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Neutron irradiation and annealing of 10B doped chemical vapor deposited diamond films

Published online by Cambridge University Press:  03 March 2011

S.A. Khasawinah
Affiliation:
Nuclear Engineering Department, University of Missouri, Columbia, Missouri 65211
Galina Popovici
Affiliation:
Nuclear Engineering Department, University of Missouri, Columbia, Missouri 65211, and Rockford Diamond Technology, Professional Arts Bldg., 501 S. Sixth Street, Champaign, Illinois 61820-55789
J. Farmer
Affiliation:
University of Missouri Research Reactor, Columbia, Missouri 65211
T. Sung
Affiliation:
Nuclear Engineering Department, University of Missouri, Columbia, Missouri 65211
M.A. Prelas
Affiliation:
Nuclear Engineering Department, University of Missouri, Columbia, Missouri 65211
J. Chamberlain
Affiliation:
Physics Department, University of Missouri, Columbia, Missouri 65211
H. White
Affiliation:
Physics Department, University of Missouri, Columbia, Missouri 65211
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Abstract

10B doped diamond films grown by hot filament chemical vapor deposition were neutron irradiated at moderately high fluence levels. The as-irradiated and annealed samples, along with an unirradiated sample, were analyzed using Raman spectroscopy and x-ray diffraction. It was found that a non-diamond amorphous phase was formed on irradiation. This phase transformed back to diamond on annealing. No graphite formation was observed. A comparison with nanodiamond powder was made. A similarity between irradiated diamond films and nanocrystalline diamond powder is discussed.

Type
Articles
Copyright
Copyright © Materials Research Society 1995

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References

REFERENCES

1Spitsyn, B., Popovici, G., and Prelas, M. A., Second International Conference on the Applications of Diamond Films and Related Materials, edited by Yoshikawa, M., Murakawa, M., Tzeng, Y., and Yarbrough, W. A., August 25–27, 1993, Tokyo, Japan, pp. 5764.Google Scholar
2Bernholc, J., Kajihara, S. A., and Antonelli, A., in New Diamond Science and Technology, edited by Messier, R., Glass, J. T., Butler, J. E., and Roy, R. (Mater. Res. Soc. Symp. Int. Proc. NDST2, Pittsburgh, PA, 1991), p. 923.Google Scholar
3Prins, J. F, Mater. Sci. Reports 7, 271 (1992).CrossRefGoogle Scholar
4Sellshop, J. P. F., The Properties of Diamond, edited by Field, J. E. (Academic Press, London, 1979), pp. 108159.Google Scholar
5Collins, A. T., Physica B 185, 284 (1993).CrossRefGoogle Scholar
6Wilks, J. and Wilks, E., Properties and Applications of Diamond (Butterworth-Heinemann, Oxford, 1991), pp. 8591, 285289.Google Scholar
7Khasawinha, S., Sung, T., Spitsyn, B., Miller, W. H., Popovici, G., Prelas, M. A., Charlson, E. J., Charlson, E. M., Meese, J., and Stacy, T., in Diamond Materials, edited by Dismukes, J. P. and Ravi, K. V., bElectrochemical Society Proc. (1993), Vol. 93–17, pp. 10321035.Google Scholar
8Gildenblat, G. S., Grot, S. A., and Badzian, A., Proc. IEEE 79, 647 (1991).CrossRefGoogle Scholar
9Warren, B. E., X-Ray Diffraction (Dover Publishers, New York, 1990), pp. 251274.Google Scholar
10Knight, D. S. and White, W. B., J. Mater. Res. 4, 385 (1989).CrossRefGoogle Scholar
11Etz, E. S., Farabaugh, E. N., Feldman, A., and Robins, L.H., SPIE, Vol. 968, Diamond Optics, edited by Feldman, A. and Holly, S. (1988), p. 86.Google Scholar
12Gheeraert, E., Deneuville, A., Bonnot, A. M., and Abello, L., Diamond and Related Materials 1, 525 (1992).CrossRefGoogle Scholar
13Grimsch, M. H., Anastakis, E., and Cardona, M., Phys. Rev. B 18, 901 (1991).CrossRefGoogle Scholar
14Bopart, H., van Straaten, J., and Silvera, I. F., Phys. Rev. B 32, 1423 (1985).CrossRefGoogle Scholar
15Klein, C. A., Harnett, T. M., and Robimson, C. J., SPIE 1534, 117 (1991).Google Scholar
16Popovici, G., Chao, C. H., Prelas, M. A., Charlson, E. J., and Meese, J. M., J. Mater. Res. 10, 2011 (1995).CrossRefGoogle Scholar