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Influence of Al addition on microstructure and properties of Cu–Fe-based coatings by laser induction hybrid rapid cladding

Published online by Cambridge University Press:  09 April 2014

Shengfeng Zhou*
Affiliation:
Department of Computer Culture Basis, School of Information Engineering, Nanchang Hangkong University, Nanchang, Jiangxi 330063, People's Republic of China
Xiaoqin Dai
Affiliation:
Department of Computer Culture Basis, School of Information Engineering, Nanchang Hangkong University, Nanchang, Jiangxi 330063, People's Republic of China
Zheng Xiong
Affiliation:
Department of Chemistry and Materials, School of Science, Naval University of Engineering, Wuhan, Hubei 430033, People's Republic of China
Chao Wu
Affiliation:
Department of Metal Corrosion and Protection, School of Material Science and Engineering, Nanchang Hangkong University, Nanchang, Jiangxi 330063, People's Republic of China
Tianyou Zhang
Affiliation:
Department of Metal Corrosion and Protection, School of Material Science and Engineering, Nanchang Hangkong University, Nanchang, Jiangxi 330063, People's Republic of China
Zezhong Zhang
Affiliation:
Department of Metal Corrosion and Protection, School of Material Science and Engineering, Nanchang Hangkong University, Nanchang, Jiangxi 330063, People's Republic of China
*
a)Address all correspondence to this author. e-mail: zhousf1228@163.com
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Abstract

To establish the relationships between composition, microstructure, and properties, the influence of Al addition on microstructure and properties of Cu–Fe-based coatings by laser induction hybrid rapid cladding was studied. With increasing Al content, the main diffraction peaks of ε-Cu phase are weakened but those of α-Fe phase are strengthened, the size of Fe-rich particles generally increases but the dendrite arm spacing is further reduced, and the number of Cu-rich grains precipitated inside the Fe-rich particles increases but the size reduces. Moreover, when the amount of Al is increased, the improvement in electrochemical resistance is attributed to large amounts of fine Cu-rich grains precipitated inside the Fe-rich particles, which results in large anode–small cathode effect. The microhardness also increases with Al content and the microhardness of Cu53.5Fe36Al10C0.5 coating is approximately 2.4 times higher than that of copper alloy substrate.

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Articles
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Luo, X., Yang, Y., Liu, C., Xu, T., Yuan, M., and Huang, B.: The thermal expansion behavior of unidirectional SiC fiber-reinforced Cu-matrix composites. Scripta Mater. 58, 401 (2008).CrossRefGoogle Scholar
Kim, J.S., Kwon, Y.S., Lomovsky, O.I., Dudina, D.V., Kosarev, V.F., Klinkov, S.V., Kwon, D.H., and Smurov, I.: Cold spraying of in situ produced TiB2–Cu nanocomposite powders. Compos. Sci. Technol. 67, 2292 (2007).CrossRefGoogle Scholar
Liu, Q., He, X., Ren, S., Liu, T., Kang, Q., and Qu, X.: Fabrication and thermal conductivity of copper matrix composites reinforced with Mo2C or TiC coated graphite fibers. Mater. Res. Bull. 48, 4811 (2013).CrossRefGoogle Scholar
Deshpande, P.K. and Lin, R.Y.: Wear resistance of WC particle reinforced copper matrix composites and the effect of porosity. Mater. Sci. Eng., A 418, 137 (2006).CrossRefGoogle Scholar
Gu, D., Shen, Y., Zhao, L., Xiao, J., Wu, P., and Zhu, Y.: Effect of rare earth oxide addition on microstructures of ultra-fine WC–Co particulate reinforced Cu matrix composites prepared by direct laser sintering. Mater. Sci. Eng., A 445446, 316 (2007).CrossRefGoogle Scholar
Pei, Y.T., Ocelik, V., and De Hosson, J.Th.M.: SiCp/Ti6Al4V functionally graded materials produced by laser melt injection. Acta Mater. 50, 2035 (2002).CrossRefGoogle Scholar
Leong, C.C., Lu, L., Fuh, J.Y.H., and Wong, Y.S.: In-situ formation of copper matrix composites by laser sintering. Mater. Sci. Eng., A 338, 81 (2002).CrossRefGoogle Scholar
He, J., Zhao, J., Yang, Y., Wang, X., and Gao, L.: Microstructure development in finely atomized droplets of copper-iron alloys. Metall. Mater. Trans. A 36, 2449 (2005).CrossRefGoogle Scholar
Fu, L., Yang, J., Bi, Q., and Liu, W.: Combustion synthesis immiscible nanostructured Fe–Cu alloy. J. Alloys Compd. 482, L22 (2009).CrossRefGoogle Scholar
Munitz, A., Bamberger, A.M., Wannaparhun, S., and Abbaschian, R.: Effects of supercooling and cooling rate on the microstructure of Cu–Co–Fe alloys. J. Mater. Sci. 41, 2749 (2006).CrossRefGoogle Scholar
Ohnuma, I., Saegusa, T., Takaku, Y., Wang, C.P., and Liu, X.J.: Microstructural evolution of alloys powder for electronic materials with liquid miscibility gap. J. Electron. Mater. 38, 2 (2009).CrossRefGoogle Scholar
Wang, C.P., Liu, X.J., Ohnuma, I., Kainuma, R., and Ishida, K.: Formation of immiscible alloy powders with egg-type microstructure. Science 297, 990 (2002).CrossRefGoogle ScholarPubMed
Munitz, A.: Metastable liquid phase separation in tungsten inert gas and electron beam copper/stainless-steel welds. J. Mater. Sci. 30, 2901 (1995).CrossRefGoogle Scholar
Zeng, D.W., Xie, C.S., and Wang, M.Q.: In situ synthesis and characterization of Fep/Cu composite coating on SAE 1045 carbon steel by laser cladding. Mater. Sci. Eng., A 344, 357 (2003).CrossRefGoogle Scholar
Munitz, A., Venkert, A., Landau, P., Kaufman, M.J., and Abbaschian, R.: Microstructure and phase selection in supercooled copper alloys exhibiting metastable liquid miscibility gaps. J. Mater. Sci. 47, 7955 (2012).CrossRefGoogle Scholar
Shi, R.P., Wang, C.P., Wheeler, D., Liu, X.J., and Wang, Y.: Formation mechanisms of self-organized core/shell and core/shell/corona microstructures in liquid droplets of immiscible alloys. Acta Mater. 61, 1229 (2013).CrossRefGoogle Scholar
Liu, N.: Investigation on the phase separation in undercooled Cu–Fe melts. J. Non-Cryst. Solids 358, 196 (2012).CrossRefGoogle Scholar
Curiotto, S., Battezzati, L., Johnson, E., and Pryds, N.: Thermodynamics and mechanism of demixing in undercooled Cu–Co–Ni alloys. Acta Mater. 55, 6642 (2007).CrossRefGoogle Scholar
Zhou, X.B., and De Hosson, J.Th.M.: Dependence of surface residual stress on laser power and laser scan velocity. Scripta Met. Mater. 25, 2007 (1991).CrossRefGoogle Scholar
Kadolkar, P.B., Watkins, T.R., De Hosson, J.Th.M., Kooi, B.J., and Dahotre, N.B.: State of residual stress in laser-deposited ceramic composite coatings on aluminum alloys. Acta Mater. 55, 1203 (2007).CrossRefGoogle Scholar
Zhou, S., Huang, Y., Zeng, X., and Hu, Q.: Microstructure characteristics of Ni-based WC composite coatings by laser induction hybrid rapid cladding. Mater. Sci. Eng., A 480, 564 (2008).CrossRefGoogle Scholar
Zhou, S. and Zeng, X.: Growth characteristics and mechanism of carbides precipitated in WC–Fe composite coatings by laser induction hybrid rapid cladding. J. Alloys Compd. 505, 685 (2010).CrossRefGoogle Scholar
Pei, Y.T. and De Hosson, J.Th.M.: Functionally graded materials produced by laser cladding. Acta Mater. 48, 2617 (2000).CrossRefGoogle Scholar
Gilgien, P. and Kurz, W.: Laser Processing: Surface Treatment and Film Deposition, edited by, Mazunder, J., Conde, O., Vilar, R. and Steen, W.. (NATO ASI, Proc. 7, Sesimbra, Portugal, 1994); p. 3.Google Scholar
Hag, M. and Hügel, H.: CO2 laser light absorption characteristics of metal powders. J. Appl. Phys. 79, 3835 (1996).CrossRefGoogle Scholar
Chen, Q. and Jin, Z.P.: The Fe–Cu system: A thermodynamic evaluation. Metall. Mater. Trans. A 26, 417 (1995).CrossRefGoogle Scholar
Andrade, E.M.: Theory of viscosity of liquids. Philos. Mag. 17, 497 (1934).CrossRefGoogle Scholar
Liu, N., Liu, F., Cheng, Z., Yang, G., yang, C., and Zhou, Y.: Liquid-phase separation in rapid solidification of undercooled Fe–Co–Cu melts. J. Mater. Sci. Technol. 28, 622 (2012).Google Scholar
Choi, Y.S., Shin, D.H., and Kim, J.G.: Sacrificial anode cathodic protection of aluminum-coated steel for automotive mufflers. Corrosion 63, 522 (2007).CrossRefGoogle Scholar