteries. Adv. Mater. 24, 4609 (2012).Google Scholar
Gao, Z.Y., Liu, J.L., Xu, F., Wu, D.P., Wu, Z.L., and Jiang, K.: One-pot synthesis of graphene-cuprous oxide composite with enhanced photocatalytic activity. Solid State Sci. 14, 276 (2012).Google Scholar
Li, J.Y., Xiong, S.L., Pan, J., and Qian, Y.: Hydrothermal synthesis and electrochemical properties of urchin-like core–shell copper oxide nanostructures. J. Phys. Chem. C 114, 9645 (2010).CrossRefGoogle Scholar
Tahir, M. and Amin, N.A.S.: Photocatalytic CO2, reduction with H2, as reductant over copper and indium co-doped TiO2, nanocatalysts in a monolith photoreactor. Appl. Catal., A 493, 90 (2015).CrossRefGoogle Scholar
Yang, D.S., Chaudhari, S., Rajesh, K.P., and Yu, J.S.: Preparation of nitrogen-doped porous carbon nanofibers and the effect of porosity, electrical conductivity, and nitrogen content on their oxygen reduction performance. ChemCatChem 6, 1236 (2014).Google Scholar
Yu, B., Liu, Y.K., Jiang, G.H., Liu, D.P., Yu, W.J., Chen, H., Li, L., Huang, Q., and Tong, Z.Z.: Preparation of electrospun Ag nanoparticles and g-C3N4 loaded composite carbon nanofibers for catalytic applications. Mater. Res. Express 4, 015603 (2017).CrossRefGoogle Scholar
Liu, Y.K., Jiang, G.H., Li, L., Chen, H., Huang, Q., Jiang, T.T., and Du, X.X.: Silver nanoparticles supported on electrospun polyacrylonitrile nanofibrous mats for catalytic applications. MRS Commun. 6, 31 (2016).Google Scholar
Chen, H., Jiang, G.H., Jiang, T.T., Li, L., Liu, Y.K., Huang, Q., and Chen, W.X.: Preparation of Mn-doped ZrO2/TiO2 photocatalysts for efficient degradation of rhodamine B. MRS Commun. 5, 525 (2015).CrossRefGoogle Scholar
Liu, Y.K., Jiang, G.H., Li, L., Chen, H., Huang, Q., Jiang, T.T., Du, X.X., and Chen, W.X.: Preparation of Au/PAN nanofibrous membranes for catalytic reduction of 4-nitrophenol. J. Mater. Sci. 50, 8120 (2015).Google Scholar
Chen, H., Jiang, G.H., Yu, W.J., Liu, D.P., Liu, Y.K., Li, L., Huang, Q., and Tong, Z.Z.: Electrospun carbon nanofibers coated with urchin-like ZnCo2O4 nanosheets as a flexible electrode material. J. Mater. Chem. A 4, 5958 (2016).Google Scholar
Mi, E.J. and Ahn, K.H.: Fluorogenic and chromogenic detection of palladium species through a catalytic conversion of a rhodamine B derivative. Org. Lett. 12, 2790 (2012).Google Scholar
Mahlambi, M.M., Mahlangu, O.T., Vilakati, G.D., and Mamba, B.B.: Visible light photodegradation of rhodamine B dye by two forms of carbon-covered alumina supported TiO2/polysulfone membranes. Ind. Eng. Chem. Res. 53, 5709 (2014).Google Scholar
Fang, H.H.P. and Chan, O.C.: Toxicity of phenol towards anaerobic biogranules. Water Res. 31, 2229 (1997).Google Scholar
Daâssi, D., Belbahri, L., Vallat, A., Woodward, S., Nasri, M., and Mechichi, T.: Enhanced reduction of phenol content and toxicity in olive mill wastewaters by a newly isolated strain of Coriolopsis gallica . Environ. Sci. Pollut. Res. 21, 1746 (2014).CrossRefGoogle ScholarPubMed
Keweloh, H., Heipieper, H.J., and Rehm, H.J.: Protection of bacteria against toxicity of phenol by immobilization in calcium alginate. Appl. Microbiol. Biotechnol. 31, 383 (1989).Google Scholar
Huang, Q., Jiang, G.H., Chen, H., Li, L., Liu, Y.K., Tong, Z.Z., and Chen, W.X.: Hierarchical nanostructures of BiOBr/AgBr on electrospun carbon nanofibers with enhanced photocatalytic activity. MRS Commun. 6, 61 (2016).Google Scholar
Kuo, C.H. and Huang, M.: Fabrication of truncated rhombic dodecahedral Cu2O nanocages and nanoframes. J. Am. Chem. Soc. 130, 12815 (2008).Google Scholar
He, F., Qin, X., Zhang, H., Yang, Y.Q., Zhang, X.Y., and Yang, Y.: Characterization of laccase isoenzymes from the white-rot fungus Ganoderma, sp.En3 and synergistic action of isoenzymes for dye decolorization. J. Chem. Technol. Biotechnol. 90, 2265 (2015).Google Scholar
Asgher, M., Bhatti, H.N., Ashraf, M., and Legge, R.L.: Recent developments in biodegradation of industrial pollutants by white rot fungi and their enzymes. Biodegradation 19, 771 (2008).Google Scholar
Sun, L.L., Wang, G.H., Hao, R., Han, D.Y., and Cao, S.: Solvothermal fabrication and enhanced visible light photocatalytic activity of Cu2O-reduced graphene oxide composite microspheres for photodegradation of rhodamine B. Appl. Surf. Sci. 358, 91 (2015).Google Scholar
Abulizi, A., Yang, G.H., and Zhu, J.J.: One-step simple sonochemical fabrication and photocatalytic properties of Cu2O–rGO composites. Ultrason. Sonochem. 21, 129 (2014).CrossRefGoogle ScholarPubMed
Kurian, M. and Sugunan, S.: Wet peroxide oxidation of phenol over mixed pillared montmorillonites. Chem. Eng. J. 115, 139 (2006).CrossRefGoogle Scholar
Chu, L.B., Wang, J.L., Dong, J., Liu, H.Y., and Sun, X.L.: Treatment of coking wastewater by an advanced Fenton oxidation process using iron powder and hydrogen peroxide. Chemosphere 86, 409 (2012).Google Scholar
Szewzyk, U., Szewzyk, R., and Schink, B.: Methanogenic degradation of hydroquinone and catechol via reductive dehydroxylation to phenol. FEMS Microbiol. Ecol. 31, 79 (1985).Google Scholar
Mijangos, F., Varona, F., and Villota, N.: Changes in solution color during phenol oxidation by Fenton reagent. Environ. Sci. Technol. 40, 5538 (2006).Google Scholar
Santos, A., Yustos, P., Quintanilla, A., Rodríguez, S., and García-Ochoa, F.: Route of the catalytic oxidation of phenol in aqueous phase. Appl. Catal., B 39, 97 (2002).CrossRefGoogle Scholar
Duprez, D., Delanoë, F., Barbier, J., Isnard, P., and Blanchard, G.: Catalytic oxidation of organic compounds in aqueous media. Catal. Today 29, 317 (1996).Google Scholar
Wang, H., Yu, X.J., and Sun, D.Z.: Study on the degradation mechanism of phenol in a new electrochemical oxidation system. Acta Sci. Circumstantiae 25, 901 (2005).Google Scholar
Chang, Y.C., Ko, F.H., Ko, C.J., and Chu, T.C.: Probing the microwave degradation mechanism of phenol-containing polymeric compounds by sample pretreatment and GC-MS analysis. Anal. Chim. Acta 526, 121 (2004).Google Scholar
Turki, A., Guillard, C., Dappozze, F., Ksibi, Z., Berhault, G., and Kochkar, H.: Phenol photocatalytic degradation over anisotropic TiO2 nanomaterials: Kinetic study, adsorption isotherms and formal mechanisms. Appl. Catal., B 163, 404 (2015).Google Scholar
Dang, T.T.T., Le, S.T.T., Channei, D., Khanitchaidecha, W., and Nakaruk, A.: Photodegradation mechanisms of phenol in the photocatalytic process. Res. Chem. Intermed. 41, 1 (2016).Google Scholar
Zhang, H., Zhao, L.X., Geng, F.L., Guo, L.H., Wan, B., and Yang, Y.: Carbon dots decorated graphitic carbon nitride as an efficient metal-free photocatalyst for phenol degradation. Appl. Catal., B 180, 656 (2016).Google Scholar