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Influence of additive composition on thermal and mechanical properties of β–Si3N4 ceramics

Published online by Cambridge University Press:  01 November 2004

Xinwen Zhu ,
Hiroyuki Hayashi ,
You Zhou  and
Kiyoshi Hirao
Xinwen Zhu
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Nagoya 463-8560, Japan
Hiroyuki Hayashi
Affiliation:
Toyota Technological Institute, Nagoya 468-8511, Japan
You Zhou
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Nagoya 463-8560, Japan
Kiyoshi Hirao*
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Nagoya 463-8560, Japan
*
a)Address all correspondence to this author.e-mail: k-hirao@aist.go.jp
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Abstract

Dense β–Si3N4 ceramics were fabricated from α–Si3N4 raw powder by gas-pressure sintering at 1900 °C for 12 h under a nitrogen pressure of 1 MPa, using four different kinds of additive compositions: Yb2O3–MgO, Yb2O3–MgSiN2, Y2O3–MgO, and Y2O3–MgSiN2. The effects of additive composition on the microstructure and thermal and mechanical properties of β–Si3N4 ceramics were investigated. It was found that the replacement of Yb2O3 by Y2O3 has no significant effect on the thermal conductivity and fracture toughness, but the replacement of MgO by MgSiN2 leads to an increase in thermal conductivity from 97 to 113 Wm-1K-1and fracture toughness from 8 to 10 MPa m1/2, respectively. The enhanced thermal conductivity of the MgSiN2-doped materials is attributed to the purification of β–Si3N4 grain and increase of Si3N4–Si3N4 contiguity, resulting from the enhanced growth of large elongated grains. The improved fracture toughness of the MgSiN2-doped materials is attributed to the increase of grain size and fraction of large elongated grains. However, the same thermal conductivity between the Yb2O3- and Y2O3-doped materials is related to not only their similar microstructures, but also the similar abilities of removing oxygen impurity in Si3N4 lattice between Yb2O3 and Y2O3. The same fracture toughness between the Yb2O3- and Y2O3-doped materials is consistent with their similar microstructures. This work implies that MgSiN2 is an effective sintering aid for developing not only high thermal conductivity (>110 Wm−1K−1) but also high fracture toughness (>10 MPa m1/2) of Si3N4 ceramics.

Keywords

CeramicThermal conductivityMechanical properties
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 11 , November 2004 , pp. 3270 - 3278
Copyright
Copyright © Materials Research Society 2004

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