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Microstructures and mechanical properties of as-ECAPed Mg–8Sn alloys with the combined addition of Zn and Al

Published online by Cambridge University Press:  18 April 2017

Wei-li Cheng*
Affiliation:
School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China; Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China; and Shanxi Key Laboratory of Advanced Magnesium-Based Materials, Taiyuan University of Technology, Taiyuan 030024, China
Liang Tian
Affiliation:
School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Yang Bai
Affiliation:
School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Shi-chao Ma
Affiliation:
School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China
Hong-xia Wang
Affiliation:
School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China; and Key Laboratory of Interface Science and Engineering in Advanced Materials, Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, China
*
a) Address all correspondence to this author. e-mail: chengweili7@126.com
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Abstract

A “RE-free” and I-phase-containing Mg–8Sn-based alloy system was developed and successfully fabricated through the equal channel angular pressing (ECAP) process. The influence of the Zn/Al mass ratio on the microstructures and mechanical properties of the as-ECAPed Mg–8Sn–(5,6,7)Zn–2(wt%)Al alloys was investigated using an optical microscope, an X-ray diffractometer, a scanning electron microscope, a transmission electron microscope, and a universal testing machine. Grain size, dynamic recrystallization behavior, and texture were found to be greatly affected by the Zn/Al mass ratio. Furthermore, the ultimate tensile strength (250 MPa) and elongation (14.5%) of the alloy with a Zn/Al mass ratio of 3 were considerably increased compared to those of the as-ECAPed alloys with Zn/Al ratios of 2.5 and 3.5 (ultimate tensile strength and elongation of 215 MPa and 13% and 184 MPa and 10%, respectively). This significant enhancement was attributed to extensive grain boundary strengthening, precipitation strengthening, and higher work hardening capacity as well as texture randomization. The strength and ductility of the as-ECAPed alloys are also discussed in terms of the I-phase and Mg2Sn formation.

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Articles
Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Jörg F. Löffler

References

REFERENCES

Ha, H.Y., Kim, H.J., Baek, S.M., Kim, B., Sohn, S.D., Shin, H.J., Jeong, H.Y., Park, S.H., Yim, C.D., You, B.S., Lee, J.G., and Park, S.S.: Improved corrosion resistance of extruded Mg–8Sn–1Zn–1Al alloy by microalloying with Mn. Scr. Mater. 109, 3843 (2015).Google Scholar
Sasaki, T.T., Ju, J.D., Hono, K., and Shin, K.S.: Heat-treatable Mg–Sn–Zn wrought alloy. Scr. Mater. 61, 8083 (2009).CrossRefGoogle Scholar
Pan, H.C., Qin, G.W., Xu, M., Fu, H., Ren, Y.P., Pan, F.S., Gao, Z.Y., Zhao, C.Y., Yang, Q.S., She, J., and Song, B.: Enhancing mechanical properties of Mg–Sn alloys by combining addition of Ca and Zn. Mater. Des. 83, 736744 (2015).CrossRefGoogle Scholar
Cheng, W.L., Park, S.S., You, B.S., and Koo, B.H.: Microstructure and mechanical properties of binary Mg–Sn alloys subjected to indirect extrusion. Mater. Sci. Eng., A 527, 46504653 (2010).Google Scholar
Roostaei, M., Parsa, M.H., Mahmudi, R., and Mirzadeh, H.: Hot compression behavior of GZ31 magnesium alloy. J. Alloys Compd. 631, 16 (2015).Google Scholar
Mirzadeh, H., Roostaei, M., Parsa, M.H., and Mahmudi, R.: Rate controlling mechanisms during hot deformation of Mg–3Gd–1Zn magnesium alloy: Dislocation glide and climb, dynamic recrystallization, and mechanical twinning. Mater. Des. 68, 228231 (2015).Google Scholar
Zhang, W.Q., Xiao, W.L., Wang, F., and Ma, C.L.: Development of heat resistant Mg–Zn–Al-based magnesium alloys by addition of La and Ca: Microstructure and tensile properties. J. Alloys Compd. 684, 814 (2016).CrossRefGoogle Scholar
Suzuki, M., Kimura, T., Koike, J., and Maruyama, K.: Strengthening effect of Zn in heat resistant Mg–Y–Zn solid solution alloys. Scr. Mater. 48, 9971002 (2003).CrossRefGoogle Scholar
Zhao, C.Y., Pan, F.S., Zhao, S., Pan, H.C., Song, K., and Tang, A.T.: Microstructure, corrosion behavior and cytotoxicity of biodegradable Mg–Sn implant alloys prepared by sub-rapid solidification. Mater. Sci. Eng., C 54, 245251 (2015).Google Scholar
Cheng, W.L., Kim, H.S., You, B.S., Koo, B.H., and Park, S.S.: Strength and ductility of novel Mg–8Sn–1Al–1Zn alloys extruded at different speeds. Mater. Lett. 65, 15251527 (2011).Google Scholar
Park, S.H., Lee, J.H., Yu, H., Yoon, J.H., and You, B.S.: Effect of cold pre-forging on the microstructure and mechanical properties of extruded Mg–8Sn–1Al–1Zn alloy. Mater. Sci. Eng., A 612, 197201 (2014).CrossRefGoogle Scholar
Kim, Y.K., Sohn, S.W., Kim, D.H., Kim, W.T., and Kim, D.H.: Role of icosahedral phase in enhancing the strength of Mg–Sn–Zn–Al alloy. J. Alloys Compd. 549, 4650 (2013).Google Scholar
Mostaed, E., Fabrizi, A., Dellasega, D., Bonollo, F., and Vedani, M.: Microstructure, mechanical behavior and low temperature superplasticity of ECAP processed ZM21 Mg alloy. J. Alloys Compd. 638, 267276 (2015).CrossRefGoogle Scholar
Wang, H.X., Zhou, K.K., Xie, G.Y., Liang, X.Z., Liang, W., and Zhao, Y.T.: Microstructure and mechanical properties of an Mg–10Al alloy fabricated by Sb-alloying and ECAP processing. Mater. Sci. Eng., A 560, 787791 (2013).Google Scholar
Akbaripanah, F., Fereshteh, S.F., Mahmudi, R., and Kim, H.K.: Microstructural homogeneity, texture, tensile and shear behavior of AM60 magnesium alloy produced by extrusion and equal channel angular pressing. Mater. Des. 43, 3139 (2013).Google Scholar
Kim, K. and Yoon, J.: Effects of starting microstructure and billet orientations on the texture evolution and the mechanical behavior of Mg–3Al–1Zn rolled plate by half channel angular extrusion (HACE). Mater. Sci. Eng., A 622, 4651 (2015).Google Scholar
Wang, Y. and Choo, H.: Influence of texture on Hall–Petch relationships in an Mg alloy. Acta Mater. 81, 8397 (2014).Google Scholar
Yuan, W., Panigrahi, S.K., Su, J.Q., and Mishra, R.S.: Influence of grain size and texture on Hall–Petch relationship for a magnesium alloy. Scr. Mater. 65, 994997 (2011).Google Scholar
Xin, R.L., Zheng, X., Liu, Z., Liu, D.J., Qiu, R.S., Li, Z.Y., and Liu, Q.: Microstructure and texture evolution of an Mg–Gd–Y–Nd–Zr alloy during friction stir processing. J. Alloys Compd. 659, 5159 (2016).CrossRefGoogle Scholar
Chao, C., Chen, J.H., Yan, H.G., Su, B., Song, M., and Zhu, S.Q.: Dynamic precipitation, microstructure and mechanical properties of Mg–5Zn–1Mn alloy sheets prepared by high strain-rate rolling. Mater. Des. 100, 5866 (2016).Google Scholar
Hantzsche, K., Bohlen, J., Wendt, J., Kainer, K.U., Yi, S.B., and Letzig, D.: Effect of rare earth additions on microstructure and texture development of magnesium alloy sheets. Scr. Mater. 63, 725730 (2010).Google Scholar
Biyiklia, E., Tokera, S.M., and Canadinca, D.: Incorporating the grain boundary misorientation effects on slip activity into crystal plasticity. Mech. Adv. Mater. Struct. 23, 865872 (2016).Google Scholar
Patrik, D., Frantisek, C., Yi, S.B., Kseniya, P., Dietmar, L., and Jan, B.: Grain size effects on deformation twinning in an extruded magnesium alloy tested in compression. Scr. Mater. 65, 424427 (2011).Google Scholar
Park, S.S., Kim, Y.J., Cheng, W.L., Kim, Y.M., and You, B.S.: Tensile properties of extruded Mg–8Sn–1Zn alloys subjected to different heat treatments. Philos. Mag. Lett. 91, 3744 (2011).Google Scholar
Jung, J.G., Park, S.H., Yu, H., Kim, Y.M., Lee, Y.K., and You, B.S.: Improved mechanical properties of Mg–7.6Al–0.4Zn alloy through aging prior to extrusion. Scr. Mater. 93, 811 (2014).Google Scholar
Tang, W.N., Park, S.S., and You, B.S.: Effect of the Zn content on the microstructure and mechanical properties of indirect-extruded Mg–5Sn–xZn alloys. Mater. Des. 32, 35373543 (2011).CrossRefGoogle Scholar
Takeuchi, T., Murasaki, S., Matsumuro, A., and Mizutani, U.: Formation of quasicrystals and approximant crystals by mechanical alloying in Mg–Al–Zn alloy system. J. Non-Cryst. Solids 156–158, 914917 (1993).Google Scholar
Takeuchi, T. and Mizutani, U.: Electronic structure, electron transport properties, and relative stability of icosahedral quasicrystals and their 1/1 and 2/1 approximants in the Al–Mg–Zn alloy system. Phys. Rev. B: Condens. Matter Mater. Phys. 52, 93009309 (1995).Google Scholar
Liu, C.Q., Chen, H.W., and Nie, J.F.: Interphase boundary segregation of Zn in Mg–Sn–Zn alloys. Scr. Mater. 123, 58 (2016).CrossRefGoogle Scholar
Shang, S.J., Deng, K.K., Nie, K.B., Li, J.C., Zhou, S.S., Xu, F.J., and Fan, J.F.: Microstructure and mechanical properties of SiCp/Mg–Al–Zn composites containing Mg17Al12 phases processed by low-speed extrusion. Mater. Sci. Eng., A 610, 243249 (2014).CrossRefGoogle Scholar
Zhang, L., Deng, K.K., Nie, K.B., Xu, F.J., Su, K., and Liang, W.: Microstructures and mechanical properties of Mg–Al–Ca alloys affected by Ca/Al ratio. Mater. Sci. Eng., A 636, 279288 (2015).CrossRefGoogle Scholar
Liu, P., Jiang, H.T., Cai, Z.X., Kang, Q., and Zhang, Y.: The effect of Y, Ce and Gd on texture, recrystallization and mechanical property of Mg–Zn alloys. JMA 4, 188196 (2016).Google Scholar
Ding, H.L., Zhang, P., Cheng, G.P., and Kamado, S.H.: Effect of calcium addition on microstructure and texture modification of Mg rolled sheets. Trans. Nonferrous Met. Soc. 25, 28752883 (2015).Google Scholar
Zhang, W.Q., Xiao, W.L., Wang, F., and Ma, C.L.: Development of heat resistant Mg–Zn–Al-based magnesium alloys by addition of La and Ca: Microstructure and tensile properties. J. Alloys Compd. 684, 814 (2016).Google Scholar
Bohlen, J., Nurnberg, M.R., Senn, J., Letzig, D., and Agnew, S.R.: The texture and anisotropy of magnesium-zinc-rare earth alloy sheets. Acta Mater. 55, 21012112 (2007).Google Scholar
Zheng, X.B., Du, W.B., Liu, K., Wang, Z.H., and Li, S.B.: Effect of trace addition of al on microstructure, texture and tensile ductility of Mg–6Zn–0.5Er alloy. JMA 4, 135139 (2016).Google Scholar
Zhang, X.M., Tang, C.P., Deng, Y.L., and Yang, L.: Effects of thermal treatment on precipitate shape and mechanical properties of Mg–8Gd–4Y–Nd–Zr alloy. Mater. Des. 32, 49944998 (2011).Google Scholar
Pourbahari, B., Mirzadeh, H., and Emamy, M.: Toward unraveling the effects of intermetallic compounds on the microstructure and mechanical properties of Mg–Gd–Al–Zn magnesium alloys in the as-cast, homogenized, and extruded conditions. Mater. Sci. Eng., A 680, 3946 (2017).Google Scholar
Sun, Y., Zhang, B., Wang, Y., Geng, L., and Jiao, X.: Preparation and characterization of a new biomedical Mg–Zn–Ca alloy. Mater. Des. 34, 5864 (2012).Google Scholar
Zhang, B.P., Geng, L., Huang, L.J., Zhang, X.X., and Dong, C.C.: Enhanced mechanical properties in fine-grained Mg–1.0Zn–0.5Ca alloys prepared by extrusion at different temperatures. Scr. Mater. 63, 10241027 (2010).Google Scholar
Haasen, P.: Physical Metallurgy, 3rd ed. (Cambridge University Press, Cambridge, 1996).Google Scholar
Cheng, W.L., Tian, Q.W., Yu, H., Zhang, H., and You, B.S.: Strengthening mechanisms of indirect-extruded Mg–Sn based alloys at room temperature. JMA 2, 299304 (2014).Google Scholar
Gladman, T.: Precipitation hardening in metals. Mater. Sci. Technol. 15, 3036 (1998).Google Scholar
Wang, J.L., Guo, Y.C., Li, J.P., Zhong, Y., Shigeharu, K., and Wang, L.M.: Microstructure, texture and mechanical properties of extruded Mg–5Al–2Nd–0.2Mn alloy. J. Alloys Compd. 635, 100107 (2015).Google Scholar
Bettles, C.J. and Gibson, M.A.: Current wrought magnesium alloys: Strengths and weaknesses. JOM 57, 4649 (2005).Google Scholar
Yang, Q., Jiang, B., He, J., Song, B., Liu, W., Dong, H., and Pan, F.: Tailoring texture and refining grain of magnesium alloy by differential speed extrusion process. Mater. Sci. Eng., A 612, 187191 (2014).Google Scholar