Hostname: page-component-cd9895bd7-gxg78 Total loading time: 0 Render date: 2024-12-28T00:46:49.414Z Has data issue: false hasContentIssue false
  • English
  • Français

Mechanochemical synthesis of ReB2 powder

Published online by Cambridge University Press:  26 August 2011

Nina Orlovskaya ,
Zhilin Xie ,
Mikhail Klimov ,
Helge Heinrich ,
David Restrepo ,
Richard Blair  and
Challapalli Suryanarayana
Nina Orlovskaya*
Affiliation:
Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, Florida 32816
Zhilin Xie
Affiliation:
Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, Florida 32816
Mikhail Klimov
Affiliation:
Materials Characterization Facility, University of Central Florida, Orlando, Florida 32826
Helge Heinrich
Affiliation:
Physics Department, University of Central Florida, Orlando, Florida 32816
David Restrepo
Affiliation:
Chemistry Department, University of Central Florida, Orlando, Florida 32816
Richard Blair
Affiliation:
Chemistry Department, University of Central Florida, Orlando, Florida 32816
Challapalli Suryanarayana
Affiliation:
Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, Florida 32816
*
a)Address all correspondence to this author. e-mail: norlovsk@mail.ucf.edu
Get access

Abstract

ReB2 was recently reported to exhibit high hardness and low compressibility, which both are strong functions of its stoichiometry, namely Re to B ratio. Most of the techniques used for ReB2 synthesis reported 1:2.5 Re to B ratio because of the loss of the B during high temperature synthesis. However, as a result of B excess, the amorphous boron, located along the grain boundaries of polycrystalline ReB2, would degrade the ReB2 properties. Therefore, techniques which could allow synthesizing the stoichiometric ReB2 preferably at room temperature are in high demand. Here, we report synthesis of ReB2 powders using mechanochemical route by milling elemental crystalline Re and amorphous B powders in the SPEX 8000 high-energy ball mill for 80 h. The formation of boron and perrhenic acids are also reported after ReB2 powder was exposed to the moist air environment for a 12-month period of time.

Keywords

CeramicReB
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 21 , 14 November 2011 , pp. 2772 - 2779
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Chung, H.Y., Weinberger, M.B., Levine, J.B., Cumberland, R.W., Kavner, A., Yang, J.M., Tolbert, S.H., and Kaner, R.B.: Synthesis of ultra-incompressible superhard rhenium diboride at ambient pressure. Science 316, 436 (2007).CrossRefGoogle ScholarPubMed
2.Latini, A., Rau, J.V., Ferro, D., Teghil, R., Albertini, V.R., and Barinov, S.M.: Superhard rhenium diboride films: Preparation and characterization. Chem. Mater. 20, 4507 (2008).CrossRefGoogle Scholar
3.Levine, J.B., Nguyen, S.L., Rasool, H.I., Wright, J.A., Brown, S.E., and Kaner, R.B.: Preparation and properties of metallic, superhard rhenium diboride crystals. J. Am. Chem. Soc. 130, 16953 (2008).CrossRefGoogle ScholarPubMed
4.Zhou, W., Wu, H., and Yildirim, T.: Electronic, dynamical, and thermal properties of ultra-incompressible superhard rhenium diboride: A combined first-principles and neutron scattering study. Phys. Rev. B 76, 184113 (2007).CrossRefGoogle Scholar
5.Aydin, S. and Simsek, M.: First-principles calculations of MnB2, TcB2, and ReB2 within the ReB2-type structure. Phys. Rev. B 80, 134107 (2009).CrossRefGoogle Scholar
6.Liang, Y. and Zhang, B.: Mechanical and electronic properties of superhard ReB2. Phys. Rev. B 76, 132101 (2007).CrossRefGoogle Scholar
7.Chen, X.Q., Fu, C.L., Krčmar, M., and Painter, G.S.: Electronic and structural origin of ultraincompressibility of 5d transition-metal diborides MB2 (M=W, Re, Os). Phys. Rev. Lett. 100, 196403 (2008).CrossRefGoogle ScholarPubMed
8.Pellicer-Porres, J., Segural, A., Munoz, A., Polian, A., and Congeduti, A.: Bond length compressibility in hard ReB2 investigated by x-ray absorption under high pressure. J. Phys. Condens. Matter 22, 045701 (2010).CrossRefGoogle ScholarPubMed
9.Koehler, M.R., Keppens, V., Sales, B.C., Jin, R., and Mandrus, D.: Elastic moduli of superhard rhenium diboride. J. Phys. D: Appl. Phys. 42, 095414 (2009).CrossRefGoogle Scholar
10.Zhang, R.F., Veprek, S., and Argon, A.S.: Mechanical and electronic properties of hard rhenium diboride of low elastic compressibility studied by first-principles calculation. Appl. Phys. Lett. 91, 201914 (2007).CrossRefGoogle Scholar
11.Dubrovinskaia, N., Dubrovinsky, L., and Solozhenko, V.L.: Comment on “Synthesis of ultra-incompressible superhard rhenium diboride at ambient pressure”. Science 318, 1550 (2007).CrossRefGoogle ScholarPubMed
12.Otani, S., Korsukova, M.M., and Aizawa, T.: High-temperature hardness of ReB2 single crystals. J. Alloy. Comp. 477, L28 (2009).CrossRefGoogle Scholar
13.Qin, J., He, D., Wang, J., Fang, L., Lei, L., Li, Y., Hu, J., Kou, Z., and Bi, Y.: Is rhenium diboride a superhard material? Adv. Mater. 20, 4780 (2008).CrossRefGoogle Scholar
14.Levine, J.B., Betts, J.B., Garrett, J.D., Guo, S.Q., Eng, J.T., Miglion, A., and Kaner, R.B.: Full elastic tensor of a crystal of the superhard compound ReB2. Acta Mater. 58, 1530 (2010).CrossRefGoogle Scholar
15.McAlister, A.J.: Binary Alloy Phase Diagrams, edited by Massalski, T.B., Okamoto, H., Subramanian, P.R. and Kacprzak, L. (ASM International, Materials Park, OH, 1990), p. 136.Google Scholar
16.Ivanov, B.L., Wellons, M.S., and Lukehart, C.M.: Confined-plume chemical deposition: Rapid synthesis of crystalline coatings of known hard or superhard materials on inorganic or organic supports by resonant IR decomposition of molecular precursors. J. Am. Chem. Soc. 131, 11744 (2009).CrossRefGoogle ScholarPubMed
17.Lyashchenko, A.B., Paderno, V.N., Filippov, V.B., and Borshchevskii, D.F.: Preparation and some properties of rhenium diboride monocrystals. Sverkhtverd. Mater. 28, 72 (2006).Google Scholar
18.LaPlaca, S.J. and Post, B.: The crystal structure of rhenium diboride. Acta Crystallogr. 15, 97 (1962).CrossRefGoogle Scholar
19.Frotscher, M., Holzel, M., and Albert, B.Z.: Crystal structures of the metal diborides ReB2, RuB2, and OsB2 from neutron powder diffraction. Z. Anorg. Allg. Chem. 636, 1783 (2010).CrossRefGoogle Scholar
20.Locci, A.M., Licheri, R., Orru, R., and Cao, G.: Reactive spark plasma sintering of rhenium diboride. Ceram. Int. 35, 397 (2009).CrossRefGoogle Scholar
21.Suryanarayana, C.: Mechanical alloying and milling. Prog. Mater. Sci. 46, 1 (2001).CrossRefGoogle Scholar
22.Suryanarayana, C.: Mechanical Alloying and Milling (Marcel Dekker, Inc., New York, NY, 2004), p. 466.CrossRefGoogle Scholar
23.Boldyrev, V.V. and Tkacova, K.: Mechanochemistry of solids: Past, present, and prospects. J. Mater. Synth. Process. 8, 121 (2000).CrossRefGoogle Scholar
24.Takacs, L.: Self-sustaining reactions induced by ball milling. Prog. Mater. Sci. 47, 355 (2002).CrossRefGoogle Scholar
25.Haessler, W., Herrmann, M., Birajdar, B., Rodig, C., Schubert, M., Holzapfel, B., Eibl, O., and Schultz, L.: Superconducting MgB2 tapes prepared using mechanically alloyed nanocrystalline precursor powder. IEEE Trans. Appl. Supercond. 17, 2919 (2007).CrossRefGoogle Scholar
26.Hwang, Y. and Lee, J.K.: Preparation of TiB2 powders by mechanical alloying. Mater. Lett. 54, 1 (2002).CrossRefGoogle Scholar
27.Millet, P. and Hwang, T.: Preparation of TiB2 and ZrB2: Influence of a mechanochemical treatment on the borothermic reduction of titania and zirconia. J. Mater. Sci. 31, 351 (1996).CrossRefGoogle Scholar
28.Radev, D.D. and Klisurski, D.: Properties of TiB2 powders obtained in a mechanochemical way. J. Alloy. Comp. 206, 39 (1994).CrossRefGoogle Scholar
29.Setoudeh, N. and Welham, N.J.: Formation of zirconium diboride (ZrB2) by room temperature mechanochemical reaction between ZrO2, B2O3 and Mg. J. Alloy. Comp. 420, 225 (2006).CrossRefGoogle Scholar
30.Varin, R.A. and Chiu, C.: Synthesis of nanocrystalline magnesium diboride (MgB2) metallic superconductor by mechano-chemical reaction and post-annealing. J. Alloy. Comp. 407, 268 (2006).CrossRefGoogle Scholar
31.Boyd, G.E., Cobble, J.W., and Smith, W.T.: Thermodynamic properties of technetium and rhenium compounds. III. Heats of formation of rhenium heptoxide and trioxide, and a revised potential diagram for rhenium. J. Am. Chem. Soc. 75, 5783 (1953).CrossRefGoogle Scholar
32.Meschel, S.V. and Kleppa, O.J.: Standard enthalpies of formation of NbB2, MoB, and ReB2 by high-temperature direct synthesis calorimetry. Metall. Mater. Trans. A 24, 947 (1993).CrossRefGoogle Scholar