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Hydrothermal synthesis of PbTiO3 films

Published online by Cambridge University Press:  31 January 2011

Woo-Seok Cho  and
Masahiro Yoshimura
Woo-Seok Cho
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
Masahiro Yoshimura
Affiliation:
Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226, Japan
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Abstract

Well-crystallized polycrystalline films of tetragonal PbTiO3 have been synthesized on Ti metal substrates in concentrated alkaline solutions of Pb(OH)2 containing KOH by the hydrothermal method under saturated vapor pressure (2.0 MPa) at 200 °C. The film microstructure depended strongly on the Pb(OH)2 and KOH concentration. The grain size became larger from approximately 0.6 to 6 μm with an increase of KOH concentration from 1 to 4 M at 0.07 M Pb(OH)2, whereas the grains decreased in size with an increase of Pb(OH)2 concentration at 1 M KOH concentration. PbTiO3 film prepared in the aqueous solution of 0.07 M Pb(OH)2 containing 2 M KOH showed a relative dielectric constant of about 215 and loss of about 5% at 1 kHz.

Type
Articles
Information
Journal of Materials Research , Volume 12 , Issue 3 , March 1997 , pp. 833 - 839
Copyright
Copyright © Materials Research Society 1997

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References

1.Herbert, J. M., Ceramic Dielectrics and Capacitors (Gordon and Breach Science Publishers, New York, 1985), pp. 171–187.Google Scholar
2.Rice, R. W. and Pohanka, R. C., J. Am. Ceram. Soc. 62, 559 (1979).CrossRefGoogle Scholar
3.Iijima, K., Tomita, Y., Takayama, R., and Ueda, I., J. Appl. Phys. 60, 361 (1986).CrossRefGoogle Scholar
4.Nakagawa, T., Yamaguchi, J., Okuyama, M., and Hamakawa, Y., Jpn. J. Appl. Phys. 21, L655 (1982).CrossRefGoogle Scholar
5.Okuyama, M. and Hamakawa, Y., Ferroelectrics 63, 243 (1985).CrossRefGoogle Scholar
6.Schwartz, R. W., Xu, Z., Payne, D. A., Detemple, T. A., and Bradley, M. A., in Ferroelectric Thin Films, edited by Myers, E. R. and Kingon, A. I. (Mater. Res. Soc. Symp. Proc. 200, Pittsburgh, PA, 1990), pp. 167–172.Google Scholar
7.Kaneko, S. and Imoto, F., Bull. Chem. Soc. Jpn. 51, 1739 (1978).CrossRefGoogle Scholar
8.Takai, K., Shoji, S., Naito, H., and Sawaoka, A., in Proceedings of the First International Symposium on Hydrothermal Reactions, edited by Sōmiya, S. (Gakujutsu Bunken Fukyu-Kai, Tokyo, Japan, 1982), pp. 877–885.Google Scholar
9.Kutty, T. R. N. and Balachandran, R., Mater. Res. Bull. 19, 1479 (1984).CrossRefGoogle Scholar
10.Suzuki, M., Uedaira, S., Masuya, H., and Tamura, H., in Ceramic Transactions, Ceramic Powder Science IIA, edited by Messing, G. L., Fuller, E. R. Jr, and Hausner, H. (The American Ceramic Society, Westerville, OH, 1988), Vol. 1, pp. 163–170.Google Scholar
11.Watson, D. J., Randall, C. A., Newnham, R. E., and Adair, J. H., in Ceramic Transactions, Ceramic Powder Science IIA, edited by Messing, G. L., Fuller, E. R. Jr, and Hausner, H. (The American Ceramic Society, Westerville, OH, 1988), Vol. 1, pp. 154–162.Google Scholar
12.Rosetti, G. A. Jr, Watson, D. J., Newnham, R. E., and Adair, J. H., J. Cryst. Growth 116, 251 (1992).Google Scholar
13.Yoshimura, M., Yoo, S. E., Hayashi, M., and Ishizawa, N., Jpn. J. Appl. Phys. 28, L2007 (1989).Google Scholar
14.Yoshimura, M., Yoo, S. E., Hayashi, M., and Ishizawa, N., in Ceramic Transactions, Vol. 15, Microelectronic Systems, edited by Nair, K. M., Pohanka, R., and Buchanan, R. C. (The American Ceramic Society, Westerville, OH, 1990), pp. 427–436.Google Scholar
15.Ishizawa, N., Yoo, S. E., Hayashi, M., and Yoshimura, M., in Ferroelectric Thin Films, edited by Myers, E. R. and Kingon, A. I. (Mater. Res. Soc. Symp. Proc. 200, Pittsburgh, PA, 1990), pp. 57–62.Google Scholar
16.Yoo, S. E., Hayashi, M., Ishizawa, N., and Yoshimura, M., J. Am. Ceram. Soc. 73, 2561 (1990).CrossRefGoogle Scholar
17.Sakabe, Y., Hamaji, Y., Hayashi, M., Ogino, Y., Ishizawa, N., and Yoshimura, M., in Proceedings of The Fifth U.S.–Japan Seminar on Dielectric and Piezoelectric Ceramics, Kyoto, Japan (1990), pp. 300–303.Google Scholar
18.Kajiyoshi, K., Tomono, K., Hamaji, Y., Kasanami, T., and Yoshimura, M., J. Mater. Res. 9, 2109 (1994).CrossRefGoogle Scholar
19.Bacsa, R. R., Dougherty, J. P., and Pilione, L. J., Appl. Phys. Lett. 63, 1053 (1993).CrossRefGoogle Scholar
20.Pilleux, M. E. and Fuenzalida, V. M., J. Appl. Phys. 74, 4664 (1993).Google Scholar
21.Bendale, P., Venigalla, S., Ambrose, J. R., Verink, E. D. Jr, and Adair, J. H., J. Am. Ceram. Soc. 76, 2619 (1993).Google Scholar
22.Bacsa, R. R., Ravindranathan, P., and Dougherty, J. P., J. Mater. Res. 7, 423 (1992).CrossRefGoogle Scholar
23.Shimomura, K., Tsurumi, T., Ohba, Y., and Daimon, M., Jpn. J. Appl. Phys. 30, 2174 (1991).Google Scholar
24.Kikuchi, T., Tsurumi, T., Ohba, Y., and Daimon, M., Jpn. J. Appl. Phys. 31, 3090 (1992).CrossRefGoogle Scholar
25.Ohba, Y., Miyauchi, M., Tsurumi, T., and Daimon, M., Jpn. J. Appl. Phys. 32, 4095 (1993).CrossRefGoogle Scholar
26. Powder Diffraction File, No. 6–0452 (Joint Committee on Powder Diffraction Standards, International Centre for Diffraction Data, Newtowne Square, PA, 1967).Google Scholar
27.Burns, G. and Scott, B. A., Phys. Rev. Lett. 25, 1191 (1970).CrossRefGoogle Scholar
28.Kakuta, K., Tsurumi, T., and Fukunaga, O., Jpn. J. Appl. Phys. 34, 5341 (1995).Google Scholar
29.Agrawal, D. C. and Raj, R., Acta Metall. 37, 2035 (1989).CrossRefGoogle Scholar
30.Kennefick, C. M. and Raj, R., Acta Metall. 37, 2974 (1989).Google Scholar
31.Miller, K. T., Lange, F. F., and Marshall, D. B., J. Mater. Res. 5, 151 (1990).Google Scholar
32.West, J. M., Basic Corrosion and Oxidation (Ellis Horwood Limited, Chichester, England, 1980), pp. 163–181.Google Scholar
33.Lencka, M. M. and Riman, R. E., Chem. Mater. 5, 61 (1993).CrossRefGoogle Scholar
34.Lencka, M. M. and Riman, R. E., J. Am. Ceram. Soc. 76, 2649 (1993).CrossRefGoogle Scholar
35.Pourbaix, M., Atlas of Electrochemical Equilibria in Aqueous Solution, 2nd ed. (National Association of Corrosion Engineers, Houston, TX, 1974), pp. 485–492.Google Scholar
36.Schrey, F., J. Am. Ceram. Soc. 48, 401 (1965).Google Scholar
37.Osseo-Asare, K., Arriagada, F. J., and Adair, J. H., in Ceramic Transactions, Ceramic Powder Science II, edited by Messing, G. L., Fuller, E. R. Jr, and Hausner, H. (The American Ceramic Society, Westerville, OH, 1988), Vol. 1, pp. 47–53.Google Scholar