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Ion beam energy dependence of surface and structural properties of amorphous carbon films deposited by IBSD method on Ni–Cu alloy

Published online by Cambridge University Press:  14 February 2017

Elham Mohagheghpour ,
Marjan Rajabi ,
Reza Gholamipour ,
Majid M. Larijani  and
Shahab Sheibani
Elham Mohagheghpour
Affiliation:
Department of Advanced Materials and Renewable Energy, Iranian Research Organization for Science and Technology, Tehran 33535111, Iran
Marjan Rajabi*
Affiliation:
Department of Advanced Materials and Renewable Energy, Iranian Research Organization for Science and Technology, Tehran 33535111, Iran
Reza Gholamipour*
Affiliation:
Department of Advanced Materials and Renewable Energy, Iranian Research Organization for Science and Technology, Tehran 33535111, Iran
Majid M. Larijani
Affiliation:
Radiation Application Research School, Nuclear Sciences and Technology Institute, Tehran 14395836, Iran
Shahab Sheibani
Affiliation:
Radiation Application Research School, Nuclear Sciences and Technology Institute, Tehran 14395836, Iran
*
a)Address all correspondence to these authors. e-mail: mrajabi@irost.ir
b)e-mail: rgholamipour@gmail.com
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Abstract

The amorphous carbon thin films were deposited by the ion beam sputtering deposition technique on Ni–Cu alloy substrates. The effect of sputtering ion beam energy on wettabillity, surface, and structural properties of thin films was examined. The sputtering ion beam energy was varied over a wide range from 2 to 5 keV. Raman spectra showed that the values of ID/IG ratio and the ‘G’ peak position have a reduction trend by increasing the argon ion beam energy while the surface roughness increased due to the resputtering effect. The wettability and surface energy of a-C carbon films were studied by contact angle measurements in relation to structure and topography. The deposited films showed a relatively high water contact angle (CA) that decreases from 87° to 75°. The X-ray photoelectron spectroscopy showed that the value of sp3/sp2 bond content of a-C thin films deposited with the highest argon ion beam energy of 5 keV was about 0.8. Furthermore, the optical band gap followed similar trends of the structural properties.

Keywords

amorphous carbon (a-C)ion beam sputtering depositionion beam energysurface energywettability
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 7 , 14 April 2017 , pp. 1258 - 1266
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Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Jürgen Eckert

References

REFERENCES

Lilly, M.B., Brezovich, I.A., and Atkinson, W.J.: Hyperthermia induction with thermally self-regulated ferromagnetic implants. Radiology 154, 243 (1985).CrossRefGoogle ScholarPubMed
Robertson, J.: Diamond-like amorphous carbon. Mater. Sci. Eng., R 37, 129–281 (2002).Google Scholar
Robertson, J.: Comparison of diamond-like carbon to diamond for applications. Phys. Status Solidi A 205, 2233 (2008).CrossRefGoogle Scholar
Aisenberg, S. and Chabot, R.: Ion-beam deposition of thin films of diamond like carbon. J. Appl. Phys. 42, 2953–2958 (1971).Google Scholar
Tang, Y., Li, Y.S., Yang, Q., and Hirose, A.: Characterization of hydrogenated amorphous carbon thin films by end-Hall ion beam deposition. Appl. Surf. Sci. 257, 4699–4705 (2011).CrossRefGoogle Scholar
Bai, L., Zhang, G., Wu, Z., Wang, J., and Yan, P.: Effect of different ion beam energy on properties of amorphous carbon film fabricated by ion beam sputtering deposition (IBSD). Nucl. Instrum. Methods Phys. Res., Sect. B 269, 1871–1877 (2011).Google Scholar
Sodhi, R.N.S.: Application of surface analytical and modification techniques to biomaterial research. J. Electron. Spectrosc. 81, 269 (1996).Google Scholar
Yari, M., Larijani, M.M., Afshar, A., Eshghabadi, M., Shokouhy, A.: Physical properties of sputtered amorphous carbon coating. J. Alloys Compd. 513, 135–138 (2012).Google Scholar
Waseem, B., Alam, S., Irfan, M., Shahid, M., Soomro, B.D., Hashim, S., and Iqbal, R.: Optimization and characterization of adhesion properties of DLC coatings on different substrates. Mater. Sci. Eng. 60, 012054 (2014).Google Scholar
Larijani, M.M., Yari, M., Afshar, A., Jafarian, M., and Eshghabadi, M.: A comparison of carbon coated and uncoated 316L stainless steel for using as bipolar plates in PEMFCs. J. Alloys Compd. 509, 7400–7404 (2011).Google Scholar
Ahmad, I., Roy, S.S., Rahman, Md.A., Okpalugo, T.I.T., Maguire, P.D., and McLaughlin, J.A.: Substrate effects on the microstructure of hydrogenated amorphous carbon films. Curr. Appl. Phys. 9, 937–942 (2009).CrossRefGoogle Scholar
Khan, N.: Dosimetric calculation of a thermo brachytherapy seed: A Monte Carlo study. In Partial fulfillment of the requirements for the degree of Master of Science in Biomedical Sciences, 2008.Google Scholar
Gautam, B., Parsai, E.I., Shvydka, D., and Feldmeier, J.: Dosimetric and thermal properties of a newly developed thermobrachytherapy seed with ferromagnetic core for treatment of solid tumors. Med. Phys. 39, 1980–1990 (2012).Google Scholar
Parsai, E.I., Gautam, B., and Shvydka, D.: Evaluation of a novel thermobrachytherapy seed for concurrent administration of brachytherapy and magnetically mediated hyperthermia in treatment of solid tumors. J. Biomed. Phys. Eng. 1, 5–16 (2011).Google Scholar
Meigooni, A.S., Yoe-Sein, M.M., Al-Otoom, A.Y., and Sowards, K.T.: Determination of the dosimetric characteristics of InterSource125 Iodine brachytherapy source. Appl. Radiat. Isot. 56, 589–599 (2002).Google Scholar
Donnet, C. and Erdemir, A. eds.: Tribology of Diamond-Like Carbon Films: Fundamentals and Applications (Springer, Berlin, 2008); pp. 102–136.Google Scholar
Manova, D., Gerlach, J.W., and Mändl, S.: Thin film deposition using energetic ions. Materials 3, 4109–4141 (2010).Google Scholar
Pauleau, Y.: Generation and evolution of residual stresses in physical vapour-deposited thin films. Vacuum 61, 175–181 (2001).Google Scholar
Bai, L., Zhang, G., Wu, Z., Wang, J., and Yan, P.: Effect of different ion beam energy on properties of amorphous carbon film fabricated by ion beam sputtering deposition (IBSD). Nucl. Instrum. Methods Phys. Res., Sect. B 269, 1871–1877 (2011).CrossRefGoogle Scholar
Chiang, K.T., Yang, L., Wei, R., and Coulter, K.: Development of DLC-coated electrodes for corrosion sensor applications at high temperatures. Thin Solid Films 517, 1120–1124 (2008).CrossRefGoogle Scholar
Ensinger, W.: Low energy ion assist during deposition-an effective tool for controlling thin film microstructure. Nucl. Instrum. Methods Phys. Res., Sect. B 127–128, 796 (1997).CrossRefGoogle Scholar
Banerjee, D., Mukherjee, S., and Chattopadhyay, K.K.: Controlling the surface topology and hence the hydrophobicity of amorphous carbon thin films. Carbon 48, 1025–1031 (2010).Google Scholar
Mohagheghpour, E., Rajabi, M., Gholamipour, R., Larijani, M.M., and Sheibani, S.: Correlation study of structural, optical and electrical properties of amorphous carbon thin films prepared by ion beam sputtering deposition technique. Appl. Surf. Sci. 360, 52–58 (2016).Google Scholar
Paulmier, T., Bell, J.M., and Fredericks, P.M.: Deposition of nano-crystalline graphite films by cathodic plasma electrolysis. Thin Solid Films 515, 2926–2934 (2007).Google Scholar
Pauleau, Y.: Generation and evolution of residual stresses in physical vapour-deposited thin films. Vacuum 61, 175–181 (2001).Google Scholar
Merel, P., Tabbal, M., Chaker, M., Moisa, S., and Margot, J.: Direct evaluation of the sp 3 content in dmond-like-carbon films by XPS. Appl. Surf. Sci. 136, 105–110 (1998).Google Scholar
Vogler, E.A.: Structure and reactivity of water at biomaterial surfaces. Adv. Colloid Interface Sci. 74, 69–117 (1998).Google Scholar
Peng, X. and Chen, A.: Aligned TiO2 nanorod arrays synthesized by oxidizing titanium with acetone. J. Mater. Chem. 14, 2542–2548 (2004).Google Scholar
Zhou, Y., Wang, B., Song, X., Li, E., Li, G., Zhao, S., and Yan, H.: Control over the wettability of amorphous carbon films in a large range from hydrophilicity to super-hydrophobicity. Appl. Surf. Sci. 253, 2690–2694 (2006).CrossRefGoogle Scholar
Ferrari, A.C.: Determination of bonding in diamond-like carbon by Raman spectroscopy. Diamond Relat. Mater. 11, 1053–1061 (2002).CrossRefGoogle Scholar
Ruso, M., Soga, T., Jimbo, T., Umen, M., and Sharon, M.: Structural and electrical properties of diamond-like carbon thin films prepared in inert gas condition. Surf. Rev. lett. 12, 691 (2005).Google Scholar
Shin, J.K., Lee, C.S., Lee, K.R., and Eun, K.Y.: Effect of residual stress on the Raman-spectrum analysis of tetrahedral amorphouscarbon films. Appl. Phys. Lett. 78, 631 (2001).Google Scholar
Ferrari, A.C. and Robertson, J.: Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B: Condens. Matter Mater. Phys. 61, 14095–14107 (2000).Google Scholar
Adamopoulos, G., Robertson, J., Morrison, N.A., and Godet, C.: Hydrogen content estimation of hydrogenated amorphous carbon by visible Raman spectroscopy. J. Appl. Phys. 96, 6348 (2004).Google Scholar
Vasin, A.V., Matveeva, L.A., and Kutsa, A.M.: Analysis of the fundamental absorption edge in amorphous hydrogenated carbon films. Tech. Phys. Lett. 25, 1006 (1999).CrossRefGoogle Scholar
Piazza, F. and Morell, G.: Wettability of hydrogenated tetrahedral amorphous carbon. Diamond Relat. Mater. 18, 43–50 (2009).CrossRefGoogle Scholar
Ostrovskaya, L.Y.: Studies of diamond and diamond-like film surfaces using XAES, AFM and wetting. Vacuum 68, 219–238 (2002).Google Scholar
Yan, X.B., Xu, T., Yue, S., Liu, H., Xue, Q., and Yang, S.: Water-repellency and surface free energy of a-C:H films prepared by heat-treatment of polymer precursor. Diamond Relat. Mater. 14, 1342–1347 (2005).Google Scholar
ModabberAsl, A., Kameli, P., Ranjbar, M., Salamati, H., and Jannesari, M.: Correlations between microstructure and hydrophobicity properties of pulsed laser deposited diamond-like carbon films. Superlattices Microstruct. 81, 64–79 (2015).Google Scholar
Kaban, I., Nowak, R., Bruzda, G., Xi, L., Sobczak, N., Eckert, J., and Giebeler, L.: Wettability and work of adhesion of liquid sulfur on carbon materials for electrical energy storage applications. Carbon 98, 702–707 (2016).Google Scholar