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Kinetics of short- and long-range B2 ordering in ternary alloys

Published online by Cambridge University Press:  31 January 2011

B. Fultz
Affiliation:
California Institute of Technology, 138-78, Pasadena, California 91125
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Abstract

The kinetics of disorder → B2 order transformations in ternary alloys were studied in the pair approximation. The predictions of two sets of rate equations were compared, one based on an atom-atom interchange mechanism and the other based on an atom-vacancy interchange mechanism. Examples are presented to show how the evolution of order is affected by differences in interatomic potentials, differences in activation barrier heights, and effects of vacancy ordering. A wide variety of states of order are possible during the disorder → order transformation in ternary alloys, and qualitative features of the sequences of these states are discussed. The sequences of states, or “kinetic paths”, are much less intuitive than for binary alloys.

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Articles
Copyright
Copyright © Materials Research Society 1992

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References

1.Kikuchi, R. and Sato, H., J. Chem. Phys. 51, 161 (1969); ibid. 57, 4962 (1972).CrossRefGoogle Scholar
2.Sato, H. and Kikuchi, R., Acta Metall. 24, 797 (1976).CrossRefGoogle Scholar
3.Sato, H., Gschwend, K., and Kikuchi, R., J. Physique C7, 357 (1977).Google Scholar
4.Gschwend, K., Sato, H., and Kikuchi, R., J. Chem. Phys. 69, 5006 (1978).CrossRefGoogle Scholar
5.Fultz, B., Acta Metall. 37, 823 (1989); B. Fultz, H. Hamdeh, and D.H. Pearson, ibid. 37, 2841 (1989).CrossRefGoogle Scholar
6.Anthony, L. and Fultz, B., J. Mater. Res. 4, 1132 (1989); ibid. 4, 1140 (1989).CrossRefGoogle Scholar
7.Bakker, H., Philos. Mag. A 40, 525 (1979).Google Scholar
8.Stolwijk, N. A., Phys. Status Solidi (b) 105, 223 (1981).CrossRefGoogle Scholar
9.Fultz, B., J. Mater. Res. 5, 1419 (1990).CrossRefGoogle Scholar
10.Fultz, B., J. Less-Common Metals 168, 145 (1991).CrossRefGoogle Scholar
11.Fultz, B., Phys. Rev. B 44, 4805 (1991).CrossRefGoogle Scholar
12.de Fontaine, D., J. Phys. Chem. Solids 34, 1285 (1973).CrossRefGoogle Scholar
13.Murakami, M., de Fontaine, D., Sanchez, J. M., and J. Fodor, Acta Metall. 22, 709 (1974).CrossRefGoogle Scholar
14.Kikuchi, R., Mohri, T., and Fultz, B., “The Pseudostable Phase”, Proceedings of the Fall Meeting of the Mater. Res. Society, Boston, MA, 1990, in press.Google Scholar