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Low temperature amorphization and superconductivity in FeSe single crystals at high pressures

Published online by Cambridge University Press:  31 January 2011

Andrew K. Stemshorn ,
Georgiy Tsoi ,
Yogesh K. Vohra ,
Stanislav Sinogeiken ,
Phillip M. Wu ,
Yilin Huang ,
Sistla M. Rao ,
Maw-Kuen Wu ,
Kuo W. Yeh  and
Samuel T. Weir
Yogesh K. Vohra*
Affiliation:
Department of Physics, University of Alabama at Birmingham, Birmingham, Alabama 35294
Stanislav Sinogeiken
Affiliation:
High Pressure Collaborative Access Team (HPCAT), Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439
Phillip M. Wu
Affiliation:
Department of Physics, Duke University, Durham, North Carolina 27708
Kuo W. Yeh
Affiliation:
Institute of Physics, Academia Sinica, Nankang, Taipei 115, Taiwan
Samuel T. Weir
Affiliation:
L-041, Lawrence Livermore National Laboratory, Livermore, California 94550
*
a)Address all correspondence to this author. e-mail: ykvohra@uab.edu
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Abstract

In this study, we report low temperature x-ray diffraction studies combined with electrical resistance measurements on single crystals of iron-based layered superconductor FeSe to a temperature of 10 K and a pressure of 44 GPa. The low temperature high pressure x-ray diffraction studies were performed using a synchrotron source and superconductivity at high pressure was studied using designer diamond anvils. At ambient temperature, the FeSe sample shows a phase transformation from a PbO-type tetragonal phase to a NiAs-type hexagonal phase at 10 ± 2 GPa. On cooling, a structural distortion from a PbO-type tetragonal phase to an orthorhombic Cmma phase is observed below 100 K. At a low temperature of 10 K, compression of the orthorhombic Cmma phase results in a gradual transformation to an amorphous phase above 15 GPa. The transformation to the amorphous phase is completed by 40 GPa at 10 K. A loss of superconductivity is observed in the amorphous phase and a dramatic change in the temperature behavior of electrical resistance indicates formation of a semiconducting state at high pressures and low temperatures. The formation of the amorphous phase is attributed to a kinetic hindrance to the growth of a hexagonal NiAs phase under high pressures and low temperatures.

Keywords

Phase transformationSuperconductingX-ray diffraction (XRD)
Type
Materials Communications
Information
Journal of Materials Research , Volume 25 , Issue 2 , February 2010 , pp. 396 - 400
Copyright
Copyright © Materials Research Society 2010

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