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(Fe,Co,Ni)–B–Si–Nb Bulk Glassy Alloy With Super-High Strength and Some Ductility [Article Retracted]

Published online by Cambridge University Press:  28 March 2011

Baolong Shen  and
Akihisa Inoue
Baolong Shen*
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan; and Research and Development Project, Core Research for Evolution Science and Technology (CREST), Japan Science and Technology Agency, Sendai 980-8577, Japan
Akihisa Inoue
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan; and Research and Development Project, Core Research for Evolution Science and Technology (CREST), Japan Science and Technology Agency, Sendai 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: shen@imr.tohoku.ac.jp

Abstract

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Glassy [(Fe0.8Co0.1Ni0.1)0.75B0.2Si0.05]96Nb4 alloy rods with glass transition temperature of 835 K, followed by a large supercooled liquid region of 55 K were produced in the diameter range up to 2 mm by copper mold casting. The glassy alloy rods exhibit super-high true fracture strength of 4225 MPa combined with elastic strain of 0.02 and true plastic strain of 0.005. The super-high strength alloy simultaneously exhibits high magnetization of 1.1 T, low coercivity of 3 A/m, and high permeability of 1.8 × 104 at 1 kHz. The success of synthesizing a super-high strength Fe-based bulk glassy alloy with some compressive plastic strain and good soft magnetic properties is encouraging for future development of Fe-based bulk glassy alloys as new engineering and functional materials.

Keywords

DuctilityMetallic glassStrength
Type
Rapid Communications
Information
Journal of Materials Research , Volume 20 , Issue 1 , January 2005 , pp. 1 - 5
Copyright
Copyright © Materials Research Society 2004

References

REFERENCES

1Inoue, A., Ohtera, K., Kita, K. and Masumoto, T.: New amorphous Mg-Ce-Ni alloys with high strength and good ductility. Jpn. J. Appl. Phys. 27, L2248 (1988).CrossRefGoogle Scholar
2Inoue, A., Zhang, T. and Mosumoto, T.: Al-La-Ni amorphous alloys with a wide supercooled liquid region. Mater. Trans. JIM 30, 965 (1989).CrossRefGoogle Scholar
3Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
4Inoue, A., Shinohara, Y. and Gook, J.S.: Thermal and magnetic properties of bulk Fe-based glassy alloys prepared by copper mold casting. Mater. Trans. JIM 36, 1427 (1995).CrossRefGoogle Scholar
5Shen, T.D. and Schwarz, R.B.: Bulk ferromagnetic glasses prepared by flux melting and water quenching. Appl. Phys. Lett. 75, 49 (1999).CrossRefGoogle Scholar
6Borrego, J.M., Conde, A., Roth, S. and Eckert, J.: Glass-forming ability and soft magnetic properties of FeCoSiAlGaPCB amorphous alloys. J. Appl. Phys. 92, 2073 (2002).CrossRefGoogle Scholar
7Pawlik, P., Davies, H.A. and Gibbs, M.R.J.: Magnetic properties and glass formability of Fe61Co10Zr5W4B20 bulk metallic glassy alloy. Appl. Phys. Lett. 83, 2775 (2003).CrossRefGoogle Scholar
8Shen, B.L., Koshiba, H., Inoue, A., Kimura, H.M. and Mizushima, T.: Bulk glassy Co43Fe20Ta5.5B31.5 alloy with high glass-forming ability and good soft magnetic properties. Mater. Trans. 42, 2136 (2001).CrossRefGoogle Scholar
9Chiriac, H., Lupu, N. and Tibu, M.: Design and preparation of new Fe-based bulk amorphous alloys torroids. IEEE Trans. Magn. 39, 3040 (2003).CrossRefGoogle Scholar
10Inoue, A., Shen, B.L., Koshiba, H., Kato, H. and Yavari, A.R.: Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties. Nat. Mater. 2, 661 (2003).CrossRefGoogle ScholarPubMed
11Inoue, A., Shen, B.L., Yavari, A.R. and Greer, A.L.: Mechanical properties of Fe-based bulk glassy alloys in Fe–B–Si–Nb and Fe–Ga–P–C–B–Si systems. J. Mater. Res. 18, 1487 (2003).CrossRefGoogle Scholar
12Ponnambalam, V., Poon, S.J., Shiflet, G.J., Keppens, V.M., Taylor, R. and Petculescu, G.: Synthesis of iron-based bulk metallic glasses as nonferromagnetic amorphous steel alloys. Appl. Phys. Lett. 83, 1131 (2003).CrossRefGoogle Scholar
13Ponnambalam, V., Poon, S.J. and Shiflet, G.J.: Fe-based bulk metallic glasses with diameter thickness larger than one centimeter. J. Mater. Res. 19, 1320 (2004).CrossRefGoogle Scholar
14Lu, Z.P., Liu, C.T. and Porter, W.D.: Role of yttrium in glass formation of Fe-based bulk metallic glasses. Appl. Phys. Lett. 83, 2581 (2003).CrossRefGoogle Scholar
15Lu, Z.P., Liu, C.T., Thompson, J.R. and Porter, W.D.: Structural amorphous steels. Phys. Rev. Lett. 92, 245503 (2004).CrossRefGoogle ScholarPubMed
16Chen, H.S.: Glassy metals. Rep. Prog. Phys. 43, 353 (1980).CrossRefGoogle Scholar
17Imafuku, M., Sato, S., Koshiba, H., Matsubara, E. and Inoue, A.: Structural variation of Fe-Nb-B metallic glasses during crystallization process. Scripta Mater. 44, 2369 (2001).CrossRefGoogle Scholar
18Imafuku, M., Sato, S., Koshiba, H., Matsubara, E. and Inoue, A.: Crystallization behavior of amorphous Fe90- X Nb10BX (X = 10 and 30) alloys. Mater. Trans. JIM 41, 1526 (2000).CrossRefGoogle Scholar
19Imafuku, M., Sato, S., Matsumara, E. and Inoue, A.: Structural study of Fe90-x Nb10Bx (x = 10, 20 and 30) glassy alloys. J. Non-Cryst. Solids 312, 589 (2002).CrossRefGoogle Scholar
20Matsubara, E., Sato, S., Imafuku, M., Nakamura, T., Koshiba, H., Inoue, A. and Waseda, Y.: Structural study of amorphous Fe10M10B20 (M = Zr, Nb, and Cr) alloys by x-ray diffraction. Mater. Sci. Eng. A 312, 136 (2001).CrossRefGoogle Scholar
21Chen, H.S., Krause, J.T. and Coleman, E.: Elastic constants, hardness and their implications to flow properties of metallic glasses. J. Non-Cryst. Solids 18, 157 (1975).CrossRefGoogle Scholar
22Chen, H.S.: Correlation between elastic constants and flow behavior in metallic glasses. J. Appl. Phys. 49, 462 (1978).CrossRefGoogle Scholar
23De Boer, F.R., Boom, R., Mattens, W.C.M., Miedema, A.R. and Niessen, A.K. Experimental and predicted enthalpies of alloy formation, in Cohesion in Metals, edited by de Boer, F.R. and Pettifor, D.G. (North-Holland, Amsterdam, The Netherlands, 1989), pp. 217–258.Google Scholar
24Inoue, A. and Shen, B.L.: Soft magnetic bulk glassy Fe-B-Si-Nb alloys with high saturation magnetization above 1.5 T. Mater. Trans. 43, 766 (2002).CrossRefGoogle Scholar
25Zhang, Z.F., Eckert, J. and Schultz, L.: Difference in compressive and tensile fracture mechanisms of Zr59Cu20Al10Ni8Ti3 bulk metallic glass. Acta Mater. 51, 1167 (2003).CrossRefGoogle Scholar