Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-29T12:41:13.677Z Has data issue: false hasContentIssue false
  • English
  • Français

Ignition and reaction mechanisms of thermal explosion reaction in the Ni-Ti-C system under air and Ar

Published online by Cambridge University Press:  31 January 2011

Y.F. Yang ,
H.Y. Wang ,
J.G. Wang ,
R.Y. Zhao  and
Q.C. Jiang
Q.C. Jiang*
Affiliation:
Key Laboratory of Automobile Materials of Ministry of Education and Department of Materials Science and Engineering, Jilin University, Nanling Campus, Changchun 130025, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: jqc@jlu.edu.cn
Get access

Abstract

The ignition and reaction mechanisms of the thermal explosion reaction in the Ni-Ti-C system under air and Ar conditions were investigated. The reaction for the formation of TiC can be initiated at a low temperature under air. The ignition temperature under air is much lower than that under Ar. Under Ar, both the ignition and reaction mechanisms consist of dissolution, reaction, and precipitation. Under air, the ignition mechanism is confirmed to be the chemical oven mechanism, and the reaction mechanism is dissolution, reaction, and precipitation. The mechanism of gas transport plays a much more minor role in the ignition and reaction processes under air.

Keywords

CeramicCombustion synthesis (SHS)Differential thermal analysis (DTA)
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 10 , October 2009 , pp. 3197 - 3205
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Xiao, G.Q., Fan, Q.C., Gu, M.Z., Wang, Z.H., and Jin, Z.H.: Dissolution-precipation mechanism of self-propagating hightemperature synthesis of TiC-Ni cermet. Mater. Sci. Eng., A 382, 132 (2004).CrossRefGoogle Scholar
2.Moore, J.J. and Feng, H.J.: Combustion synthesis of advanced materials: Part I. Reaction parameters. Prog. Mater. Sci. 39, 243 (1995).CrossRefGoogle Scholar
3.Yi, H.C. and Moore, J.J.: Self-propagating high-temperature synthesis (SHS) of powder-compacted materials. J. Mater. Sci. 25, 1159 (1990).CrossRefGoogle Scholar
4.Song, I., Wang, L., Wixom, M., and Thompson, L.T.: Selfpropagating high temperature synthesis and dynamic compaction of titanium diboride/titanium carbide composites. J. Mater. Sci. 35, 2611 (2000).CrossRefGoogle Scholar
5.Durlu, N.: Titanium carbide based composites for high temperature applications. J. Eur. Ceram. Soc. 19, 2415 (1999).CrossRefGoogle Scholar
6.Dunmead, S.D., Ready, D.W., Semler, C.E., and Holt, J.B.: Kinetics of combustion synthesis in the Ti-C and Ti-C-Ni systems. J. Am. Ceram. Soc. 72, 2318 (1989).CrossRefGoogle Scholar
7.LaSalvia, J.C., Kim, D.K., Lipsett, R.A., and Meyers, M.A.: Combustion synthesis in the Ti-C-Ni-Mo system. Part I. Micromechanisms. Metall. Mater. Trans. A 26, 3001 (1995).CrossRefGoogle Scholar
8.LaSalvia, J.C. and Meyers, M.A.: Combustion synthesis in the Ti-C-Ni-Mo system: Part II. Analysis. Metall. Mater. Trans. A 26, 3011 (1995).CrossRefGoogle Scholar
9.Mishra, S.K., Das, S.K., Ray, A.K., and Ramchandrarao, P.: Effect of nickel on sintering of self-propagating high-temperature synthesis produced titanium carbide. J. Mater. Res. 14, 3594 (1999).CrossRefGoogle Scholar
10.Wong, J., Larson, E.M., Holt, J.B., Waide, P.A., Rupp, B., and Frahm, R.: Time-resolved x-ray diffraction study of solid combustion reactions. Science 249, 1406 (1990).CrossRefGoogle ScholarPubMed
11.Fan, Q.C., Chai, H.F., and Jin, Z.H.: Role of iron addition in combustion synthesis of TiC-Fe cermet. J. Mater. Sci. 32, 4319 (1997).CrossRefGoogle Scholar
12.Shon, I.J. and Munir, Z.A.: Synthesis of TiC, TiC-Cu composites, and TiC-Cu functionally graded materials by electrothermal combustion. J. Am. Ceram. Soc. 81, 3243 (1998).CrossRefGoogle Scholar
13.Klinger, L., Gotman, I., and Horvitz, D.: In situ processing of TiB2/TiC ceramic composites by thermal explosion under pressure: Experimental study and modeling. Mater. Sci. Eng., A 302, 92 (2001).CrossRefGoogle Scholar
14.Atong, D. and Clark, D.E.: Ignition behavior and characteristics of microwave-combustion synthesized Al2O3–TiC powders. Ceram. Int. 30, 1909 (2004).CrossRefGoogle Scholar
15.Lee, J.H., Ko, S.K., and Won, C.W.: Combustion characteristics of TiO2/Al/C system. Mater. Res. Bull. 36, 1157 (2001).CrossRefGoogle Scholar
16.Choi, Y. and Rhee, S.W.: Reaction of TiO2-Al-C in the combustion synthesis of TiC-Al2O3 composite. J. Am. Ceram. Soc. 78, 986 (1995).CrossRefGoogle Scholar
17.Koc, R.: Kinetic and phase evolution during carbothermal synthesis of titanium carbide from ultrafine titania/carbon mixture. J. Mater. Sci. 33, 1049 (1998).CrossRefGoogle Scholar
18. M. Eslamloo-Grami and Munir, Z.A.: Effect of porosity on the combustion synthesis of titanium nitride. J. Am. Ceram. Soc. 73, 1235 (1990).Google Scholar
19. M. Eslamloo-Grami and Munir, Z.A.: Effect of nitrogen pressure and diluent content on the combustion synthesis of titanium nitride. J. Am. Ceram. Soc. 73, 2222 (1990).Google Scholar
20.Agrafiotis, C.C., Puszynski, J.A., and Hlavacek, V.: Experimental study on the synthesis of titanium and tantalum nitrides in the self-propagating regime. Combust. Sci. Technol. 76, 187 (1991).CrossRefGoogle Scholar
21.Merzhanov, A.G. and Borovinskaya, I.P.: Self-propagating hightemperature sysnthesis of inoganic compounds. Dokl. Akad. Nauk 204, 429 (1972).Google Scholar
22.Yeh, C.L. and Chuang, H.C.: Experimental studies on selfpropagating combustion synthesis of niobium nitride. Ceram. Int. 30, 733 (2004).CrossRefGoogle Scholar
23.Yeh, C.L., Liu, E.W., and Chang, Y.C.: Effect of preheating on synthesis of tantalum nitride by self-propagating combustion. J. Eur. Ceram. Soc. 24, 3807 (2004).CrossRefGoogle Scholar
24.Liang, Y.J. and Che, Y.C.: Handbook of Thermodynamic Data of Inorganics (Northeastern University Press, Shenyang, 1993).Google Scholar
25.Barin, I.: Thermochemical Data of Pure Substances, 2nd ed. (VCH GmbH, Weinheim, Germany, 1993).Google Scholar
26.Yang, Y.F., Wang, H.Y., Liang, Y.H., Zhao, R.Y., and Jiang, Q.C.: Effects of C particle size on the ignition and combustion characteristics of the SHS reaction in the 20wt%Ni-Ti-C system. J. Alloys Compd. 460, 276 (2008).CrossRefGoogle Scholar
27.Kakazey, M., Vlasova, M., Gonzalez-Rodriguez, J.G., Dominguez-Patino, M., and Leder, R.: X-ray and EPR study of reactions between B4C and TiO2. Mater. Sci. Eng., A 418, 111 (2006).CrossRefGoogle Scholar
28.Adachi, S., Wada, T., Mihara, T., Miyamoto, Y., Koizumi, M., and Yamada, O.: Fabrication of titanium carbide ceramics by highpressure self-combustion sintering of titanium powder and carbon fiber. J. Am. Ceram. Soc. 72, 805 (1989).CrossRefGoogle Scholar
29.Xu, J.G., Zhang, B.L., and Jiang, G.J.: Synthesis of SiCw/MoSi2 powder by the “chemical oven” self-propagating combustion method. Ceram. Int. 32, 633 (2006).CrossRefGoogle Scholar
30.Massalski, T.B., Okamoto, H., Subramanian, P.R., and Kacprzak, L.: Binary Alloy Phase Diagrams, 2nd ed. (ASM International, Materials Park, OH, 1990).Google Scholar
31.Holt, J.B. and Munir, Z.A.: Combution synthesis of titanium carbide: Theory and experiment. J. Mater. Sci. 21, 251 (1986).CrossRefGoogle Scholar