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Field decrystallization and structural modifications of highly doped silicon in a 2.45-GHz microwave single-mode cavity

Published online by Cambridge University Press:  03 March 2011

Ramesh Peelamedu*
Affiliation:
Materials Research Institute, The Pennsylvania State University,University Park, Pennsylvania 16802
Rustum Roy
Affiliation:
Materials Research Institute, The Pennsylvania State University,University Park, Pennsylvania 16802
Dinesh Agrawal
Affiliation:
Materials Research Institute, The Pennsylvania State University,University Park, Pennsylvania 16802
William Drawl
Affiliation:
Materials Research Institute, The Pennsylvania State University,University Park, Pennsylvania 16802
*
a) Address all correspondence to this author. e-mail: pdramesh@psu.edu
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Abstract

Highly doped n-type silicon powder responds aggressively to a 2.45-GHz microwave E-field, whereas it remains unperturbed in the H-field. In the E-field, after about 30 s of treatment, the silicon powder attained submelting temperatures and thus coagulated to a bulk solid piece. X-ray diffraction analysis of the surface and the cross section of this solid material failed to show any detectable peaks, ascertaining the fact that the material had decrystallized. The Raman spectra of the material had broad and shallow peaks quite different from the thin, sharp lines exhibited by Si wafer. It appears that the E-field treatment has considerably distorted the lattice structure creating lattice strains throughout the sample. These lattice strains were relieved by grinding (recrystallized).

Type
Rapid Communications
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1Cheng, J.P., Agrawal, D.K., Komarneni, S., Mathis, M. and Roy, R.: Microwave processing of WC-Co composites and ferroic titanates. Mater. Res. Innov. 1, 44 (1997).CrossRefGoogle Scholar
2Roy, R., Agrawal, D.K., and Cheng, J.P., in Ceramic Transactions , edited by Clark, D.E., Binner, J.G.P., and Lewis, D.A. (The American Ceramics Society, Westerville, OH 2001), Vol. 111, pp. 471485Google Scholar
3Agrawal, D.K.: Microwave processing of ceramics. Curr. Opin. Solid State Maert. Sci. 3, 480 (1998).CrossRefGoogle Scholar
4Clark, D.E. and Sutton, W.H.: Microwave processing of materials. Ann. Rev. Mater. Sci. 26, 299 (1996).CrossRefGoogle Scholar
5Johnson, D.L.: Microwave and plasma sintering of ceramics. Ceramics Int. 17,295 (1991).CrossRefGoogle Scholar
6Gasgnier, M. and Petit, A.: Syntheses of chromium copper and chromium manganese oxides performed by means of a low power monomode microwave. J. Alloy Compd. 358, 302 (2003).CrossRefGoogle Scholar
7Panneerselvam, M. and Rao, K.J.: Novel microwave method for the synthesis and sintering of mullite from kaolinite. Chem. Mater. 15, 2247 (2003).CrossRefGoogle Scholar
8Cheng, J.P., Roy, R. and Agrawal, D.: Experimental proof of major role of magnetic field losses in microwave heating of metal and metallic composites. J. Mater. Sci. Lett. 20, 1561 (2001).CrossRefGoogle Scholar
9Dube, D.C., Peelamedu, R., Cheng, J., Lanagan, M.T., Agrawal, D. and Roy, R. Experimental evidence of re-distribution of fields during processing in a high power microwave cavity. Appl. Phys. Lett . (communicated)Google Scholar
10Takizawa, H., Uheda, K. and Endo, T.: Rapid formation and growth of bixbyite-type (In0.67Fe0.33)2O3 by 28 GHz microwave irradiation. J. Am. Ceram. Soc. 83, 2321 (2000).CrossRefGoogle Scholar
11Roy, R., Peelamedu, R., Hurtt, L., Cheng, J.P. and Agrawal, D.: Definitive experimental evidence for microwave effects: Radically new effects of separated E and H fields, such as decrystallization of oxides in seconds. Mater. Res. Innov. 6,128 (2002).CrossRefGoogle Scholar
12 T. Kimura, H. Takizawa, K. Uheda, and T. Endo: Microwave synthesis of x-rays amorphous ferrites and the magnetic properties. Proc. Int. Conf. Microwave Chemistry (2000) pp. 335338.Google Scholar
13Kumar, S. and Kumar, D. Plasma-assisted decrystallization. PCT Int. Appl. (2003), p. 50 CODEN: PIXXD2 WO 2003096772.Google Scholar