Hostname: page-component-cd9895bd7-mkpzs Total loading time: 0 Render date: 2024-12-28T08:29:09.508Z Has data issue: false hasContentIssue false
  • English
  • Français

Gas-sensing properties and in situ diffuse reflectance infrared Fourier transform spectroscopy study of formaldehyde adsorption and reactions on SnO2 films

Published online by Cambridge University Press:  06 November 2013

Zhenxin Zhang ,
Kaijin Huang ,
Fangli Yuan  and
Changsheng Xie
Zhenxin Zhang
Affiliation:
State Key Laboratory of Materials Processing and Die and Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China
Kaijin Huang*
Affiliation:
State Key Laboratory of Materials Processing and Die and Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China; State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Science, Beijing 100190, People's Republic of China; and State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, People's Republic of China
Fangli Yuan
Affiliation:
State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Science, Beijing 100190, People's Republic of China
Changsheng Xie
Affiliation:
State Key Laboratory of Materials Processing and Die and Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China
*
a)Address all correspondence to this author. e-mail: huangkaijin@hust.edu.cn
Get access

Abstract

Formaldehyde (HCHO) is widely used in construction, wood processing, furniture, textile, and carpeting industries. However, it is highly toxic. It strongly irritates human eyes and nose, and is a carcinogen. In this paper, the effects of gas concentration and operating temperature on the sensing properties of the nano-SnO2 flat-type coplanar gas sensor arrays to formaldehyde were studied. The results revealed that the nano-SnO2 flat-type coplanar gas sensor arrays exhibited good sensitivity such as a fast response, short recovery time, and low detection limit. In addition, the adsorption and surface reactions of formaldehyde on SnO2 films were also studied by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) at 200–300 °C. Molecularly adsorbed formaldehyde, formate, dioxymethylene, polyoxymethylene, H2O, and CO2 surface species were formed during formaldehyde adsorption at 200–300 °C. Moreover, a possible mechanism of the reaction process was given.

Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 1: Focus Issue: Synthesis of Nanostructured Functional Oxides , 14 January 2014 , pp. 139 - 147
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Li, Y., Zhang, S.P., and Zhang, G.Z.: Specially environmental responses induced by multi-field coupling for nanocrystalline SnO2 porous film as gas sensor. Sens. Actuators, B 182, 239 (2013).Google Scholar
Ding, X.H., Zeng, D.W., and Xie, C.S.: Controlled growth of SnO2 nanorods clusters via Zn doping and its influence on gas-sensing properties. Sens. Actuators, B 149, 336 (2010).CrossRefGoogle Scholar
Maekawa, T., Suzuki, K., Takada, T., Kobayashi, T., and Egashira, M.: Odor identification using a SnO2-based sensor array. Sens. Actuators, B 80, 51 (2001).CrossRefGoogle Scholar
Ray, S.C., Karanjai, M.K., and Gupta, D.D.: Tin dioxide based transparent semiconducting films deposited by the dip-coating technique. Surf. Coat. Technol. 102, 73 (1998).CrossRefGoogle Scholar
Zeng, W., Liu, T.M., and Liu, D.J.: Formaldehyde gas sensing property and mechanism of TiO2–Ag nanocomposite. Physica B 405, 4235 (2010).Google Scholar
Meng, F.L., Li, H.H., Kong, L.T., Liu, J.Y., Jin, Z., Li, W., Jia, Y., Liu, J.H., and Huang, X.J.: Parts per billion-level detection of benzene using SnO2/graphene nanocomposite composed of sub-6nm SnO2 nanoparticles. Anal. Chim. Acta 736, 100 (2012).CrossRefGoogle ScholarPubMed
Takeshi, O., Ryota, M., and Ken, W.: Synthesizing SnO2 thin films and characterizing sensing performances. Sens. Actuators, B 150, 99 (2010).Google Scholar
Liu, S.Q., Xie, M.J., Li, Y.X., Guo, X.F., Ji, W.J., Ding, W.P., and Chaktong, A.: Novel sea urchin-like hollow core-shell SnO2 superstructures: Facile synthesis and excellent ethanol sensing performance. Sens. Actuators, B 151, 229 (2010).CrossRefGoogle Scholar
Mir, W.A., Usmah, K., and Ahsanulhaq, Q.: Synthesis and characterization of Cu-SnO2 nanoparticles deposited on glass using ultrasonic spray pyrolysis and their H2S sensing properties. Curr. Nanosci. 8, 919 (2012).Google Scholar
Srivastava, J.K., Pandey, P., Mishra, V.N., and Dwivedi, R.: Sensing mechanism of Pd-doped SnO2 sensor for LPG detection. Solid State Sci. 11, 1602 (2009).CrossRefGoogle Scholar
Thorsten, W., Kohl, C.D., Michael, F., and Michael, T.: Gas sensing properties of ordered mesoporous SnO2 . Sensors 6, 318 (2006).Google Scholar
Matthias, B. and Ulrike, D.: The surface and materials science of tin oxide. Prog. Surf. Sci. 79, 47 (2005).Google Scholar
Hoefer, U. and Frank, J.: High temperature Ga2O3-gas sensors and SnO2-gas sensors: A comparison. Sens. Actuators, B 78, 6 (2001).CrossRefGoogle Scholar
Zhang, C.B. and He, H.: A comparative study of TiO2 supported noble metal catalysts for the oxidation of formaldehyde at room temperature. Catal. Today 126, 345 (2007).CrossRefGoogle Scholar
Collins, J.J., Ness, R., and Tyl, W.R.: A review of adverse pregnancy outcomes and formaldehyde exposure in human and animal studies. Regul. Toxicol. Pharm. 34, 17 (2001).CrossRefGoogle ScholarPubMed
Zheng, Y.G., Wang, J., and Yao, P.J.: Formaldehyde sensing properties of electrospun NiO-doped SnO2 nanofibers. Sens. Actuators, B 156, 723 (2011).CrossRefGoogle Scholar
Woutersen, R.A., Hoetmer, A.V.G., Bruijntjes, J.P., Zwart, A., and Ferson, J.V.: Nasal tumours in rats after severe injury to the nasal mucosa and prolonged exposure to 10 ppm formaldehyde. J. Appl. Toxicol. 9, 39 (1989).CrossRefGoogle Scholar
Mitkus, J.R., Hess, A.M., and Schwartz, S.L.: Pharmacokinetic modeling as an approach to assessing the safety of residual formaldehyde in infant vaccines. Vaccine 31, 2738 (2013).CrossRefGoogle ScholarPubMed
Heck, H.D. and Casanova, M.: The implausibility of leukemia induction by formaldehyde: A critical review of the biological evidence on distant-site toxicity. Regul. Toxicol. Pharm. 40, 92 (2004).CrossRefGoogle ScholarPubMed
Hopkins, R.J., Still, T., Haider, A.S., Fisher, R.I., Lewis, C.A., and Seakins, W.P.: A simplified apparatus for ambient formaldehyde detection via GC-pHID. Atmos. Environ. 37, 2557 (2003).CrossRefGoogle Scholar
Bareket, L., Rephaeli, A., Berkovitch, G., Nudelman, A., and Rishpon, J.: Carbon nanotubes based electrochemical biosensor for detection of formaldehyde released from a cancer cell line treated with formaldehyde-releasing anticancer prodrugs. Bioelectrochemistry 77, 94 (2010).CrossRefGoogle ScholarPubMed
Tian, S.Q., Ding, X.H., Zeng, D.W., Wu, J.J., Zhang, S.P., and Xie, C.S.: A low temperature gas sensor based on Pd-functionalized mesoporous SnO2 fibers for detecting trace formaldehyde. RSC Adv. 3, 11823 (2013).CrossRefGoogle Scholar
Gunawan, P., Lin, M., Teo, J., Ma, J.M., Highfield, J., and Li, Q.H.: Ultrahigh sensitivity of Au/1D α-Fe2O3 to acetone and the sensing mechanism. Langmuir 28, 14090 (2012).CrossRefGoogle ScholarPubMed
Sambeth, E.J., Centeno, A.M., Paúl, A., Briand, E.L., Thoms, J.H., and Odriozola, A.J.: In situ DRIFTS study of the adsorption–oxidation of CH3OH on V2O5 . J. Mol. Catal. A: Chem. 161, 89 (2000).CrossRefGoogle Scholar
He, Y.B. and Ji, H.B.: In-situ DRIFTS study on catalytic oxidation of formaldehyde over Pt/TiO2 under mild conditions. Chin. J. Catal. 31, 171 (2010).CrossRefGoogle Scholar
Huang, K.J., Kong, L.C., Yuan, F.L., and Xie, C.S.: In situ diffuse reflection Fourier transform infrared spectroscopy study of formaldehyde adsorption and reactions on nano γ-Fe2O3 films. Appl. Surf. Sci. 38, 405 (2013).CrossRefGoogle Scholar
Chen, M., Wang, Z.H., Han, D.M., Gu, F.B., and Guo, G.S.: High-sensitivity NO2 gas sensors based on flower-like and tube-like ZnO nanomaterials. Sens. Actuators, B 157, 565 (2011).CrossRefGoogle Scholar
Huang, K.J., Zhang, Z.X., Yuan, F.L., and Xie, C.S.: Fabrication and hexanal gas sensing property of nano-SnO2 flat-type coplanar gas sensor arrays at ppb level. Curr. Nanosci. 9, 357 (2013).CrossRefGoogle Scholar
Tolvaj, L., Mitsui, K., and Varga, D.: Validity limits of Kubelka-Munk theory for DRIFT spectra of photodegraded solid wood. Wood Sci. Technol. 45, 135 (2011).CrossRefGoogle Scholar
Xie, C.S., Xiao, L.Q., Hu, M.L., Bai, Z.K., Xia, X.P., and Zeng, D.W.: Fabrication and formaldehyde gas-sensing property of ZnO–MnO2 coplanar gas sensor arrays. Sens. Actuators, B 145, 457 (2010).CrossRefGoogle Scholar
Dong, X.W., Qin, L.P., Xu, J.Q., Pan, Q.Y., Cheng, Z.X., and Xiang, Q.: Gas sensing properties of Au modified SnO2 micron rods. Curr. Nanosci. 4, 236 (2008).Google Scholar
Neri, G., Bonavita, A., Rizza, G., Galvagno, S., Pinna, N., Niederberger, M., Capone, S., and Siciliano, P.: Towards enhanced performances in gas sensing: SnO2 based nanocrystalline oxides application. Sens. Actuators, B 122, 564 (2007).CrossRefGoogle Scholar
Chen, Y.J., Nie, L., Xue, X.Y., Wang, Y.G., and Wang, T.H.: Linear ethanol sensing of SnO2 nanorods with extremely high sensitivity. Appl. Phys. Lett. 88, 083105 (2006).CrossRefGoogle Scholar
Zhang, T., Liu, L., Qi, Q., Li, S.C., and Lu, G.Y.: Development of microstructure In/Pd-doped SnO2 sensor for low-level CO detection. Sens. Actuators, B 139, 287 (2009).CrossRefGoogle Scholar
Grossmann, K., Pavelko, G.R., Barsan, N., and Weimar, U.: Interplay of H2, water vapor and oxygen at the surface of SnO2 based gas sensors: An operando investigation utilizing deuterated gases. Sens. Actuators, B 166–167, 787 (2012).CrossRefGoogle Scholar
Raskó, J., Kecskés, T., and Kiss, J.: Adsorption and reaction of formaldehyde on TiO2-supported Rh catalysts studied by FTIR and mass spectrometry. J. Catal. 226, 183 (2004).CrossRefGoogle Scholar
Kecskés, T., Raskó, J., and Kiss, J.: FTIR and mass spectrometric studies on the interaction of formaldehyde with TiO2 supported Pt and Au catalysts. Appl. Catal., A 273, 55 (2004).CrossRefGoogle Scholar
Xu, W.Z., Raftery, D., and Francisco, S.J.: Effect of irradiation sources and oxygen concentration on the photocatalytic oxidation of 2-propanol and acetone studied by in situ FTIR. J. Phys. Chem. B 107, 4537 (2003).CrossRefGoogle Scholar
Du, X., Du, Y., and George, S.M.: CO gas sensing by ultrathin tin oxide films grown by atomic layer deposition using transmission FTIR spectroscopy. J. Phys. Chem. A 112, 9211 (2008).CrossRefGoogle ScholarPubMed
Millar, J.G., Colin, H., Rochester, H.C., and Waugh, C.K.: An FTIR study of adsorption of formic acid and formaldehyde on potassium-promoted Cu/SiO2 catalyst. J. Catal. 155, 52 (1995).CrossRefGoogle Scholar
Lochař, V.: FT-IR study of methanol, formaldehyde and methyl formate adsorption on the surface of Mo/Sn oxide catalyst. Appl. Catal., A 309, 33 (2006).CrossRefGoogle Scholar