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Influence of boron nitride on reinforcement to improve high temperature oxidation resistance of titanium

Published online by Cambridge University Press:  18 February 2019

Jose D. Avila  and
Amit Bandyopadhyay Open the ORCID record for Amit Bandyopadhyay [Opens in a new window]
Jose D. Avila
Affiliation:
W. M. Keck Biomedical Materials Research Lab, School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164, USA
Amit Bandyopadhyay*
Affiliation:
W. M. Keck Biomedical Materials Research Lab, School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164, USA
*
a)Address all correspondence to this author. e-mail: amitband@wsu.edu
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Abstract

Influence of boron nitride (BN) addition in commercially pure titanium (Cp-Ti) was characterized for their microstructural variation, hardness, and oxidation kinetics. Feedstock powders, Cp-Ti with 3 wt% BN (3BN) and 6 wt% BN (6BN), were prepared by roller mill followed by additive manufacturing using laser engineered net shaping (LENS™). Rate of oxidation was measured from thermogravimetric analysis (TGA) at 1000 °C for 50 h. Average instantaneous parabolic constants (kp) for Cp-Ti, 3BN, and 6BN were 41.2 ± 12.0, 28.6 ± 2.8, and 18.2 ± 9.2 mg2/(cm4 h), respectively. Cp-Ti displayed acicular α-Ti microstructure. After TGA, large equiaxed grains along with TiO2 formation at the grain boundaries were observed, which increased the hardness. With BN addition, plate-like TiN and needle-like TiB secondary phases were also observed. Hardness for Cp-Ti, 3BN, and 6BN were 256.9 ± 7.7, 424.0 ± 33.6, and 548.3 ± 49.7 HV0.2, respectively. Overall, a small addition of BN was effective in improving the oxidation resistance of Cp-Ti.

Keywords

laser engineered net shapingoxidationtitaniumboron nitridetitanium nitridetitanium boride
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 7: Focus Section: Interconnects and Interfaces in Energy Conversion Materials , 15 April 2019 , pp. 1279 - 1289
Copyright
Copyright © Materials Research Society 2019 

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Footnotes

b)

This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/editor-manuscripts/.

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