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Optical studies of polyvinylpyrrolidone reduction effect on free and complex metal ions

Published online by Cambridge University Press:  03 March 2011

Caixia Kan ,
Weiping Cai ,
Cuncheng Li  and
Lide Zhang
Caixia Kan
Affiliation:
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academia of Sciences, Hefei 230031, People's Republic of China
Weiping Cai*
Affiliation:
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academia of Sciences, Hefei 230031, People's Republic of China
Cuncheng Li
Affiliation:
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academia of Sciences, Hefei 230031, People's Republic of China
Lide Zhang
Affiliation:
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academia of Sciences, Hefei 230031, People's Republic of China
*
a) Address all correspondence to this author. e-mail: wpcai@issp.ac.cn
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Abstract

Polyvinylpyrrolidone (PVP) reduction effect on free and complex Ag+ and Au3+ ions was studied from optical measurements by adding a metal precursor (K-30), commonly used as a stabilizer, to PVP. It was found that PVP has a strong reduction effect on free ionic metal, such as Ag+ ion in AgNO3, but much weaker on complex ionic metals, AuCl4− in HAuCl4 and Ag(NH3)2+ in Ag(NH3)2OH. This is explained based on the coordinative field of polar group in PVP molecules.

Keywords

Chemical reactivityNanoparticleOptical properties
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 2 , February 2005 , pp. 320 - 324
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1.Faraday, M.: Experimental relations of gold (and other metals) to light. Philos. Trans. R. Soc. London 147, 145 (1857).Google Scholar
2.Giersig, M. and Mulvaney, P.: Preparation of ordered colloid monolayers by electrophoretic deposition. Langmuir 9, 3408 (1993).CrossRefGoogle Scholar
3.Brust, M., Walker, M., Bethell, D., Schiffrin, D.J. and Whyman, R.: Synthesis of thiol derivatised gold nanoparticles in a two phase liquid/liquid system. J. Chem. Soc. 801 (1994).Google Scholar
4.Pileni, M.P.: Nanocrystal self-assemblies: fabrication and collective properties. J. Phys. Chem. B 105, 3358 (2001).CrossRefGoogle Scholar
5.Hao, E. and Lian, T.: Buildup of polymer/Au nanoparticles multilayer thin films based on hydrogen bonding. Chem. Mater. 12, 3392 (2000).CrossRefGoogle Scholar
6.Liu, F.K., Hsieh, S.Y., Chu, T.C. and Dai, B.T.: Synthesis of nanometer-sized poly (methyl methacrylate) polymer network by gold nanoparticle template. Jpn. J. Appl. Phys. 42, 4147 (2003).CrossRefGoogle Scholar
7.Toshima, N.: Metals—reactions in homogenous solutions, in Fine Particles—Synthesis, Characterization, and Mechanisms of Growth, edited by Sugimoto, T. (Institute for Advanced Materials Proc., Marcel Dekker, New York, 2000), p. 439.Google Scholar
8.Sun, Y.G., Gates, B., Mayers, B. and Xia, Y.N.: Crystalline Silver nanowires by soft solution processing. Nano Lett. 2, 165 (2002).CrossRefGoogle Scholar
9.Silvert, P.Y., Urbina, R.H. and Elhsissen, K.T.: Preparation of colloidal silver dispersions by the polyol process. Part 2: Mechanism of particles formation. J. Mater. Chem. 7, 293 (1997).CrossRefGoogle Scholar
10.Duff, D.G., Baiker, A. and Edwards, P.: New hydrosol of gold clusters. 1. Formation and particle size variation. Langmuir 9, 2301 (1993).CrossRefGoogle Scholar
11.Santos, I.P. and Marzán, L.M.: Formation of PVP-protected metal nanoparticles in DMF. Langmuir 18, 2888 (2002).CrossRefGoogle Scholar
12.Sun, Y.G., Mayers, B., Herricks, T. and Xia, Y.N.: Polyol synthesis of uniform silver nanowires: A plausible growth mechanism and the supporting evidence. Nano Lett. 3, 955 (2002).CrossRefGoogle Scholar
13.Carotenuto, G., DeNicola, S. and Nicolais, L.: Spectroscopic study of the growth mechanism of silver microclusters. J. Nanopart. Res. 3, 469 (2001).CrossRefGoogle Scholar
14.Han, M.Y., Quek, C.H., Huang, W., Chew, C.H. and Gan, L.M.: A simple and effective chemical route for the preparation of uniform nonaqueous Au colloids. Chem. Mater. 11, 1144 (1999).CrossRefGoogle Scholar
15.Krebig, U. and Vollmer, M.: Theoretical considerations—single clusters: Intrinsic size effects of the optical properties, in Optical Properties of Metal Clusters, edited by Gonser, U., Osgood, R.M. Jr.Panish, M.B., and Sakaki, H. (Springer-Verlag, Berlin and Heidelberg, Germany, 1995), p. 83.CrossRefGoogle Scholar
16.Bohren, C.F. and Huffman, D.R.: Surface modes in small particles, in Absorption and Scattering of Light by Small Particles, edited by Bohren, C.F. and Huffman, D.R. (J. Wiley & Sons Inc., New York, 1983), p. 373.Google Scholar
17.Esumi, K., Hara, J., Aihara, N., Usui, K. and Torigoe, K.: Preparation of aniosotropic gold particles using a Gemini surfactant. J. Colloid Interface Sci. 208, 578 (1998).CrossRefGoogle Scholar
18.Zhou, G.D. and Duan, L.Y.: Structure and properties of coordination composites, in Structural Chemistry, edited by Zhou, G.D. and Duan, L.Y. (Beijing University Press, Beijing, China, 1995), p. 288.Google Scholar
19.Zhang, Z.T., Zhao, B. and Hu, L.M.: PVP protective mechanism of ultrafine silver powder synthesized by chemical reduction processes. J. Solid State Chem. 121, 105 (1996).CrossRefGoogle Scholar
20.Gratzel, M. and Frank, A.J.: Interfacial electron-transfer reactions in colloidal semiconductor dispersions. Kinetic analysis. J. Phys. Chem. 86, 2964 (1982).CrossRefGoogle Scholar