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Nanocomposite stability in Fe-, Co-, and Mn-based perovskite/spinel systems

Published online by Cambridge University Press:  11 April 2012

Joerg Hoffmann ,
Sven Schnittger ,
Jonas Norpoth ,
Stephanie Raabe ,
Thilo Kramer  and
Christian Jooss
Joerg Hoffmann*
Affiliation:
Institute of Materials Physics, University of Goettingen, 37077 Goettingen, Germany
Sven Schnittger
Affiliation:
Institute of Materials Physics, University of Goettingen, 37077 Goettingen, Germany
Jonas Norpoth
Affiliation:
Institute of Materials Physics, University of Goettingen, 37077 Goettingen, Germany
Stephanie Raabe
Affiliation:
Institute of Materials Physics, University of Goettingen, 37077 Goettingen, Germany
Thilo Kramer
Affiliation:
Institute of Materials Physics, University of Goettingen, 37077 Goettingen, Germany
Christian Jooss
Affiliation:
Institute of Materials Physics, University of Goettingen, 37077 Goettingen, Germany
*
a)Address all correspondence to this author. e-mail: jhoffmann@ump.gwdg.de
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Abstract

Fabrication of thin film nanocomposites via decomposition and self-assembly from the vapor phase is a promising path for cost-effective fabrication of multifunctional materials. In particular, oxides as a new class of energy materials allow for rich functionalities, e.g., by combining p- and n-doped systems in catalytic or light harvesting units. Combining A-site doped perovskites ABO3 with CoFe2O4 spinel, we have investigated thin film phase composition and nanocomposite morphology in the pseudobinary system La0.6Sr0.4BO3–CoFe2O4 for B = Fe, Co, and Mn. We observe formation of an epitaxial two-phase nanocomposite for B = Fe, i.e., the coexistence of La0.6Sr0.4FeO3 and CoFe2O4. In contrast, for B = Co or Mn nanocomposites are formed, where perovskite La0.6Sr0.4BO3 solid solutions coexists with Co-rich spinel and periclase phases. We derive conclusions for the preparation of perovskite-spinel nanocomposites with well-designed doping levels.

Keywords

CompositeOxideSelf-assembly
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 11 , 14 June 2012 , pp. 1462 - 1470
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

1.Fiebig, M.: Revival of the magnetoelectric effect. J. Phys. D: Appl. Phys. 38, R123 (2005).CrossRefGoogle Scholar
2.Nan, C., Bichurin, M.I., Dong, S., Viehland, D., and Srinivasan, G.: Multiferroic magnetoelectric composites: Historical perspective, status, and future directions. J. Appl. Phys. 103, 031101 (2008).CrossRefGoogle Scholar
3.Yang, F., Shtein, M., and Forrest, S.R.: Controlled growth of a molecular bulk heterojunction photovoltaic cell. Nat. Mater. 4, 37 (2005).CrossRefGoogle Scholar
4.Yoon, J., Cho, S., Kim, J., Lee, J., Bi, Z., Serquis, A., Zhang, X., Manthiram, A., and Wang, H.: Vertically aligned nanocomposite thin films as a cathode/electrolyte interface layer for thin-film solid oxide fuel cells. Adv. Funct. Mater. 19, 3868 (2009).CrossRefGoogle Scholar
5.MacManus-Driscoll, J.L.: Self-assembled heteroepitaxial oxide nanocomposite thin film structures: Designing interface-induced functionality in electronic materials. Adv. Funct. Mater. 20, 2035 (2010).CrossRefGoogle Scholar
6.MacManus-Driscoll, J.L., Zerrer, P., Wang, H., Yang, H., Yoon, J., Fouchet, A., Yu, R., Blamire, M.G., and Jia, Q.: Strain control and spontaneous phase ordering in vertical nanocomposite heteroepitaxial thin films. Nat. Mater. 7, 314 (2008).CrossRefGoogle ScholarPubMed
7.Zheng, H., Wang, J., Lofland, S.E., Ma, Z., Mohaddes-Ardabili, L., Zhao, T., Salamanca-Riba, L., Shinde, S.R., Ogale, S.B., Bai, F., Viehland, D., Jia, Y., Schlom, D.G., Wuttig, M., Roytburd, A., and Ramesh, R.: Multiferroic BaTiO3-CoFe2O4 nanostructures. Science 303, 661 (2004).CrossRefGoogle ScholarPubMed
8.Zavaliche, F., Zheng, H., Mohaddes-Ardabili, L., Yang, S., Zhan, Q., Shafer, P., Reilly, E., Chopdekar, R., Jia, Y., Wright, P., Schlom, D., Suzuki, Y., and Ramesh, R.: Electric field-induced magnetization switching in epitaxial columnar nanostructures. Nano Lett. 5, 1793 (2005).CrossRefGoogle ScholarPubMed
9.Zhan, Q., Yu, R., Crane, S.P., Zheng, H., Kisielowski, C., and Ramesh, R.: Structure and interface chemistry of perovskite-spinel nanocomposite thin films. Appl. Phys. Lett. 89, 172902 (2006).CrossRefGoogle Scholar
10.Tokura, Y.: Colossal Magnetoresistive Oxides (Gordon and Breach Science Publishers, Amsterdam, 2000).CrossRefGoogle ScholarPubMed
11.Tomioka, Y., Asamitsu, A., Kuwahara, H., Moritomo, Y., and Tokura, Y.: Magnetic-field-induced metal-insulator phenomena in Pr1-xCaxMnO3 with controlled charge-ordering instability. Phys. Rev. B 53, R1689 (1996).CrossRefGoogle ScholarPubMed
12.Asamitsu, A., Tomioka, Y., Kuwahara, H., and Tokura, Y.: Current switching of resistive states in magnetoresistive manganites. Nature 388, 50 (1997).CrossRefGoogle Scholar
13.Zakhvalinskii, V.S., Laiho, R., Lashkul, A.V., Lisunov, K.G., Lähderanta, E., Nekrasova, Yu.S., and Petrenko, P.A.: Hopping conductivity of La1-xSrxMn1-yFeyO3. J. Phys. Conf. Ser. 303, 012066 (2011).CrossRefGoogle Scholar
14.Jonker, G.H.: Analysis of the semiconducting properties of cobalt ferrite. J. Phys. Chem. Solids 9, 165 (1959).CrossRefGoogle Scholar
15.Man, I.C., Su, H-Y., Calle-Vallejo, F., Hansen, H.A., Martinez, J.I., Inoglu, N.G., Kitchin, J., Jaramillo, T.F., Nørskov, J.K., and Rossmeisl, J.: Universality in oxygen evolution electrocatalysis on oxide surfaces. ChemCatChem 2, 1159 (2011).CrossRefGoogle Scholar
16.Roiter, B.D. and Paladino, A.E.: Phase equilibria in the ferrite region of the system Fe-Co-O. J. Am. Ceram. Soc. 45, 128 (1962).CrossRefGoogle Scholar
17.Axelsson, A-K., Aguesse, F., Spillane, L., Valant, M., McComb, D.W., and Alford, N.McN.: Quantitative strain analysis and growth mode of pulsed laser deposited epitaxial CoFe2O4 thin films. Acta Mater. 59, 514 (2011).CrossRefGoogle Scholar
18.Kim, K.J., Kim, H.K., Park, Y.R., and Park, J.Y.: Effects of Mn substitution of Co and Fe in spinel CoFe2O4 thin films. J. Magn. Magn. Mater. 304, e106 (2006).CrossRefGoogle Scholar
19.Kubaschewski, O., Alcock, C.B., and Spencer, P.J.: Materials Thermochemistry (Pergamon Press, New York, 1993).Google Scholar
20.Navrotski, A. and Kleppa, O.J.: Thermodynamics of formation of simple spinels. J. Inorg. Nucl. Chem. 30, 479 (1968).CrossRefGoogle Scholar
21.Calle-Vallejo, F., Martínez, J.I., García-Lastra, J.M., Mogensen, M., and Rossmeisl, J.: Trends in stability of perovskite oxides. Angew. Chem. Int. Ed. 49, 7699 (2010).CrossRefGoogle ScholarPubMed
22.Cheng, J. and Navrotsky, A.: Enthalpies of formation of LaMO3 perovskites (M = Cr, Fe, Co, and Ni). J. Mater. Res. 20, 191 (2005).CrossRefGoogle Scholar
23.Jung, I-H., Decterov, S.A., Pelton, A.P., Kim, H-M., and Kang, Y-B.: Thermodynamic evaluation and modeling of the Fe–Co–O system. Acta Mater. 52, 507 (2004).CrossRefGoogle Scholar
24.Filonova, E.A., Demina, A.N., Kleibaum, E.A., Gavrilova, L.Y., and Petrov, A.N.: Phase equilibria in the system LaMnO3+d–SrMnO3–LaFeO3–SrFeO3–d. Inorg. Mater. 42, 443 (2006).CrossRefGoogle Scholar
25.Aksenova, T.V., Anan’ev, M.V., Gavrilova, L.Y., and Cherepanov, V.A.: Phase equilibria and crystal structures of solid solutions in the system LaCoO3–d–SrCoO2.5±d–SrFeO3–d–LaFeO3–d. Inorg. Mater. 43, 296 (2007).CrossRefGoogle Scholar
26.Subramanian, R. and Dieckmann, R.: Limits of thermodynamic stability of cobalt-iron-manganese mixed oxides at 1200 °C. J. Am. Ceram. Soc. 75, 382 (1992).CrossRefGoogle Scholar
27.Kaul, A.R., Gorbenko, O.Y., and Kamenev, A.A.: The role of heteroepitaxy in the development of new thin-film oxide-based functional materials. Russ. Chem. Rev. 73, 861 (2004).CrossRefGoogle Scholar
28.Zheng, H., Zhan, Q., Zavaliche, F., Sherburne, M., Straub, F., Cruz, M.P., Chen, L-Q., Dahmen, U., and Ramesh, R.: Controlling self-assembled perovskite-spinel nanostructures. Nano Lett. 6, 1401 (2006).CrossRefGoogle ScholarPubMed
29.Shchukin, V.A. and Bimberg, D.: Spontaneous ordering of nanostructures on crystal surfaces. Rev. Mod. Phys. 71, 1125 (1999).CrossRefGoogle Scholar
30.Li, Z., Fisher, E.S., Liu, J.Z., and Nevitt, M.V.: Single-crystal elastic constants of Co-Al and Co-Fe spinels. J. Mater. Sci. 26, 2621 (1991).CrossRefGoogle Scholar
31.Sumino, Y., Kumazwa, M., Nishizawa, O., and Pluschkell, W.: The elastic constants of single crystal Fe1-xO, MnO and CoO and the elasticity of stoichiometric magnesiowustite. J. Phys. Earth 28, 475 (1980).CrossRefGoogle Scholar
32.Varghese, B., Zhang, Y., Dai, L., Tan, V.B.C., Lim, C.T., and Sow, C-H.: Structure-mechanical property of individual cobalt oxide nanowires. Nano Lett. 8, 3226 (2008).CrossRefGoogle ScholarPubMed
33.Orlovskaya, N., Anderson, H., Brodnikovskyy, M., Lugovy, M., and Reece, M.J.: Inelastic deformation behavior of La0.6Sr0.4FeO3 perovskite. J. Appl. Phys. 100, 026102 (2006).CrossRefGoogle Scholar
34.Rajendran, V., Kumaran, S.M., Sivasubramanian, V., Jayakumar, T., and Raj, B.: Anomalies in elastic moduli and ultrasonic attenuation near ferromagnetic transition temperature in La0.67Sr0.33MnO3 perovskite. Phys. Status Solidi A 195, 350 (2003).CrossRefGoogle Scholar
35.Srolovitz, D.J.: On the stability of surfaces of stressed solids. Acta Metall. Mater. 37, 621 (1989).CrossRefGoogle Scholar