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Microstructure and mechanical properties of electron beam weld joints of a Zr41Ti14Cu12Ni10Be23 bulk metallic glass with Zr

Published online by Cambridge University Press:  03 March 2011

R. Bhowmick
Affiliation:
Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India
S. Bysakh
Affiliation:
Defense Metallurgical Research Laboratory, Hyderabad 500058, India
Y. Kawamura
Affiliation:
Department of Materials Science and Engineering, Shock Wave and Condensed Matter Research Center, Kumamoto University, Kumamoto 860-8555, Japan
M. Yamasaki
Affiliation:
Department of Materials Science and Engineering, Shock Wave and Condensed Matter Research Center, Kumamoto University, Kumamoto 860-8555, Japan
U. Ramamurty
Affiliation:
Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India
K. Chattopadhyay*
Affiliation:
Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India
*
a) Address all correspondence to this author. e-mail: kamanio@materials.iisc.ernet.in
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Abstract

The electron beam welding technique was used to join Zr41Ti14Cu12Ni10Be23 bulk metallic glass (BMG) to crystalline pure Zr. Compositional, microstructural, and mechanical property variations across the welded interface were evaluated. It is shown that a crystalline layer develops close to the welding interface. Transmission electron microscopy of this layer indicates the crystalline phase to be tetragonal with lattice parameters close to that reported for Zr2Ni. However, the composition of this phase is different as it contains other alloying additions. The interface layer close to the bulk metallic glass side contains nanocrystalline Zr2Cu phase embedded in the glassy matrix. Nanoindentation experiments indicate that the hardness of the crystalline layer, although less than the bulk metallic glass, is more than the Zr itself. Commensurately, tensile tests indicate that the failure of the welded samples occurs at the Zr side rather than at the weld joint.

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Articles
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999).CrossRefGoogle Scholar
2Kawamura, Y., Kagao, S., and Ohno, Y.: Electron beam welding of Zr-based bulk metallic glass to crystalline Zr metal. Mater. Trans. 42, 2649 (2001).CrossRefGoogle Scholar
3Kawamura, Y. and Ohno, Y.: Spark welding of Zr55Al10Ni5Cu30 bulk metallic glasses. Scripta Mater. 45, 127 (2001).CrossRefGoogle Scholar
4Kawamura, Y. and Ohno, Y.: Metallurgical bonding of bulk metallic glasses. Mater. Trans., JIM 42, 717 (2001).CrossRefGoogle Scholar
5Jr, J. Swiston, Hufnagel, T.C., and Weihs, J.P.: Joining bulk metallic glass using reactive multilayer foils. Scripta Mater. 48, 1575 (2003).Google Scholar
6Murali, P. and Ramamurty, U.: Embrittlement of a bulk metallic glass due to sub-Tg annealing. Acta Mater. 53, 1467 (2005).CrossRefGoogle Scholar
7Ramamurty, U., Lee, I.M.L., Basu, J., and Li, Y.: Embrittlement of a bulk metallic glass due to low temperature annealing. Scripta Mater. 47, 107 (2002).CrossRefGoogle Scholar
8Nagendra, N., Ramamurty, U., Goh, T.T., and Li, Y.: Effect of crystallinity on the impact toughness of a La-based bulk metallic glass. Acta Mater. 48, 2603 (2000).CrossRefGoogle Scholar
9Basu, J., Nagendra, N., Li, Y., and Ramamurty, U.: Microstructure and mechanical properties of partially-crystallized La-based bulk metallic glass. Philos. Mag. 83, 1747 (2003).CrossRefGoogle Scholar
10Schuh, C.A. and Neih, T.G.: A survey of instrumented indentation studies on metallic glasses. J. Mater. Res. 19, 46 (2004).CrossRefGoogle Scholar
11Patnaik, M.N.M., Narasimhan, R., and Ramamurty, U.: Spherical indentation response of metallic glasses. Acta Mater. 52, 3335 (2004).CrossRefGoogle Scholar
12Ramamurty, U., Jana, S., Kawamura, Y., and Chattopadhyay, K.: Hardness and plastic deformation in a bulk metallic glass. Acta Mater. 53, 705 (2005).CrossRefGoogle Scholar
13Bhowmick, R., Raghavan, R., Chattopadhyay, K., and Ramamurty, U.: Plastic flow softening in a bulk metallic glass. Acta Mater. 54, 4221 (2006).CrossRefGoogle Scholar
14Oliver, W.C. and Pharr, G.M.: An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mater. Res. 7, 1564 (1992).CrossRefGoogle Scholar
15Trivedi, R. and Kurz, W.: Solidification microstructures: A conceptual approach. Acta Mater. 42, 15 (1994).CrossRefGoogle Scholar
16Kurz, W. and Fusher, D.J.: Dendrite growth at the limit of stability. Tip radius and spacing. Acta Metall. 29, 11 (1981).CrossRefGoogle Scholar
17Dey, G.K., Baburaj, E.G., and Banerjee, S.: Crystallization kinetics of Zr-33at.% Ni amorphous alloy. J. Mater. Sci. 21, 117 (1986).CrossRefGoogle Scholar
18Kim, Y.J., Busch, R., Johnson, W.L., Rulison, L., and Rhim, W.K.: Experimental determination of a time-temperature-transformation diagram of the undercooled Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 alloy using the containerless electrostatic levitation processing technique. Appl. Phys. Lett. 68, 1057 (1996).CrossRefGoogle Scholar
19Wang, W. H., Dong, C., and Shek, C. H.: Bulk metallic glasses. Mater. Sci. Eng., R 44, 45 (2004).CrossRefGoogle Scholar
20Pelletier, J.M. and Van Moortele, B. de: Phase separation and crystallization in the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 bulk metallic glass determined by physical measurements and electron microscopy. J. Non-Cryst. Solids 325, 133 (2003).CrossRefGoogle Scholar
21Schneider, S., Thiyagarajan, P., and Johnson, W. L.: Formation of nanocrystals based on decomposition in the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 alloy. Appl. Phys. Lett 68, 493 (1996).CrossRefGoogle Scholar
22Tang, X-P., Loffler, J.F., Johnson, W.L., and Wu, Y.: Devitrification of the Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 bulk metallic glass studied by XRD, SANS, and NMR. J. Non-Cryst. Solids 317, 118 (2003).CrossRefGoogle Scholar