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Kinetics of the reactive spreading of molten aluminum on ceramic surfaces

Published online by Cambridge University Press:  03 March 2011

Douglas A. Weirauch Jr. ,
Willy M. Balaba  and
Anthony J. Perrotta
Douglas A. Weirauch Jr.
Affiliation:
Alcoa Technical Center, 100 Technical Drive, Alcoa Center, Pennsylvania 156069-0001
Willy M. Balaba
Affiliation:
Alcoa Technical Center, 100 Technical Drive, Alcoa Center, Pennsylvania 156069-0001
Anthony J. Perrotta
Affiliation:
Alcoa Technical Center, 100 Technical Drive, Alcoa Center, Pennsylvania 156069-0001
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Abstract

The spreading kinetics of molten aluminum on ceramic surfaces bearing reactive coatings has been studied through the direct observation of sessile drops, either formed in situ or emplaced at temperature. Analysis of videotapes permitted the assessment of the rate of advance of rapidly spreading droplets. Experimental conditions in this study were chosen to avoid the severe retarding effect of the aluminum oxide film which is typically encountered in aluminum wetting experiments. A variety of reactive coating systems were examined (B, Cu, Ni, Ti, and Ti + B), and the effect of coating amount was assessed. Based upon the experiments of this study, the main effect of the coatings is to drive spreading due to strong exothermic interfacial reactions. The intensity of the interfacial reaction causes the change in free energy per unit area of interface to dominate the rate of movement of the triple line.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 3 , March 1995 , pp. 640 - 650
Copyright
Copyright © Materials Research Society 1995

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References

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