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MOF derived porous Co@C hexagonal-shaped prisms with high catalytic performance

Published online by Cambridge University Press:  09 September 2016

Hui Li ,
Le Chi ,
Chao Yang ,
Liugen Zhang ,
Fan Yue  and
Jide Wang
Hui Li
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Le Chi
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Chao Yang
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Liugen Zhang
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Fan Yue
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
Jide Wang*
Affiliation:
Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, College of Chemistry and Chemical Engineering of Xinjiang University, Urumqi 830046, China
*
a) Address all correspondence to this author. e-mail: awangjd@sina.cn
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Abstract

There has been a continuous call for active, durable, and low-cost catalysts for a range of catalysis reactions. In this paper, porous Co@C composed of uniformly dispersed Co metal nanoparticles in hexagonal-shaped prisms carbon matrix were fabricated by in situ pyrolysis of hexagonal-shaped prismatic Co-MOF-74 crystals. The obtained nanoporous carbons have a high surface area of 195.2 m2/g and a strong magnetic response, thereby realizing fast molecular diffusion of reactant and easy magnetic separation. The resulting Co@C catalyst show a superior and durable catalytic activity for reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). Moreover, Co@C can be recycled and still retains more than 75% of its original catalytic activity after 6 cycles. Therefore, it is reasonable to believe that such Co@C nanocomposites have great potential as a highly efficient and low-cost heterogeneous catalyst. It is believed that MOFs can be used to produce other catalysts with high porosity and uniformly dispersed active sites.

Keywords

carbonizationcatalyticCo
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 19 , 14 October 2016 , pp. 3069 - 3077
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Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Bai, C., Yao, X., and Li, Y.: Easy access to amides through aldehydic C–H bond functionalization catalyzed by heterogeneous Co-based catalysts. ACS Catal. 5(2), 884–891 (2015).Google Scholar
Kim, M., Nam, D.H., Park, H.Y., Kwon, C., Eom, K., Yoo, S., Jang, J., Kim, H.J., Cho, E., and Kwon, H.: Cobalt–carbon nanofibers as an efficient support-free catalyst for oxygen reduction reaction with a systematic study of active site formation. J. Mater. Chem. A 3(27), 14284–14290 (2015).CrossRefGoogle Scholar
Wang, J., Gao, D., Wang, G., Miao, S., Wu, H., Li, J., and Bao, X.: Cobalt nanoparticles encapsulated in nitrogen-doped carbon as a bifunctional catalyst for water electrolysis. J. Mater. Chem. A 2(47), 20067–20074 (2014).CrossRefGoogle Scholar
Zhong, W., Liu, H., Bai, C., Liao, S., and Li, Y.: Base-free oxidation of alcohols to esters at room temperature and atmospheric conditions using nanoscale Co-based catalysts. ACS Catal. 5(3), 1850–1856 (2015).Google Scholar
Ania, C.O., Seredych, M., Rodriguez-Castellon, E., and Bandosz, T.J.: New copper/GO based material as an efficient oxygen reduction catalyst in an alkaline medium: The role of unique Cu/rGO architecture. Appl. Catal., B 163, 424–435 (2015).CrossRefGoogle Scholar
Rai, R.K., Mahata, A., Mukhopadhyay, S., Gupta, S., Li, P.Z., Nguyen, K.T., Zhao, Y., Pathak, B., and Singh, S.K.: Room temperature chemoselective reduction of nitro groups using non-noble metal nanocatalysts in water. Inorg. Chem. 53, 2904–2909 (2014).CrossRefGoogle ScholarPubMed
Lin, F.H. and Doong, R.A.: Bifunctional Au–Fe3O4 heterostructures for magnetically recyclable catalysis of nitrophenol reduction. J. Phys. Chem. C 115(14), 6591–6598 (2011).Google Scholar
Jiang, Z., Jiang, D., Showkot Hossain, A.M., Qian, K., and Xie, J.: In situ synthesis of silver supported nanoporous iron oxide microbox hybrids from metal–organic frameworks and their catalytic application in p-nitrophenol reduction. Phys. Chem. Chem. Phys. 17(4), 2550–2559 (2015).Google Scholar
Shi, Z.Q., Jiao, L.X., Sun, J., Chen, Z.B., Chen, Y.Z., Zhu, X.H., Zhou, J.H., Zhou, X.C., Li, X.Z., and Li, R.: Cobalt nanoparticles in hollow mesoporous spheres as a highly efficient and rapid magnetically separable catalyst for selective epoxidation of styrene with molecular oxygen. RSC Adv. 4(1), 47–53 (2014).Google Scholar
Yan, N., Zhao, Z., Li, Y., Wang, F., Zhong, H., and Chen, Q.: Synthesis of novel two phase Co@SiO2 nanorattles with high catalytic activity. Inorg. Chem. 53, 9073–9079 (2014).Google Scholar
Sun, J.K., Zhan, W.W., Akita, T., and Xu, Q.: Toward homogenization of heterogeneous metal nanoparticle catalysts with enhanced catalytic performance: Soluble porous organic cage as a stabilizer and homogenizer. J. Am. Chem. Soc. 137, 7063–7066 (2015).Google Scholar
Zhu, Y., Li, X., He, G., and Qi, X.: Magnetic C–C@Fe3O4 double-shelled hollow microspheres via aerosol-based Fe3O4@C–SiO2 core–shell particles. Chem. Commun. 51(14), 2991–2994 (2015).Google Scholar
Li, M., Li, X., Qi, X., Luo, F., and He, G.: Shape controlled synthesis of magnetic iron oxide@SiO2–Au@C particles with core–shell nanostructures. Langmuir 31(18), 5190–5197 (2015).Google Scholar
Zhou, S., Bai, S., Cheng, E., Qiao, R., Xie, Y., and Li, Z.: Facile embedding of Au nanocrystals into silica spheres with controllable quantity for improved catalytic reduction of p-nitrophenol. Inorg. Chem. Front. 2(10), 938–944 (2015).Google Scholar
Zhang, W., Lu, G., Cui, C., Liu, Y., Li, S., Yan, W., Xing, C., Chi, Y.R., Yang, Y., and Huo, F.: A family of metal-organic frameworks exhibiting size selective catalysis with encapsulated noble-metal nanoparticles. Adv. Mater. 26, 4056–4060 (2014).CrossRefGoogle ScholarPubMed
Jiang, H.L., Akita, T., Ishida, T., Haruta, M., and Xu, Q.: Synergistic catalysis of Au@Ag core–shell nanoparticles stabilized on metal–organic framework. J. Am. Chem. Soc. 133(5), 1304–1306 (2011).CrossRefGoogle ScholarPubMed
Nam, J.O., Kim, J., Jin, S.H., Chung, Y.M., and Lee, C.S.: Microfluidic preparation of a highly active and stable catalyst by high performance of encapsulation of polyvinylpyrrolidone (PVP)-Pt nanoparticles in microcapsules. J. Colloid Interface Sci. 464, 246–253 (2016).CrossRefGoogle ScholarPubMed
Gong, W., Su, L., and Zhang, X.: Preparation of catalytic films of the Au nanoparticle-carbon composite tubular arrays. Chem. Commun. 51(29), 6333–6336 (2015).Google Scholar
Chen, Y.Z., Wang, C., Wu, Z.Y., Xiong, Y., Xu, Q., Yu, S.H., and Jiang, H.L.: From bimetallic metal–organic framework to porous carbon: High surface area and multicomponent active dopants for excellent electrocatalysis. Adv. Mater. 27, 5010–5016 (2015).CrossRefGoogle ScholarPubMed
Zheng, F., Yang, Y., and Chen, Q.: High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal–organic framework. Nat. Commun. 5, 1–10 (2014).Google Scholar
Torad, N.L., Hu, M., Kamachi, Y., Takai, K., Imura, M., Naito, M., and Yamauchi, Y.: Facile synthesis of nanoporous carbons with controlled particle sizes by direct carbonization of monodispersed ZIF-8 crystals. Chem. Commun. 49(25), 2521–2523 (2013).Google Scholar
Li, H., Yue, F., Yang, C., Qiu, P., Xue, P., Xu, Q., and Wang, J.D.: Porous nanotubes derived from a metal-organic framework as high-performance supercapacitor electrodes. Ceram. Interfaces 42(2), 3121–3129 (2016).CrossRefGoogle Scholar
Zhang, Y.Z., Wang, Y., Xie, Y.L., Cheng, T., Lai, W.Y., Pang, H., and Huang, W.: Porous hollow Co3O4 with rhombic dodecahedral structures for high-performance supercapacitors. Nanoscale 6(23), 14354–14359 (2014).Google Scholar
Pang, H., Deng, J., Du, J., Li, S., Li, J., Ma, Y., Zhang, J., and Chen, J.: Porous nanocubic Mn3O4–Co3O4 composites and their application as electrochemical supercapacitors. Dalton Trans. 41(34), 10175–10181 (2012).CrossRefGoogle ScholarPubMed
Xi, J., Xia, Y., Xu, Y., Xiao, J., and Wang, S.: (Fe,Co)@nitrogen-doped graphitic carbon nanocubes derived from polydopamine encapsulated metal–organic frameworks as a highly stable and selective non-precious oxygen reduction electrocatalyst. Chem. Commun. 51(52), 10479–10482 (2015).CrossRefGoogle ScholarPubMed
Yang, J., Zhang, F., Lu, H., Hong, X., Jiang, H., Wu, Y., and Li, Y.: Hollow Zn/Co ZIF particles derived from core–shell ZIF-67@ZIF-8 as selective catalyst for the semi-hydrogenation of acetylene. Angew. Chem., Int. Ed. 54, 10889–10893 (2015).CrossRefGoogle ScholarPubMed
Wu, R., Wang, D.P., Rui, X., Liu, B., Zhou, K., Law, A.W.K., Yan, Q., Wei, J., and Chen, Z.: In situ formation of hollow hybrids composed of cobalt sulfides embedded within porous carbon polyhedra/carbon nanotubes for high-performance lithium-ion batteries. Adv. Mater. 27(19), 3038–3044 (2015).CrossRefGoogle ScholarPubMed
Wang, Q., Zou, R., Xia, W., Ma, J., Qiu, B., Mahmood, A., Zhao, R., Yang, Y., Xia, D., and Xu, Q.: Facile synthesis of ultrasmall CoS2 nanoparticles within thin N-doped porous carbon shell for high performance lithium-ion batteries. Small 11(21), 2511–2517 (2015).CrossRefGoogle ScholarPubMed
Yu, X.Y., Yu, L., Wu, H.B., and Lou, X.W.: Formation of nickel sulfide nanoframes from metal–organic frameworks with enhanced pseudocapacitive and electrocatalytic properties. Angew. Chem., Int. Ed. 54, 1–6 (2015).Google Scholar
Nie, P., Shen, L., Luo, H., Ding, B., Xu, G., Wang, J., and Zhang, X.G.: Prussian blue analogues: A new class of anode materials for lithium ion batteries. J. Mater. Chem. A 2(16), 5852–5857 (2014).Google Scholar
Liu, Y., Liu, S., He, D., Li, N., Ji, Y., Zheng, Z., Luo, F., Liu, S., Shi, Z., and Hu, C.: Crystal facets make a profound difference in polyoxometalate containing metal–organic frameworks as catalysts for biodiesel production. J. Am. Chem. Soc. 137(39), 12697–12703 (2015).Google Scholar
Zhang, S., Liu, H., Liu, P., Yang, Z., Feng, X., Huo, F., and Lu, X.: A template free method for stable CuO hollow microspheres fabricated from a metal organic framework (HKUST-1). Nanoscale 7(21), 9411–9415 (2015).CrossRefGoogle ScholarPubMed
Torad, N.L., Hu, M., Ishihara, S., Sukegawa, H., Belik, A.A., Imura, M., Ariga, K., Sakka, Y., and Yamauchi, Y.: Direct synthesis of MOF derived nanoporous carbon with magnetic Co nanoparticles toward efficient water treatment. Small 10(10), 2096–2107 (2014).Google Scholar
Lü, Y., Wang, Y., Li, H., Lin, Y., Jiang, Z., Xie, Z., Kuang, Q., and Zheng, L.: MOF derived porous Co/C nanocomposites with excellent electromagnetic wave absorption properties. ACS Appl. Mater. Interfaces 7(24), 13604–13611 (2015).Google Scholar
Xiao, Y.H., Liu, S., Li, F., Zhang, A., Zhao, J., Fang, S., and Jia, D.Z.: 3D hierarchical Co3O4 twin-spheres with an urchin like structure: Large-scale synthesis, multistep-splitting growth, and electrochemical pseudocapacitors. Adv. Funct. Mater. 22, 4052–4059 (2012).Google Scholar
Peng, S.J., Li, L.L., Tan, H.T., Cai, R., Shi, W.H., Li, C.C., Mhaisalkar, S.G., Srinivasan, M., Ramakrishna, S., and Yan, Q.Y.: MS2 (M = Co and Ni) hollow spheres with tunable interiors for high-performance supercapacitors and photovoltaics. Adv. Funct. Mater. 24, 2155–2162 (2014).Google Scholar
Yi, H.B., Wen, F.S., Qiao, L., and Li, F.S.: Microwave electromagnetic properties of multiwalled carbon nanotubes filled with Co nanoparticles. J. Appl. Phys. 106, 103922–103926 (2009).CrossRefGoogle Scholar
Shi, X., Zheng, F., Yan, N., and Chen, Q.: CoMn2O4 hierarchical microspheres with high catalytic activity towards p-nitrophenol reduction. Dalton Trans. 43(37), 13865–13873 (2014).Google Scholar
Aditya, T., Pal, A., and Pal, T.: Nitroarene reduction: A trusted model reaction to test nanoparticle catalysts. Chem. Commun. 51(46), 9410–9431 (2015).Google Scholar
Ma, Y., Ni, Y., Guo, F., and Xiang, N.: Flowerlike copper(II)-based coordination polymers particles: Rapid room-temperature fabrication, influencing factors, and transformation toward CuO microstructures with good catalytic activity for the reduction of 4-nitrophenol. Cryst. Growth Des. 15(5), 2243–2252 (2015).Google Scholar
Wu, Y.G., Wen, M., Wu, Q.S., and Fang, H.: Ni/graphene nanostructure and its electron-enhanced catalytic action for hydrogenation reaction of nitrophenol. J. Phys. Chem. C 118(12), 6307–6313 (2014).Google Scholar
Jiang, Z., Xie, J., Jiang, D., Jing, J., and Qin, H.: Facile route fabrication of nano-Ni core mesoporous silica shell particles with high catalytic activity towards 4-nitrophenol reduction. CrystEngComm 14(14), 4601–4611 (2012).Google Scholar
Mandlimath, T.R. and Gopal, B.: Catalytic activity of first row transition metal oxides in the conversion of p-nitrophenol to p-aminophenol. J. Mol. Catal. A: Chem. 350(1–2), 9–15 (2011).Google Scholar
Hu, L., Zhang, R., Wei, L., Zhang, F., and Chen, Q.: Synthesis of FeCo nanocrystals encapsulated in nitrogen-doped graphene layers for use as highly efficient catalysts for reduction reactions. Nanoscale 7(2), 450–454 (2015).CrossRefGoogle ScholarPubMed
Bhattacharjee, A. and Ahmaruzzaman, M.: A green approach for the synthesis of SnO2 nanoparticles and its application in the reduction of p-nitrophenol. Mater. Lett. 157, 260–264 (2015).Google Scholar
Wang, Z., Xu, C., Gao, G., and Li, X.: Facile synthesis of well-dispersed Pd-graphene nanohybrids and their catalytic properties in 4-nitrophenol reduction. RSC Adv. 4(26), 13644–13651 (2014).Google Scholar
Deng, Y.H., Cai, Y., Sun, Z., Liu, J., Liu, C., Wei, J., Li, W., Liu, C., Wang, Y., and Zhao, D.Y.: Multifunctional mesoporous composite microspheres with well-designed nanostructure: A highly integrated catalyst system. J. Am. Chem. Soc. 132(24), 8466–8473 (2010).Google Scholar
Wu, K.L., Wei, X.W., Zhou, X.M., Wu, D.H., Liu, X.W., Ye, Y., and Wang, Q.: NiCo2 alloys: Controllable synthesis, magnetic properties, and catalytic applications in reduction of 4-nitrophenol. J. Phys. Chem. C 115(33), 16268–16274 (2011).Google Scholar