Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-26T19:11:30.278Z Has data issue: false hasContentIssue false
  • English
  • Français

High-performance supercapacitor electrodes based on NiMoO4 nanorods

Published online by Cambridge University Press:  20 May 2019

Yong Zhang Open the ORCID record for Yong Zhang [Opens in a new window] ,
Cui-rong Chang ,
Hai-li Gao ,
Shi-wen Wang ,
Ji Yan ,
Ke-zheng Gao ,
Xiao-dong Jia ,
He-wei Luo ,
Hua Fang  and
Ai-qin Zhang
...Show all authors
Yong Zhang*
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China; and Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, China
Cui-rong Chang
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Hai-li Gao*
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Shi-wen Wang
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Ji Yan
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Ke-zheng Gao*
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Xiao-dong Jia
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
He-wei Luo
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Hua Fang
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Ai-qin Zhang
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
Li-zhen Wang
Affiliation:
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: zy@zzuli.edu.cn
b)e-mail: gaohaili@zzuli.edu.cn
Get access

Abstract

Novel NiMoO4-integrated electrode materials were successfully prepared by solvothermal method using Na2MoO4·2H2O and NiSO4·6H2O as main raw materials, water, and ethanol as solvents. The morphology, phase, and structure of the as-prepared materials were characterized by SEM, XRD, Raman, and FT-IR. The electrochemical properties of the materials in supercapacitors were investigated by cyclic voltammetry, constant current charge–discharge, and electrochemical impedance spectroscopy techniques. The effects of volume ratio of water to ethanol (W/E) in solvent on the properties of the product were studied. The results show that the pure phase monoclinic crystal NiMoO4 product can be obtained when the W/E is 2:1. The diameter and length are 0.1–0.3 µm and approximately 3 µm, respectively. As an active material for supercapacitor, the NiMoO4 nanorods material delivered a discharge specific capacitance of 672, 498, and 396 F/g at a current density of 4, 7, and 10 A/g, respectively. The discharge specific capacitance slightly decreased from 815 to 588 F/g with a retention of 72% after 1000 cycles at a current density of 1 A/g. With these superior capacitance properties, the novel NiMoO4 integrated electrode materials could be considered as promising material for supercapacitors.

Keywords

solvothermal methodNiMoO4-integrated electrode materialsnickel foamspecific capacitanceelectrochemical properties
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 14 , 28 July 2019 , pp. 2435 - 2444
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Zang, H-Y., Lan, Y-Q., Yang, G-S., Wang, X-L., Shao, K-Z., Xu, G-J., and Su, Z-M.: Construction and property investigation of transition-metal complexes modified octamolybdate hybrid materials based on V-shaped organic ligands. CrystEngComm 12, 434 (2010).CrossRefGoogle Scholar
Jeseentharani, V., Dayalan, A., and Nagaraja, K.S.: Nanocrystalline composites of transition metal molybdate (Ni1−xCoxMoO4; x = 0, 0.3, 0.5, 0.7, 1) synthesized by a co-precipitation method as humidity sensors and their photoluminescence properties. J. Phys. Chem. Solids 115, 75 (2018).CrossRefGoogle Scholar
Jin, M., Lu, S., Ma, L., and Gan, M.: One-step synthesis of in situ reduced metal Bi decorated bismuth molybdate hollow microspheres with enhancing photocatalytic activity. Appl. Surf. Sci. 396, 438 (2017).CrossRefGoogle Scholar
Watcharatharapong, T., Minakshi Sundaram, M., Chakraborty, S., Li, D., Shafiullah, G.M., Aughterson, R.D., and Ahuja, R.: Effect of transition metal cations on stability enhancement for molybdate-based hybrid supercapacitor. ACS Appl. Mater. Interfaces 9, 17977 (2017).CrossRefGoogle ScholarPubMed
Wang, Y-Y., Zhang, M., Li, S-L., Zhang, S-R., Xie, W., Qin, J-S., Su, Z-M., and Lan, Y-Q.: Diamondoid-structured polymolybdate-based metal–organic frameworks as high-capacity anodes for lithium-ion batteries. Chem. Commun. 53, 5204 (2017).CrossRefGoogle ScholarPubMed
Xu, R., Lin, J., Wu, J., Huang, M., Fan, L., Xu, Z., and Song, Z.: A high-performance pseudocapacitive electrode material for supercapacitors based on the unique NiMoO4/NiO nanoflowers. Appl. Surf. Sci. 463, 721 (2019).CrossRefGoogle Scholar
Silva, R.M., Noremberg, B.S., Marins, N.H., Milne, J., Zhitomirsky, I., and Carreño, N.L.V.: Microwave-assisted hydrothermal synthesis and electrochemical characterization of niobium pentoxide/carbon nanotubes composites. J. Mater. Res. 34, 592 (2019).CrossRefGoogle Scholar
Neeraj, N.S., Mordina, B., Srivastava, A.K., Mukhopadhyay, K., and Prasad, N.E.: Impact of process conditions on the electrochemical performances of NiMoO4 nanorods and activated carbon based asymmetric supercapacitor. Appl. Surf. Sci. 473, 807 (2019).CrossRefGoogle Scholar
Wang, H. and Cui, J.: Preparation of NiCo2O4 with different morphologies and its effect on absorbing properties. Mater. Lett. 236, 465 (2019).CrossRefGoogle Scholar
Altarawneh, I.S., Rawadieh, S.E., Batiha, M.A., Al-Makhadmeh, L.A., Al-Shaweesh, M.A., and Altarawneh, M.K.: Structures and thermodynamic stability of cobalt molybdenum oxide (CoMoO4-II). Surf. Sci. 677, 52 (2018).CrossRefGoogle Scholar
Wei, H., Yang, J., Zhang, Y., Qian, Y., and Geng, H.: Rational synthesis of graphene-encapsulated uniform MnMoO4 hollow spheres as long-life and high-rate anodes for lithium-ion batteries. J. Colloid Interface Sci. 524, 256 (2018).CrossRefGoogle ScholarPubMed
Qing, C., Yang, C., Chen, M., Li, W., Wang, S., and Tang, Y.: Design of oxygen-deficient NiMoO4 nanoflake and nanorod arrays with enhanced supercapacitive performance. Chem. Eng. J. 354, 182 (2018).CrossRefGoogle Scholar
Wang, B., Li, S., Wu, X., Liu, J., and Tian, W.: Hierarchical NiMoO4 nanowire arrays supported on macroporous graphene foam as binder-free 3D anodes for high-performance lithium storage. Phys. Chem. Chem. Phys. 18, 908 (2016).CrossRefGoogle ScholarPubMed
Cao, M., Bu, Y., Lv, X., Jiang, X., Wang, L., Dai, S., Wang, M., and Shen, Y.: Three-dimensional TiO2 nanowire@NiMoO4 ultrathin nanosheet core–shell arrays for lithium ion batteries. Appl. Surf. Sci. 435, 641 (2018).CrossRefGoogle Scholar
Cai, D., Liu, B., Wang, D., Liu, Y., Wang, L., Li, H., Wang, Y., Wang, C., Li, Q., and Wang, T.: Facile hydrothermal synthesis of hierarchical ultrathin mesoporous NiMoO4 nanosheets for high performance supercapacitors. Electrochim. Acta 115, 358 (2014).CrossRefGoogle Scholar
Chen, C., Yan, D., Luo, X., Gao, W., Huang, G., Han, Z., Zeng, Y., and Zhu, Z.: Construction of core–shell NiMoO4@Ni–Co–S nanorods as advanced electrodes for high-performance asymmetric supercapacitors. ACS Appl. Mater. Interfaces 10, 4662 (2018).CrossRefGoogle ScholarPubMed
Li, Y., Jian, J., Fan, Y., Wang, H., Yu, L., Cheng, G., Zhou, J., and Sun, M.: Facile one-pot synthesis of a NiMoO4/reduced graphene oxide composite as a pseudocapacitor with superior performance. RSC Adv. 6, 69627 (2016).CrossRefGoogle Scholar
Huang, Y., Cui, F., Zhao, Y., Lian, J., Bao, J., and Li, H.: Controlled growth of ultrathin NiMoO4 nanosheets on carbon nanofiber membrane as advanced electrodes for asymmetric supercapacitors. J. Alloys Compd. 753, 176 (2018).CrossRefGoogle Scholar
Nti, F., Anang, D.A., and Han, J.I.: Facilely synthesized NiMoO4/CoMoO4 nanorods as electrode material for high performance supercapacitor. J. Alloys Compd. 742, 342 (2018).CrossRefGoogle Scholar
Ezeigwe, E.R., Khiew, P.S., Siong, C.W., Kong, I., and Tan, M.T.T.: Synthesis of NiMoO4 nanorods on graphene and superior electrochemical performance of the resulting ternary based composites. Ceram. Int. 43, 13772 (2017).CrossRefGoogle Scholar
Cai, D., Liu, B., Wang, D., Liu, Y., Wang, L., Li, H., Wang, Y., Wang, C., Li, Q., and Wang, T.: Enhanced performance of supercapacitors with ultrathin mesoporous NiMoO4 nanosheets. Electrochim. Acta 125, 294 (2014).CrossRefGoogle Scholar
Wei, C., Huang, Y., Yan, J., Chen, X., and Zhang, X.: Synthesis of hierarchical carbon sphere@NiMoO4 composite materials for supercapacitor electrodes. Ceram. Int. 42, 15694 (2016).CrossRefGoogle Scholar
Cai, D., Wang, D., Liu, B., Wang, Y., Liu, Y., Wang, L., Li, H., Huang, H., Li, Q., and Wang, T.: Comparison of the electrochemical performance of NiMoO4 nanorods and hierarchical nanospheres for supercapacitor applications. ACS Appl. Mater. Interfaces 5, 12905 (2013).CrossRefGoogle ScholarPubMed
Ji, J., Zhang, L.L., Ji, H., Li, Y., Zhao, X., Bai, X., Fan, X., Zhang, F., and Ruoff, R.S.: Nanoporous Ni(OH)2 thin film on 3D ultrathin-graphite foam for asymmetric supercapacitor. ACS Nano 7, 6237 (2013).CrossRefGoogle ScholarPubMed
Adhikary, M.C., Priyadarsini, M.H., Rath, S.K., and Das, C.K.: 3D porous NiMoO4 nanoflakes arrays for advanced supercapacitor electrodes. J. Nanopart. Res. 19, 314 (2017).CrossRefGoogle Scholar
Hammond, O.S., Edler, K.J., Bowron, D.T., and Torrente-Murciano, L.: Deep eutectic-solvothermal synthesis of nanostructured ceria. Nat. Commun. 8, 14150 (2017).CrossRefGoogle ScholarPubMed
Quan, B., Yu, S-H., Chung, D.Y., Jin, A., Park, J.H., Sung, Y-E., and Piao, Y.: Single source precursor-based solvothermal synthesis of heteroatom-doped graphene and its energy storage and conversion applications. Sci. Rep. 4, 5639 (2014).CrossRefGoogle ScholarPubMed
Gao, H., Wu, F., Wang, X., Hao, C., and Ge, C.: Preparation of NiMoO4-PANI core–shell nanocomposite for the high-performance all-solid-state asymmetric supercapacitor. Int. J. Hydrogen Energy 43, 18349 (2018).CrossRefGoogle Scholar
Chen, C., Wang, S., Luo, X., Gao, W., Huang, G., Zeng, Y., and Zhu, Z.: Reduced ZnCo2O4@NiMoO4·H2O heterostructure electrodes with modulating oxygen vacancies for enhanced aqueous asymmetric supercapacitors. J. Power Sources 409, 112 (2019).CrossRefGoogle Scholar
Hong, W., Wang, J., Gong, P., Sun, J., Niu, L., Yang, Z., Wang, Z., and Yang, S.: Rational construction of three dimensional hybrid Co3O4@NiMoO4 nanosheets array for energy storage application. J. Power Sources 270, 516 (2014).CrossRefGoogle Scholar
Senthilkumar, B. and Kalai Selvan, R.: Hydrothermal synthesis and electrochemical performances of 1.7 V NiMoO4·xH2O‖FeMoO4 aqueous hybrid supercapacitor. J. Colloid Interface Sci. 426, 280 (2014).CrossRefGoogle ScholarPubMed
Chen, Y., Liu, B., Liu, Q., Wang, J., Liu, J., Zhang, H., Hu, S., and Jing, X.: Flexible all-solid-state asymmetric supercapacitor assembled using coaxial NiMoO4 nanowire arrays with chemically integrated conductive coating†. Electrochim. Acta 178, 429 (2015).CrossRefGoogle Scholar
Lin, L., Liu, T., Liu, J., Sun, R., Hao, J., Ji, K., and Wang, Z.: Facile synthesis of groove-like NiMoO4 hollow nanorods for high-performance supercapacitors. Appl. Surf. Sci. 360(Part A), 234 (2016).CrossRefGoogle Scholar
Abdel-Dayem, H.M.: Dynamic phenomena during reduction of α-NiMoO4 in different atmospheres: In situ thermo-Raman spectroscopy study. Ind. Eng. Chem. Res. 46, 2466 (2007).CrossRefGoogle Scholar
Fan, X., Li, J., Zhao, Z., Wei, Y., Liu, J., Duan, A., and Jiang, G.: Synthesis of a new ordered mesoporous NiMoO4 complex oxide and its efficient catalytic performance for oxidative dehydrogenation of propane. J. Energy Chem. 23, 171 (2014).CrossRefGoogle Scholar
Jothi, P.R., Shanthi, K., Salunkhe, R.R., Pramanik, M., Malgras, V., Alshehri, S.M., and Yamauchi, Y.: Synthesis and characterization of α-NiMoO4 nanorods for supercapacitor application. Eur. J. Inorg. Chem. 2015, 3694 (2015).CrossRefGoogle Scholar
Hu, W., Yu, J., Jiang, X., Liu, X., Jin, R., Lu, Y., Zhao, L., Wu, Y., and He, Y.: Enhanced photocatalytic activity of g-C3N4 via modification of NiMoO4 nanorods. Colloids Surf., A 514, 98 (2017).CrossRefGoogle Scholar
Seevakan, K., Manikandan, A., Devendran, P., Shameem, A., and Alagesan, T.: Microwave combustion synthesis, magneto-optical and electrochemical properties of NiMoO4 nanoparticles for supercapacitor application. Ceram. Int. 44, 13879 (2018).CrossRefGoogle Scholar
Senthilkumar, B., Vijaya Sankar, K., Kalai Selvan, R., Danielle, M., and Manickam, M.: Nano α-NiMoO4 as a new electrode for electrochemical supercapacitors. RSC Adv. 3, 352 (2013).CrossRefGoogle Scholar
Kazemi, S.H., Bahmani, F., Kazemi, H., and Kiani, M.A.: Binder-free electrodes of NiMoO4/graphene oxide nanosheets: Synthesis, characterization and supercapacitive behavior. RSC Adv. 6, 111170 (2016).CrossRefGoogle Scholar
Dong, T., Li, M., Wang, P., and Yang, P.: Synthesis of hierarchical tube-like yolk–shell Co3O4@NiMoO4 for enhanced supercapacitor performance. Int. J. Hydrogen Energy 43, 14569 (2018).CrossRefGoogle Scholar
Zhang, S-W., Yin, B-S., Liu, C., Wang, Z-B., and Gu, D-M.: NiMoO4 nanowire arrays and carbon nanotubes film as advanced electrodes for high-performance supercapacitor. Appl. Surf. Sci. 458, 478 (2018).CrossRefGoogle Scholar
Tian, X., Li, X., Yang, T., Wang, K., Wang, H., Song, Y., Liu, Z., and Guo, Q.: Porous worm-like NiMoO4 coaxially decorated electrospun carbon nanofiber as binder-free electrodes for high performance supercapacitors and lithium-ion batteries. Appl. Surf. Sci. 434, 49 (2018).CrossRefGoogle Scholar
Wang, B., Li, S., Wu, X., Tian, W., Liu, J., and Yu, M.: Integration of network-like porous NiMoO4 nanoarchitectures assembled with ultrathin mesoporous nanosheets on three-dimensional graphene foam for highly reversible lithium storage. J. Mater. Chem. A 3, 13691 (2015).CrossRefGoogle Scholar