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Glass corrosion in ambient temperature lithium battery headers

Published online by Cambridge University Press:  31 January 2011

Bruce C. Bunker ,
Sally C. Douglas  and
Rod K. Quinn
Bruce C. Bunker
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185
Sally C. Douglas
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185
Rod K. Quinn
Affiliation:
Los Alamos National Laboratories, Los Alamos, New Mexico 87544
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Abstract

During high-temperature storage, glass corrosion in glass-to-metal feedthroughs can limit the lifetimes of lithium batteries designed to operate at ambient temperatures. Ampule tests have been conducted to simulate glass corrosion for Li/So2, Li/SOCl2, and Li/SOCl2 + BrCl batteries. In all lithium battery systems tested, lithium metal has been identified as the source of glass corrosion. On the basis of thermodynamic and kinetic stability, glass compositions have been developed that minimize the corrosion problem in all lithium battery systems tested.

Type
Articles
Information
Journal of Materials Research , Volume 2 , Issue 2 , April 1987 , pp. 182 - 194
Copyright
Copyright © Materials Research Society 1987

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References

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