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A highly robust and reusable polyimide-supported nanosilver catalyst for the reduction of 4-nitrophenol

Published online by Cambridge University Press:  02 September 2015

Jun Li ,
Ya Wang ,
Mingyu Wang ,
Lisi Wang  and
Hengfeng Li
Jun Li*
Affiliation:
Department of Materials Chemistry, School of Materials and Engineering, Central South University, Changsha, Hunan 410083, China
Ya Wang
Affiliation:
Department of Materials Chemistry, School of Materials and Engineering, Central South University, Changsha, Hunan 410083, China
Mingyu Wang
Affiliation:
Department of Materials Chemistry, School of Materials and Engineering, Central South University, Changsha, Hunan 410083, China
Lisi Wang
Affiliation:
Department of Materials Chemistry, School of Materials and Engineering, Central South University, Changsha, Hunan 410083, China
Hengfeng Li*
Affiliation:
Department of Materials Chemistry, School of Materials and Engineering, Central South University, Changsha, Hunan 410083, China
*
a)Address all correspondence to this author. e-mail: lihf@csu.edu.cn
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Abstract

A simple and efficient method for in situ preparation of highly stable polyimide (PI)-supported silver nanoparticles (AgNPs) was proposed. This process achieves excellent dispersion and high stability of AgNPs in the PI matrix. The formation of AgNPs in PI and the morphology evolution of PI/Ag nanocomposites were characterized by x-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy (FT-IR), and x-ray photoelectron spectra studies. The catalytic properties of these PI-supported AgNPs were investigated by monitoring the reduction of 4-nitrophenol by excess NaBH4 in water. The catalytic reaction was observed to have a pseudo first-order rate constant of 0.567 min−1 (9.45 × 10−3 s−1), which is comparable to other heterogeneous silver catalysts reported in the literature. Notably, the PI-supported AgNPs retained their relatively high catalytic activity over seven recycles with almost no leaching of catalytic species in the reaction solution. Moreover, the catalytic activity of the catalyst is still quite appreciable even after a six-month shelf-storage under room temperature.

Keywords

polyimide-supported catalystsilver nanoparticleheterogeneous catalysisrecyclability4-nitrophenol
Type
Articles
Information
Journal of Materials Research , Volume 30 , Issue 18 , 28 September 2015 , pp. 2713 - 2721
Copyright
Copyright © Materials Research Society 2015 

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