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High-resolution electron microscopy of amorphization of Cu4 Ti3

Published online by Cambridge University Press:  31 January 2011

D.E. Luzzi
Affiliation:
Department of Materials Science and Engineering and the Materials Research Center, Northwestern University, Evanston, Illinois 60201
M. Meshii
Affiliation:
Department of Materials Science and Engineering and the Materials Research Center, Northwestern University, Evanston, Illinois 60201
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Abstract

The electron irradiation-induced, crystalline-to-amorphous transition was studied in the intermetallic compound Cu4Ti3 by high-resolution electron microscopy. Using highresolution maps from the crystalline region into the amorphized region, the amorphization process and the amorphous structure were examined. The extent of chemical order in crystalline regions just prior to amorphization was studied by simultaneously imaging superlattice and fundamental lattice fringe contrast. The chemical order continuously decreased in these regions but faint superlattice contrast was recognized as long as the crystalline feature remained on the image, supporting the theory that chemical disordering is the major driving force for amorphization. The amorphization process appears to be evolutionary, leading to a nanocrystalline type of amorphous structure. A model of the amorphization process is proposed based on the present results and those from previous studies.

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Articles
Copyright
Copyright © Materials Research Society 1986

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References

REFERENCES

1Luzzi, D. E. and Meshii, M., Scr. Metall. 20, 943 (1986); D. E. Luzzi and M. Meshii, Res. Mech. (in press).Google Scholar
2Luzzi, D. E., Mori, H., Fujita, H., and Meshii, M., Scr. Metall. 18, 957 (1984).Google Scholar
3Luzzi, D. E., Mori, H., Fujita, H., and Meshii, M., Scr. Metall. 19, 897 (1985).Google Scholar
4Luzzi, D. E., Mori, H., Fujita, H., and Meshii, M., Acta Metall. 34,629 (1986).Google Scholar
5Luzzi, D. E., Mori, H., Fujita, H., and Meshii, M., in In Situ Experiments with HVEM, Osaka, Japan (1985), p. 472.Google Scholar
6Luzzi, D. E., Mori, H., Fujita, H., and Meshii, M., Beam-Solid Interactions and Phase Transitions, edited by Kurz, H., Olson, G. L., and Poate, J.M., Materials Research Society Symposium Proceedings, Symposium A, Boston, MA (Materials Research Society, Pittsburgh, PA, 1986), p. 479.Google Scholar
7Fujita, H., J. Electron Microsc. Tech. 3, 45 (1986).Google Scholar
8Bragg, W. L. and Williams, E. J., Proc. R. Soc. London Ser. A 145, 699 (1934).Google Scholar
9Luzzi, D.E., Mori, H., Fujita, H., and Meshii, M., Materials Problem Solving with the Transmission Electron Microscope, edited by Hobbs, L. M., Westmacott, H. K., and Williams, D. B., Materials Research Society Symposium Proceedings, Symposium Q, Boston, MA, December 1985 (in press).Google Scholar
10Schubert, K., Z. Metallkd. 56, 197 (1965).Google Scholar
11Eremenko, V. N., Buyanov, Y. I., and Prima, S. B., Poroshk. Metall. 42, 77 (1966).Google Scholar
12Spence, J. C. H., Experimental High-Resolution Electron Microscopy (Clarendon, Oxford, 1981), p. 277.Google Scholar
13Marks, L. D., Ultramicroscopy 18, 33 (1985).Google Scholar
14Luzzi, D. E., Ph.D. dissertation, Northwestern University, 1986.Google Scholar
15Shiojiri, M., Miyano, T., and Kaito, C., Jpn. J. Appl. Phys. 18, 1937 (1979).Google Scholar
16Sinclair, R., Schneider, K., and Thomas, G., Acta Metall. 23, 873 (1975).Google Scholar
17Marks, L. D. (private communication).Google Scholar