Hostname: page-component-784d4fb959-9bxm5 Total loading time: 0 Render date: 2025-07-16T10:16:12.762Z Has data issue: false hasContentIssue false
  • English
  • Français

Grain size effect on the phase transformations of higher manganese silicide thermoelectric materials: An in situ energy dispersive x-ray diffraction study

Published online by Cambridge University Press:  13 May 2011

Aijun Zhou ,
Tiejun Zhu ,
Xinbing Zhao  and
Eckhard Mueller
Aijun Zhou
Affiliation:
State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China; and State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China; and Institute of Materials Research, German Aerospace Center (DLR), 51147 Cologne, Germany
Tiejun Zhu
Affiliation:
State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Xinbing Zhao*
Affiliation:
State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Eckhard Mueller
Affiliation:
Institute of Materials Research, German Aerospace Center (DLR), 51147 Cologne, Germany
*
a)Address all correspondence to this author. e-mail: zhaoxb@zju.edu.cn
Get access

Abstract

Phase structures of microscale and nanoscale higher manganese silicides (HMSs) were investigated using in situ energy dispersive x-ray diffraction at high temperatures or/and high pressure. A few phase transformations accompanied with the presence of MnSi phase were observed in different temperature regions, which were associated with the interevolution of several incommensurate HMS phases. It was found that in nanostructured HMS, the interevolution of HMS was remarkable and accelerated compared to that in the micropowders. Meanwhile, high pressure was able to influence these phase transformations due to giant strain in the materials. The phase transformations were discussed from thermodynamic aspects with respect to the different formation enthalpy of Mn–Si system and the large surface energy and structural instability of the nanopowders.

Keywords

ThermoelectricX-ray diffractionPhase transformation

Information

Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 15: Focus Issue: Advances in Thermoelectric Materials , 14 August 2011 , pp. 1900 - 1906
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1.Fedorov, M.I. and Zaitsev, V.K.: Thermoelectric properties of transition metal silicides, in Thermoelectrics Handbook, edited by Rowe, D.M. (CRC Press, New York, 2005).Google Scholar
2.Mahan, J.E.: The potential of higher manganese silicide as an optoelectronic thin film material. Thin Solid Films 461(1), 152 (2004).CrossRefGoogle Scholar
3.de Ridder, R., van Tendeloo, G., and Amelinckx, S.: Electron microscopic study of the chimney ladder structures MnSi2-x and MoGe2-x. Phys. Status Solidi A Appl. Res. 33, 383 (1976).CrossRefGoogle Scholar
4.de Ridder, R., van Tendeloo, G., and Amelinckx, S.: Incommensurate superstructures in MnSi2-x. Phys. Status Solidi A Appl. Res. 30, K99 (1976).CrossRefGoogle Scholar
5.Zaitsev, V.K.: Thermoelectric properties of anisotropic MnSi1.75, in Handbook of Thermoelectrics, edited by Rowe, D.M. (CRC Press, New York, 2005).Google Scholar
6.Fedorov, M.I., Zaitsev, V.K., Solomkin, F.Y., and Vedernikov, M.V.: Thermoelectric elements based on compounds of silicon and transition metals. Tech. Phys. Lett. 23(8), 602 (1997).CrossRefGoogle Scholar
7.Zhou, A.J., Zhao, X.B., Zhu, T.J., Dasgupta, T., Stiewe, C., Hassdorf, R., and Mueller, E.: Mechanochemical decomposition of higher manganese suicides in the ball milling process. Intermetallics 18(11), 2051 (2010).Google Scholar
8.Zhou, A.J., Zhao, X.B., Zhu, T.J., Cao, Y.Q., Stiewe, C., Hassdorf, R., and Mueller, E.: Composites of higher manganese silicides and nanostructured secondary phases and their thermoelectric properties. J. Electron. Mater. 38(7), 1072 (2009).Google Scholar
9.Zhou, A.J., Zhu, T.J., Ni, H.L., Zhang, Q., and Zhao, X.B.: Preparation and transport properties of CeSi2/HMS thermoelectric composites. J. Alloy. Comp. 455(1–2), 255 (2008).CrossRefGoogle Scholar
10.Chen, H.Y., Zhao, X.B., Zhu, T.J., Jiang, J.Z., Stiewe, C., Lathe, C., and Mueller, E.: In situ energy dispersive x-ray diffraction study of iron disilicide thermoelectric materials. J. Phys. Chem. Solids 69(8), 2013 (2008).Google Scholar
11.Nishida, I., Masumoto, K., Kawasumi, I., and Sakata, M.: Striations and crystal structure of the matrix in the MnSi-Si alloy system. J. Less-Common Met. 71(2), 293 (1980).Google Scholar
12.Aoyama, I., Fedorov, M.I., Zaitsev, V.K., Solomkin, F.Y., Eremin, I.S., Samunin, A.Y., Mukoujima, M., Sano, S., and Tsuji, T.: Effects of Ge doping on micromorphology of MnSi in MnSi-1.7 and on their thermoelectric transport properties. Jpn. J. Appl. Phys. 44(12), 8562 (2005).Google Scholar
13.Kaempfe, I., Luczak, F., and Michel, B.: Energy dispersive x-ray diffraction. Part. Part. Syst. Char. 22(6), 391 (2005).CrossRefGoogle Scholar
14.Zaitsev, V.K., Ordin, S.V., Rakhimov, K.A., and Engalychev, A.E.: Characteristics of the crystal structure and thermoelectric power of the higher manganese silicide. Sov. Phys. Sol. Sta. 23(2), 353 (1981).Google Scholar
15.Venkataraman, K.S. and Narayanan, K.S.: Energetics of collision between grinding media in ball mills and mechanochemical effects. Powd. Tech. 96(3), 190 (1998).CrossRefGoogle Scholar
16.Kanibolotskii, D.S. and Lesnyak, V.V.: Thermodynamic properties of Mn-Si alloys. Russ. Metall. 2006, 199 (2006).Google Scholar