Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-11T01:50:47.316Z Has data issue: false hasContentIssue false
  • English
  • Français

Enhanced electrical conductivity and mechanical stability of flexible pressure-sensitive GNPs/CB/SR composites: Synergistic effects of GNPs and CB

Published online by Cambridge University Press:  02 November 2015

Ping Liu ,
Ying Huang Open the ORCID record for Ying Huang [Opens in a new window] ,
Caixia Liu ,
Yue Wang ,
Xiaohui Guo ,
Yugang Zhang  and
Yunjian Ge
Ping Liu*
Affiliation:
School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui Province, People's Republic of China
Ying Huang
Affiliation:
School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui Province, People's Republic of China; and Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031, Anhui Province, People's Republic of China
Caixia Liu*
Affiliation:
School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui Province, People's Republic of China
Yue Wang
Affiliation:
School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui Province, People's Republic of China
Xiaohui Guo
Affiliation:
School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui Province, People's Republic of China
Yugang Zhang
Affiliation:
School of Electronic Science and Applied Physics, Hefei University of Technology, Hefei 230009, Anhui Province, People's Republic of China
Yunjian Ge
Affiliation:
Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031, Anhui Province, People's Republic of China
*
a)Address all correspondence to this author. e-mail: liuping@hfut.edu.cn
Get access

Abstract

Silicone Rubber (SR) filled with graphene nanoplatelets (GNPs) and carbon black (CB) is prepared for high performance flexible pressure sensor. Due to the synergetic effect of mixed GNPs and CB, the percolation threshold of GNPs/CB/SR is lower than that of CB/SR, which indicates the addition of GNPs is contributed to enhance the electrical conductivity of GNPs/CB/SR. Moreover, the GNPs/CB/SR has a higher electrical stability and weaker resistance creep than that of GNPs/SR. That is to say, the addition of CB can promote the electrical and mechanical performance of GNPs/CB/SR, simultaneously. The pressure sensor array based on GNPs/CB/SR with weight on different sensing element is tested, and the results show that the size of applied loading on the pressure-sensitivity array can be recognized accurately.

Keywords

synergistic effectselectrical propertiesmechanical propertiespressureconductive composites
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 22 , 27 November 2015 , pp. 3394 - 3402
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Mallory, L.H., Alex, C., Benjamin, C.K.T., T Jeffrey, B.H., and Bao, Z.: 25th anniversary article: The evolution of electronic skin (E-skin): A brief history, design considerations, and recent progress. Adv. Mater. 25, 5997 (2013).Google Scholar
Ravinder, S.D., Philipp, M., Maurizio, V., Cheng, G., and Vladimir, J.L.: Directions toward effective utilization of tactile skin: A review. IEEE Sens. J. 13, 4121 (2013).Google Scholar
Hanna, Y., Mehdi, B., and Kaspar, A.: Tactile sensing for dexterous in-hand manipulation in robotics—A review. Sens. Actuators, A 167, 171 (2011).Google Scholar
Vladimir, J.L., Michael, S.S., and Sigurd, W.: Sensitive skin. IEEE Sens. J. 1, 41 (2001).Google Scholar
Shimojo, M., Namiki, A., Ishikawa, M., Makino, R., and Mabuchi, K.: A tactile sensor sheet using pressure conductive rubber with electrical-wires stitched method. IEEE Sens. J. 4, 589 (2004).CrossRefGoogle Scholar
Yang, Y.J., Cheng, M.Y., Chang, W.Y., Tsao, L.C., Yang, S.A., Shih, W.P., Chang, F.Y., Chang, S.H., and Fan, K.C.: An integrated flexible temperature and tactile sensing array using PI-copper films. Sens. Actuators, A 143, 143 (2008).Google Scholar
Wang, L., Ding, T., and Wang, P.: Effects of instantaneous compression pressure on electrical resistance of carbon black filled silicone rubber composite during compressive stress relaxation. Compos. Sci. Technol. 68, 3448 (2008).Google Scholar
Sekitani, T., Noguchi, Y., Hata, K., Fukushima, T., Aida, T., and Someya, T.: A rubberlike stretchable active matrix using elastic conductors. Science 321, 1468 (2008).Google Scholar
Lipomi, D.J., Vosgueritchian, M., Tee, B.C.K., Hellstrom, S.L., Lee, J.A., Fox, C.H., and Bao, Z.: Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes. Nat. Nanotechnol. 6, 788 (2011).Google Scholar
Park, J., Lee, Y., Hong, J., Lee, Y., Ha, M., Jung, Y., Lim, H., Kim, S.Y., and Ko, H.: Tactile-direction-sensitive and stretchable electronic skins based on human-skin-inspired interlocked microstructures. ACS Nano 8, 12020–12029 (2014).Google Scholar
Li, W., Dichiara, A., and Bai, J.: Carbon nanotube–graphene nanoplatelet hybrids as high-performance multifunctional reinforcements in epoxy composites. Compos. Sci. Technol. 74, 221 (2013).CrossRefGoogle Scholar
Chen, J., Du, X.C., Zhang, W.B., Yang, J.H., Zhang, N., Huang, T., and Wang, Y.: Synergistic effect of carbon nanotubes and carbon black on electrical conductivity of PA6/ABS blend. Compos. Sci. Technol. 81, 1 (2013).Google Scholar
Zhang, W., Dehghani-Sanij, A.A., and Blackburn, R.S.: Carbon based conductive polymer composites. J. Mater. Sci. 42, 3408 (2007).Google Scholar
Thongruang, W., Spontak, R.J., and Balik, C.M.: Correlated electrical conductivity and mechanical property analysis of high-density polyethylene filled with graphite and carbon fiber. Polymer 43, 2279 (2002).Google Scholar
Clingerman, L.M., Weber, E.H., King, J.A., and Schulz, K.H.: Synergistic effect of carbon fillers in electrically conductive nylon 6,6 and polycarbonate based resins. Polym. Compos. 23, 911 (2002).Google Scholar
Tian, M., Huang, Y., Wang, W., Li, R., Liu, P., Liu, C., and Zhang, Y.: Temperature-dependent electrical properties of graphene nanoplatelets film dropped on flexible substrates. J. Mater. Res. 29, 1288 (2014).Google Scholar
Luan, V.H., Tien, H.N., Cuong, T.V., Kong, B.S., Chung, J.S., Kim, E.J., and Hur, S.H.: Novel conductive epoxy composites composed of 2-D chemically reduced graphene and 1-D silver nanowire hybrid fillers. J. Mater. Chem. 22, 8649 (2012).CrossRefGoogle Scholar
Wang, D., Huang, Y., Ma, Y., Liu, P., Liu, C., and Zhang, Y.: Research on highly sensitive humidity sensor based on Tr-MWCNT/HEC composite films. J. Mater. Res. 29, 2845 (2014).Google Scholar
Zheng, Q., Shen, L., Li, W.C., Song, Y.H., and Yi, X.S.: Reversible nonlinear conduction behavior for HDPE/CB composites. Chin. Sci. Bull. 49, 2257 (2004).Google Scholar
Yi, X.S., Shen, L., and Pan, Y.: Thermal volume expansion in polymeric PTC composites: A theoretical approach. Compos. Sci. Technol. 61, 949 (2001).Google Scholar
Mclachlan, D.S., Blaszkiewicz, M., and Newnham, R.E.: Electrical resistivity of composites. J. Am. Ceram. Soc. 73, 2187 (1990).Google Scholar
Hussain, M., Choa, Y.H., and Niihara, K.: Fabrication process and electrical behavior of novel pressure-sensitive composites. Composites, Part A 32, 1689 (2001).Google Scholar
Balberg, I.: Excluded-volume explanation of Archie's law. Phys. Rev. B 33, 3618 (1986).Google Scholar
Celzard, A., McRae, E., Deleuze, C., Dufort, M., Furdin, G., and Marêché, J.F.: Critical concentration in percolating systems containing a high-aspect-ratio filler. Phys. Rev. B 53, 6209 (1996).Google Scholar
Ounaies, Z., Park, C., Wise, K.E., Siochi, E.J., and Harrison, J.S.: Electrical properties of single wall carbon nanotube reinforced polyimide composites. Compos. Sci. Technol. 63, 1637 (2003).CrossRefGoogle Scholar
Pike, G.E. and Seager, C.H.: Percolation and conductivity: A computer study. I. Phys. Rev. B 10, 1421 (1974).Google Scholar
Seager, C.H. and Pike, G.E.: Percolation and conductivity: A computer study. II. Phys. Rev. B 10, 1435 (1974).Google Scholar
Sun, Y., Bao, H.D., Guo, Z.X., and Yu, J.: Modeling of the electrical percolation of mixed carbon fillers in polymer-based composites. Macromolecules 42, 459 (2009).Google Scholar
Wang, L., Ding, T., and Wang, P.: Influence of carbon black concentration on piezoresistivity for carbon black filled silicone rubber composite. Carbon 47, 3151 (2009).Google Scholar
Omnès, B., Thuillier, S., Pilvin, P., Grohens, Y., and Gillet, S.: Effective properties of carbon black filled natural rubber: Experiments and modeling. Composites, Part A 39, 1141 (2008).Google Scholar
Soltania, R. and Katbabb, A.A.: The role of interfacial compatibilizer in controlling the electrical conductivity and piezoresistive behavior of the nanocomposites based on RTV silicone rubber/graphite nanosheets. Sens. Actuators, A 163, 213 (2010).Google Scholar
Jean, L.L.: Rubber-filler interactions and rheological properties in filled compounds. Prog. Polym. Sci. 27, 627 (2002).Google Scholar
Ma, P.C., Liu, M.Y., Zhang, H., Wang, S.Q., Wang, R., Wang, K., Wong, Y.K., Tang, B.Z., Hong, S.H., Paik, K.W., and Kim, J.K.: Enhanced electrical conductivity of nanocomposites containing hybrid fillers of carbon nanotubes and carbon black. ACS Appl. Mater. Interfaces 1, 1090 (2009).Google Scholar
Saxena, R.S., Bhan, R.K., and Aggrawal, A.: A new discrete circuit for readout of resis-tive sensor arrays. Sens. Actuators, A 149, 93 (2009).Google Scholar
Mei, H., Wang, R., Wang, Z., Feng, J., Xia, Y., and Zhang, T.: A flexible pressure-sensitive array based on soft substrate. Sens. Actuators, A 222, 80 (2015).Google Scholar