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Graphene oxide coated popcorn-like Ag nanoparticles for reliable sensitive surface-enhanced Raman scattering detection of drug residues

Published online by Cambridge University Press:  12 March 2019

Maofeng Zhang Open the ORCID record for Maofeng Zhang [Opens in a new window] ,
Zhexue Chen ,
Zhuoer Wang ,
Zhiyuan Zheng  and
Dapeng Wang
Maofeng Zhang*
Affiliation:
School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, People’s Republic of China
Zhexue Chen
Affiliation:
School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, People’s Republic of China
Zhuoer Wang*
Affiliation:
School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, People’s Republic of China
Zhiyuan Zheng
Affiliation:
School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, People’s Republic of China
Dapeng Wang*
Affiliation:
Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031, People’s Republic of China
*
a)Address all correspondence to these authors. e-mail: mfzhang@hfut.edu.cn
b)e-mail: dpwang@iim.ac.cn
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Abstract

Conventional methods for determination of trace drug residues are either time consuming or labor intensive or require large specialized instruments, which hamper their practical applications in field analysis. Here, we present a rapid and quantitative surface-enhanced Raman scattering (SERS) detection method coupled with a portable Raman spectrometer for determination of trace drug residues on fish surface. Graphene oxide (GO) decorated popcorn-like Ag nanoparticles (NPs) on Cu plate (GO/AgNPs/Cu) were fabricated by a facile approach and directly employed as a robust SERS detection substrate. For practical SERS detections, trace-level residues of crystal violet (10−8 M, 4.1 ng/g) and malachite green (10−8 M, 3.6 ng/g) could be readily detected by simply swabbing the contaminated fish scale surface with the SERS substrate. Importantly, SERS detection was quantitatively realized in the broad linear concentrations. Compared with lab-based Raman spectrometer with large footprints, our method has potential applications in practical rapid, accurate, and on-site SERS determination.

Keywords

AgnanostructureRaman spectroscopy
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 17: Focus Issue: Building Advanced Materials via Particle Aggregation and Molecular Self-Assembly , 16 September 2019 , pp. 2935 - 2943
Copyright
Copyright © Materials Research Society 2019 

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