Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-10T11:30:51.534Z Has data issue: false hasContentIssue false

Effects of minor Cu and Mg additions on microstructure and material properties of 8xxx aluminum conductor alloys

Published online by Cambridge University Press:  08 March 2017

Lei Pan
Affiliation:
Department of Applied Sciences, University of Québec at Chicoutimi, Saguenay, QC G7H 2B1, Canada
Kun Liu
Affiliation:
Department of Applied Sciences, University of Québec at Chicoutimi, Saguenay, QC G7H 2B1, Canada
Francis Breton
Affiliation:
Arvida Research and Development Centre, Rio Tinto, Saguenay, QC, G7S 4K8, Canada
X-Grant Chen*
Affiliation:
Department of Applied Sciences, University of Québec at Chicoutimi, Saguenay, QC G7H 2B1, Canada
*
a) Address all correspondence to this author. e-mail: xgrant_chen@uqac.ca
Get access

Abstract

The effects of minor Cu (0–0.29 wt%) and Mg (0–0.1 wt%) additions on the microstructure, electrical conductivity, mechanical, and creep properties of 8xxx aluminum conductor alloys were studied. The microstructure evolution was investigated using an optical microscope and the electron backscattered diffraction technique. The creep property was characterized by the primary creep strain and the minimum creep rate during creep deformation. The results demonstrated that additions of minor Cu and Mg reasonably improved the ultimate tensile strength but slightly reduced electrical conductivity. The addition of Cu remarkably decreased the primary creep strain but had a negligible effect on the minimum creep rate, leading to a beneficial effect on the short-term creep resistance but no advantage to the creep resistance under the long-term creep process. The minor addition of Mg greatly reduces both the primary creep strain and minimum creep rate, resulting in a significant and effective improvement in the creep resistance.

Type
Articles
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: Jürgen Eckert

References

REFERENCES

Engler, O., Laptyeva, G., and Wang, N.: Impact of homogenization on microchemistry and recrystallization of the Al–Fe–Mn alloy AA 8006. Mater. Charact. 79, 60 (2013).Google Scholar
Pan, L., Mirza, F.A., Liu, K., and Chen, X.G.: Effect of Fe-rich particles and solutes on creep behavior of 8xxx alloys. Mater. Sci. Technol. (2016). doi: 10.1080/02670836.2016.1258156.Google Scholar
Mcqueen, H.J., Chia, E.H., and Starke, E.A.: Fe-particle-stabilized aluminum conductors. JOM 38(4), 19 (1986).Google Scholar
Mamala, A. and Sciezor, W.: Evaluation of the effect of selected alloying elements on the mechanical and electrical aluminium properties. Arch. Metall. Mater. 59(1), 413 (2014).CrossRefGoogle Scholar
Murashkin, M.Y., Sabirov, I., Sauvage, X., and Valiev, R.Z.: Nanostructured Al and Cu alloys with superior strength and electrical conductivity. J. Mater. Sci. 51(1), 33 (2016).Google Scholar
Marquis, E.A., Seidman, D.N., and Dunand, D.C.: Effect of Mg addition on the creep and yield behavior of an Al–Sc alloy. Acta Mater. 51(16), 4751 (2003).CrossRefGoogle Scholar
Ryen, O., Nijs, O., Sjolander, E., Holmedal, B., Ekstrom, H.E., and Nes, E.: Strengthening mechanisms in solid solution aluminum alloys. Metall. Mater. Trans. A 37(6), 1999 (2006).Google Scholar
Karnesky, R.A., Meng, L., and Dunand, D.C.: Strengthening mechanisms in aluminum containing coherent Al3Sc precipitates and incoherent Al2O3 dispersoids. Acta Mater. 55(4), 1299 (2007).Google Scholar
Ashby, M.F., Shercliff, H., and Cebon, D.: Materials: Engineering, Science, Processing and Design, 1st ed. (Elsevier Butterworth-Heinemann, Burlington, MA, 2007); p. 514.Google Scholar
Chaudhury, P.K. and Mohamed, F.A.: Creep characteristics of an Al–2wt-percent–Cu alloy in the solid-solution range. Mater. Sci. Eng., A 101, 13 (1988).Google Scholar
Du, N.N., Qi, Y., Krajewski, P.E., and Bower, A.F.: The effect of solute atoms on aluminum grain boundary sliding at elevated temperature. Metall. Mater. Trans. A 42(3), 651 (2011).CrossRefGoogle Scholar
Lumley, R.N., Morton, A.J., and Polmear, I.J.: Enhanced creep performance in an Al–Cu–Mg–Ag alloy through underageing. Acta Mater. 50(14), 3597 (2002).CrossRefGoogle Scholar
Sauvage, X., Enikeev, N., Valiev, R., Nasedkina, Y., and Murashkin, M.: Atomic-scale analysis of the segregation and precipitation mechanisms in a severely deformed Al–Mg alloy. Acta Mater. 72, 125 (2014).Google Scholar
Reynolds, G.H., Lenel, F.V., and Ansell, G.S.: The effect of solute additions on the steady-state creep behavior of dispersion-strengthened aluminum. Metall. Mater. Trans. B 2(11), 3027 (1971).Google Scholar
Kato, M.: Grain boundary sliding in high-purity aluminium bicrystal and Al–Cu solid solution bicrystal during plastic deformation. Trans. Jpn. Inst. Met. 10(3), 215 (1969).Google Scholar
Shi, C.J., Mao, W.M., and Chen, X.G.: Evolution of activation energy during hot deformation of AA7150 aluminum alloy. Mater. Sci. Eng., A 571, 83 (2013).Google Scholar
Pan, L., Liu, K., Breton, F., and Chen, X.G.: Effect of Fe on microstructure and properties of 8xxx aluminum conductor alloys. J. Mater. Eng. Perform. 25(11), 1059 (2016).Google Scholar
Spittel, M. and Spittel, T.: Part 2: Non-ferrous Alloys-light Metal, 4th ed. (Springer, Berlin, Germany, 2011); p. 1953.CrossRefGoogle Scholar
Neumann, G. and Tuijn, C.: Self-diffusion and Impurity Diffusion in Pure Metals: Handbook of Experimental Data, 1st ed. (Elservier Ltd, Amsterdam, Netherlands, 2009); p. 349.Google Scholar
Shakiba, M., Parson, N., and Chen, X.G.: Hot deformation behavior and rate-controlling mechanism in dilute Al–Fe–Si alloys with minor additions of Mn and Cu. Mater. Sci. Eng., A 636, 572 (2015).CrossRefGoogle Scholar
Raeisinia, B., Poole, W.J., and Lloyd, D.J.: Examination of precipitation in the aluminum alloy AA6111 using electrical resistivity measurements. Mater. Sci. Eng., A 420(1–2), 245 (2006).Google Scholar
Wei, X.W., Zu, X.T., and Zhou, W.L.: Compressive creep behaviour of Mg–Li–Al alloy. Mater. Sci. Technol. 22(6), 730 (2006).CrossRefGoogle Scholar
Nabarro, F.R.N.: The time constant of logarithmic creep and relaxation. Mater. Sci. Eng., A 309, 227 (2001).Google Scholar
Westerlund, R.W.: Effects of composition and fabrication practice on resistance to annealing and creep of aluminum conductor alloys. Metall. Trans. 5(3), 667 (1974).Google Scholar
Mohamed, F.A.: Incorporation of the suzuki and the fisher interactions in the analysis of creep-behavior of solid-solution alloys. Mater. Sci. Eng., A 61(2), 149 (1983).Google Scholar
Halliday, M.D. and Beevers, C.J.: Some observations of grain-boundary sliding in aluminium bicrystals tested at constant strain rate and constant rate of stress increase. J. Mater. Sci. 6(10), 1254 (1971).Google Scholar
Babicheva, R.I., Dmitriev, S.V., Zhang, Y., Kok, S.W., Srikanth, N., Liu, B., and Zhou, K.: Effect of grain boundary segregations of Fe, Co, Cu, Ti, Mg and Pb on small plastic deformation of nanocrystalline Al. Comput. Mater. Sci. 98, 410 (2015).CrossRefGoogle Scholar
Ovid’ko, I.A., Sheinerman, A.G., and Valiev, R.Z.: Mg segregations at and near deformation-distorted grain boundaries in ultrafine-grained Al–Mg alloys. J. Mater. Sci. 49(19), 6682 (2014).Google Scholar
Mahmoud, S.A., Georgy, K.H., Mansy, F.M., and Kamel, R.: Effect of cold work on the mechanism controlling the high temperature creep in Al–2 wt% Mg. Phys. Status Solidi A 51(1), 257 (1979).CrossRefGoogle Scholar
Liu, X.Y., Pan, Q.L., Zhang, X.L., Liang, S.X., Gao, F., Zheng, L.Y., and Li, M.X.: Creep behavior and microstructural evolution of deformed Al–Cu–Mg–Ag heat resistant alloy. Mater. Sci. Eng., A 599, 160 (2014).Google Scholar