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Dynamic indentation response of ZrHf-based bulk metallic glasses

Published online by Cambridge University Press:  03 March 2011

Ghatu Subhash*
Affiliation:
Mechanical Engineering-Engineering Mechanics Department, Michigan Technological University, Houghton, Michigan 49931
Hongwen Zhang
Affiliation:
Department of Materials Science & Engineering, Michigan Technological University, Houghton, Michigan 49931
*
a)Address all correspondence to this author. Present address: Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611. e-mail: Subhash@ufl.edu
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Abstract

Static and dynamic Vickers indentations were performed on ZrHf-based bulk amorphous alloys. A decrease in indentation hardness was observed at higher strain rates compared with static indentation hardness. For equivalent loads, dynamic indentations produced more severe deformation features on the loading surface than static indentations. Using bonded interface technique, the induced shear band patterns beneath the indentations were studied. In static indentations, the majority of the deformation was primarily accommodated by closely spaced semicircular shear bands surrounding the indentation. In dynamic indentations two sets of widely spaced semicircular shear bands with two different curvatures were observed. The observed shear band patterns and softening in hardness were rationalized based on the variations in the confinement pressure, strain rate, and temperature within the indentation region during dynamic indentations. It is also proposed that free volume migration and formation of nano-voids leading to cracking are favored due to adiabatic heating and consequently cause the observed softening at high strain rates.

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Articles
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 10, 42 (1999).CrossRefGoogle Scholar
2Inoue, A.: Bulk Amorphous Alloys: Preparation and Fundamental Characteristics. Switzerland: Trans Tech Publication (1998).Google Scholar
3Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 27 (2000).CrossRefGoogle Scholar
4Luborsky, F.E.: Amorphous Metallic Alloys. (Butterworth, London, 1983).CrossRefGoogle Scholar
5He, Y., Poon, S.J., and Shiflet, G.J.: Synthesis and properties of metallic glasses that contain aluminum. Science 241, 1640 (1988).CrossRefGoogle ScholarPubMed
6Inoue, A.: Bulk Amorphous Alloys: Preparation and Fundamental Characteristics. Switzerland, Trans Tech Publication (1998).Google Scholar
7Jana, S., Ramamurty, U., Chattopadhyay, K., and Kawamura, Y.: Subsurface deformation during Vickers indentation of bulk metallic glasses. Mater. Sci. Eng., A 375–377, 1191 (2004).CrossRefGoogle Scholar
8Jana, S., Bhowmick, R., Kawamura, Y., Chattopadhyay, K., and Ramamurty, U.: Deformation morphology underneath the Vickers indent in a Zr-based bulk metallic glass. Intermetallics 12, 1097 (2004).CrossRefGoogle Scholar
9Ramamurty, U., Jana, S., Kawamura, Y., and Chattopadhyay, K.: Hardness and plastic deformation in a bulk metallic glass. Acta Mater. 53, 705 (2005).CrossRefGoogle Scholar
10Zhang, H.W., Jing, X.N., Subhash, G., Kecskes, L.J., and Dowding, R.J.: Investigation of shear band evolution in amorphous alloys beneath a Vickers indentation. Acta Mater. 53, 3849 (2005).CrossRefGoogle Scholar
11Narasimhan, R.: Analysis of indentation of pressure sensitive plastic solids using the expanding cavity model. Mech. Mater. 36, 633 (2004).CrossRefGoogle Scholar
12Patnaik, M.N.M., Narasimhan, R., and Ramamurty, U.: Spherical indentation response of metallic glasses. Acta Mater. 52, 3335 (2004).CrossRefGoogle Scholar
13Zhang, H.W., Subhash, G., Jing, X.N., Kecskes, L.J., and Dowding, R.J.: Evaluation of hardness-yield strength relationships for bulk metallic glasses. Philos. Mag. Lett. 86, 333 (2006).CrossRefGoogle Scholar
14Clifton, R.J.: Dynamic plasticity. J. Appl. Mech. 50, 941 (1983).CrossRefGoogle Scholar
15Subhash, G.: The constitutive behavior of refractory metals as a function of strain rate. JOM 47, 55 (1995).CrossRefGoogle Scholar
16Lankford, J.: Mechanisms responsible for strain rate dependent compressive strength in ceramic materials. J. Am. Ceram. Soc. 64, 33 (1981).CrossRefGoogle Scholar
17Ravichandran, G. and Subhash, G.: A micromechanical model for the high strain rate behavior of ceramics. Int. J. Solid Struct. 32, 2627 (1995).CrossRefGoogle Scholar
18Bruck, H.A., Rosakis, A.J., and Johnson, W.L.: The dynamic compressive behavior of beryllium bearing bulk metallic glasses. J. Mater. Res. 11, 503 (1996).CrossRefGoogle Scholar
19Subhash, G., Dowding, R., and Kecskes, L.: Characterization of uniaxial compressive response of bulk amorphous Zr–Ti–Cu– Ni–Be alloy. Mater. Sci. Eng., A 334, 33 (2002).CrossRefGoogle Scholar
20Lu, J., Ravichandran, G., and Johnson, W.L.: Deformation behavior of the Zr41.2Ti13.8Cu12.5Ni10Be22.5 bulk metallic glass over a wide range of strain-rates and temperatures. Acta Mater. 51, 3429 (2003).CrossRefGoogle Scholar
21Mukai, T., Nieh, T.G., Kawamura, Y., Inoue, A., and Higashi, K.: Effect of strain rate on compressive behavior of a Pd40Ni40P20 bulk metallic glass. Intermetallics 10, 3429 (2002).CrossRefGoogle Scholar
22Hufnagel, T.C., Jiao, T., Li, Y., Xing, L.Q., and Ramesh, K.T.: Deformation and failure of Zr57Ti5Cu20Ni8Al10 bulk metallic glass under quasi-static and dynamic compression. J. Mater. Res. 17, 1441 (2002).CrossRefGoogle Scholar
23Gu, X., Jiao, T., Kecskes, L.J., Woodman, R.H., Fan, C., Ramesh, K.T., and Hufnagel, T.C.: Crystallization and mechanical behavior of (Hf, Zr)–Ti–Cu–Ni–Al metallic glasses. J. Non-Cryst. Solids 317, 112 (2003).CrossRefGoogle Scholar
24Li, H., Subhash, G., Gao, X.L., Kecskes, L.J., and Dowding, R.J.: Negative strain rate sensitivity and compositional dependence of fracture strength in Zr/Hf based bulk metallic glasses. Scripta Mater. 49, 1087 (2003).CrossRefGoogle Scholar
25Nemat-Nasser, S., Isaac, J.B., and Starrett, J.E.: Hopkinson techniques for dynamic recovery experiments. Proc. R. Soc. (London) A 435, 371 (1991).Google Scholar
26Subhash, G., Koeppel, B.J., and Chandra, A.: Dynamic indentation hardness and rate sensitivity in metals. J. Eng. Mater. Technol. 121, 257 (1999).CrossRefGoogle Scholar
27Anton, R.J. and Subhash, G.: Dynamic Vickers indentation of brittle materials. Wear 239, 27 (2000).CrossRefGoogle Scholar
28Gu, X., Xing, L.Q., and Hufnagel, T.C.: Glass-forming ability and crystallization of bulk metallic glass (Hf xZr1−x)52.5Cu17.9Ni14.6Al10Ti5. J. Non-Cryst. Solids 311, 77 (2002).CrossRefGoogle Scholar
29Zhang, H.W., Subhash, G., Kecskes, L.J., and Dowding, R.J.: Mechanical behavior of bulk (ZrHf). TiCuNiAl Amorphous Alloys. Scripta Mater. 86, 333 (2006).Google Scholar
30Subhash, G.: Dynamic indentation testing. ASM Handbook. 8, 519 (1999).Google Scholar
31Koeppel, B.J.: Dynamic indentation hardness of materials. Ph.D. Dissertation, Michigan Technological University, Houghton, MI, 1997.Google Scholar
32Lu, J.: Mechanical behavior of a bulk metallic glass and its composite over a wide range of strain rate and temperature. Ph.D. Thesis, California Institute of Technology, Pasadena, CA, 2002.Google Scholar
33Lewandowski, J.J. and Greer, A.L.: Temperature rise at shear bands in metallic glasses. Nat. Mater. 5, 15 (2006).CrossRefGoogle Scholar
34Zhang, H., Maiti, S., and Subhash, G.: Shear band evolution in bulk metallic glass under dynamic indentation. Acta Mater. (submitted 2006).Google Scholar
35Bhowmick, R., Raghavan, R., Chattopadhyay, K., and Ramamurty, U.: Plastic flow softening in a bulk metallic glass. Acta Mater. 54, 4221 (2006).CrossRefGoogle Scholar
36Li, J., Spaepen, F., and Hufnagel, T.C.: Nanometre-scale defects in shear bands in a metallic glass. Philos. Mag. A 82, 2623 (2002).CrossRefGoogle Scholar